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PAGEREF _Toc12685507 \h 49  HYPERLINK \l "_Toc12685508" ;075@>;N<8=5AF5=F8/ Sm3+ 2 <8=5@0;0E 3@C??K 15@10=:8B0, :0@1>F5@=08B5 8 AB@>=F80=8B5  PAGEREF _Toc12685508 \h 51  HYPERLINK \l "_Toc12685509" 8=5@0;>38O ?>;>38E @C4=KE B5; <5AB>@>645=8O >G1C;0:  PAGEREF _Toc12685509 \h 52  HYPERLINK \l "_Toc12685510" AA>F80F8O A0<>@>4=KE <8=5@0;>2 A8AB5<K Pb Sn Sb 87 ?>@>4 @C4=>3> :><?;5:A0 >24>@A:>3> <0AA820  PAGEREF _Toc12685510 \h 54  HYPERLINK \l "_Toc12685511"     &!! ! "& #," "  ! . #   PAGEREF _Toc12685511 \h 55  HYPERLINK \l "_Toc12685512"  &+ - -" ! !" / (.+ # , !!/)  PAGEREF _Toc12685512 \h 56  HYPERLINK \l "_Toc12685513"  <8=5@0;L=>< A>AB025  A8=8E 3;8= =86=53> :5<1@8O A525@>-70?040 CAA:>9 ?;0BD>@<K  PAGEREF _Toc12685513 \h 57  HYPERLINK \l "_Toc12685514" $"-  ".!&&/ !" !# ! !" /   #,! !"&   !"&  % #/  PAGEREF _Toc12685514 \h 58  HYPERLINK \l "_Toc12685515" &!"   + +" / ! "" ! !" / % "-!!".  PAGEREF _Toc12685515 \h 60  HYPERLINK \l "_Toc12685516" % " + !!"   !" )!"  . !% "  +% "/% .-!"  !   PAGEREF _Toc12685516 \h 60  HYPERLINK \l "_Toc12685517" !C;LD84=0O <8=5@0;870F8O :0@1>=0B8B>2 8 @C4 >24>@A:>3> <0AA820  PAGEREF _Toc12685517 \h 61  HYPERLINK \l "_Toc12685518"  ! ) ,"  "'!%  %  %/-+!%   PAGEREF _Toc12685518 \h 62  HYPERLINK \l "_Toc12685519" + #+ ",- "+% "!""  " $ & ( ! !" / (!  # )  PAGEREF _Toc12685519 \h 63  HYPERLINK \l "_Toc12685520" A>15==>AB8 <5B0A><0B8G5A:8E ?@>F5AA>2 2 M2>;NF88 @>48=38B>2 (=0 ?@8<5@5 065=>2A:>3> <5AB>@>645=8O, !@54=89 #@0;)  PAGEREF _Toc12685520 \h 65  HYPERLINK \l "_Toc12685521"  "+  & +: !!", !" ,       PAGEREF _Toc12685521 \h 66  HYPERLINK \l "_Toc12685522" .! ) !"   "+% "!"" . !!  PAGEREF _Toc12685522 \h 68  HYPERLINK \l "_Toc12685523" !2>9AB20 8 A>AB02 A0<>@>4=>3> 7>;>B0 .6=>-G:0@A:>9 @>AAK?8 #@0;0  PAGEREF _Toc12685523 \h 69  HYPERLINK \l "_Toc12685524" !0<>@>4=0O <54L 5B=53> <54=>:>;G540==>3> <5AB>@>645=8O, .6=K9 #@0;  PAGEREF _Toc12685524 \h 70  HYPERLINK \l "_Toc12685525" 10;0=A )!"    F!!% # "&  "" .!"+%   "+% ?>@>  PAGEREF _Toc12685525 \h 71  HYPERLINK \l "_Toc12685526" $ &/ ",+%   "+%  " PR1 # ! )"  PAGEREF _Toc12685526 \h 73  HYPERLINK \l "_Toc12685527" Mineralogy of the Upper Mantle Xenoliths in Alkaline Basalts of Tariat and Dariganga plateaus, Mongolia  PAGEREF _Toc12685527 \h 74  HYPERLINK \l "_Toc12685528" STUDYING ORGANIC SUBSTANCE AS A STRUCTURAL ELEMENT OF URIC STONES.  PAGEREF _Toc12685528 \h 75  HYPERLINK \l "_Toc12685529" MINERALS of the MIDWESTERN UNITED STATES  PAGEREF _Toc12685529 \h 75  HYPERLINK \l "_Toc12685530" PGM AND OTHER ACCESSORY MINERALS OF HYDROGENOUS FERROMNGANESE OCEANIC CRUSTS PACIFIC OCEAN CASE STUDY  PAGEREF _Toc12685530 \h 76  HYPERLINK \l "_Toc12685531" CHOLESTEROL AS AN ORGANIC COMPONENT OF BIOMINERALS AT CHOLELITHIASIS  PAGEREF _Toc12685531 \h 78 !0<>@>4=>5 7>;>B> 87 @C4 7>;>B>-A5@51@O=>3> <5AB>@>645=8O !8=538B0 (5:A8:0) =8A8<>2 .!. XE "=8A8<>2 .!."  !0=:B-5B5@1C@3A:89 3>AC40@AB25==K9 C=825@A8B5B, >AA8O Anisimov I.S. Native gold from Cieneguita gold-silver deposit, Mexico. (Saint-Petersburg State University, Russia). Native gold from Cieneguita deposit is both hypogene and hypergene. Hypogene gold appears in quartz-muskovite-polymetallic, quartz-pyrite-arsenopyrite and quartz parageneses; hypergene found in quartz-gematite paragenesis. Minerals from each association differs in grain and surface morphology, and chemical composition. Hypergene gold appears to have porous grains, richer probe (980990), more admixtures: Fe, Te, Cu while hypogene gold has more silver and less other admixtures. 0;>5 7>;>B>A5@51@O=>5 <5AB>@>645=85 !8=538B0 =0E>48BAO 2 3>@0E 0?04=0O !L5@@0-04@5. => ?@8=04;568B : >4=>8<5==>9 D>@<0F88 8 O2;O5BAO 1;87?>25@E=>AB=K<. >;>B>A5@51@O=>5 >B=>H5=85 =0 <5AB>@>645=88 :>;51;5BAO 2 ?@545;0E 0,1 0,02. C4=K5 B5;0 ?@54AB02;5=K ;8=59=K<8 @C4=K<8 7>=0<8 A 2:@0?;5==>9, @565 ?@>68;:>2>-2:@0?;5==>9 ?8@8B>2>9 <8=5@0;870F859 2 0@38;;878B0E. >=0 >:8A;5=8O ?@>A;568205BAO 4> 3;C18=K 30 50 < 8 55 <>6=> @0745;8BL =0 ?>47>=K O@>78B870F88 8 35<0B8B870F88 [2]. 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"01;8F0 2 K45;5==K5 7>;>B>=>A=K5 0AA>F80F88$>@<0 2K45;5=89%0@0:B5@ ?>25@E=>AB8 07<5@ 2K45;5=89, <:<@>10@8<5A820@F-<CA:>28B-?8@8B>20O (?>;8<5B0;;8G5A:0O)><:>284=K5(5@>E>20B0O, A >B?5G0B:0<8 A>A54=8E <8=5@0;>250 300910 940Ag, Fe20@F-?8@8B-0@A5=>?8@8B>20O 48A?5@A=>< 2845 2 As-?8@8B5 8 0@A5=>?8@8B5  @54?>;>-68B5;L=> >:>;> 1  20@F520O@>2>;>:>284=K5, 45=4@8B>284=K5 >2=0O, 1;5ABOI0O50 200930 960Ag, Fe, "520@F-35<0B8B>20O/G58ABK5, 3C1G0BK5, 87><5B@8G=K5 >2=0O 8 OG58AB0O5 100980 990Ag, Fe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o;>B0 ?@8 CG0AB88 Fe2(SO4)3. 5@5>B;>65=85 7>;>B0 2 7>=5 38?5@35=570 7>;>B>@C4=KE 8 ?>;8<5B0;;8G5A:8E <5AB>@>645=89 8 >A0645=85 38?5@35==>3> ?>@8AB>3> 2KA>:>?@>1=>3> 7>;>B0 87 :8A;KE @0AB2>@>2 :>=AB0B8@CNB <=>385 8AA;54>20B5;8 [3 5, 6, 9]. 8B5@0BC@0: 1.Diaz Avalos Jorge Alberto Minera Glamis S.A.de C.V. Calculation of reserves and conceptual study of mine working for the  La Cieneguita on the surface mine. Chihuahua, Mexico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ixue Yang, Norbert Blum, Erio Rahders. The Nature of Invisible Gold in Sulfides from The Xiangxi Au Sb W Ore Deposit in Northern Hunan, People's Republic of China // The Can. Min., 1998. V.36. .1361 1372. + +   % , &,   / =8A8<>20 .!. XE "=8A8<>20 .!."   ! , 3. /:CBA:, >AA8O, g.s.anisimova@diamond.ysn.ru Anisimova G.S. New data about minerals of copper, zinc, tin and vanadium (IGDNM SB RAS, Yakutsk, Russia). The colusite-group mineral has been discovered for the first time in the Sette-Daban gold ores. Based on the tentative data on mineragraphy, microprobe and X-ray phase analyses, the mineral is attributed to zinciferous nekrasovite. The mineral up to 0.07 mm in size occurs in sphalerite both as individual disseminations and closely intergrowths with kesterite (second finding in Yakutia) and high-vanadium (54% V) mineral phase. Major lines of the mineral X-ray pattern: 3.10 (10), 1.908 (5), 1.632 (1). According to microprobe analyses of 10 grains, the average composition of mineral includes 40.03% Cu, 9.26% Zn, 2.64% V, 18.05% Sn, 0.15% Sb, 0.19% Ge, 0.37% Te, 28.76% S. The anomalously high content of zinc and absence of arsenic, antimony in its composition is the main difference between the mineral and nekrasovite [2] already known. One can suspect that Zn2+ is substituted for Cu2+ in the mineral composition and the X-position is completely occupied by tin. In the colusite group minerals the contents of one- and two-valent metals (Cu, Zn, Fe) may significantly change and the X-position remains stable. 8=5@0;K <548, F8=:0, >;>20 8 20=048O, 2E>4OI85 2 3@C??C :>;CA8B0, 8<5NB A;54CNICN D>@<C;C: Cu181+Cu62+(Cu2+,Fe,Zn)2 [(V3+,Fe3+)2 X64+S322 ], 345 X=[(As,Sb)3++(As,Sb)5+]/2, Sn4+, Ge4+, Te, Mo. 0==0O 3@C??0 =54>AB0B>G=> 87CG5=0 8 E0@0:B5@87C5BAO H8@>:8<8 20@80F8O<8 A>45@60=89 87><>@D=KE M;5<5=B>2.  <8=5@0;0E MB>9 3@C??K >ICB8<K5 87<5=5=8O ?@>8AE>4OB <564C A>45@60=85< <KHLO:0, AC@L<K, >;>20 8 35@<0=8O, 8 ?> MB><C ?@87=0:C 2K45;ONBAO ACI5AB25==> <KHLO:>28ABK9 0=0;>3  :>;CA8B [5], ACI5AB25==> AC@L<O=8ABK9 0=0;>3  AB818>:>;CA8B [3], ACI5AB25==> 35@<0=852K9 0=0;>3  35@<0=>:>;CA8B [4] 8 ACI5AB25==> >;>2O=8ABK9 0=0;>3  =5:@0A>28B [2]. 0: 284=>, H8@>:85 20@80F88 <564C :>=F5=B@0F859 <KHLO:0, AC@L<K, 35@<0=8O 8 >;>20 4>AB0B>G=> 8725AB=K, 0 A;CG08 20@80F88 <564C <54LN, 65;57>< 8 F8=:>< 2 A>AB025 <8=5@0;0 2 ;8B5@0BC@5 ?>:0 =5 ?@82>48;8AL. 0<8 2 7>;>B>=>A=KE @C40E (8@>:8=A:>3> C7;0 (!5BB5-010=A:89 3>@AB-0=B8:;8=>@89) =0945= <8=5@0;, :>B>@K9 ?> <8=5@03@0D8G5A:8<, <8:@>7>=4>2K< 8 @5=B35=>D07>2K< 40==K< ?@5420@8B5;L=> >B=5A5= : F8=:8AB><C =5:@0A>28BC [1]. 8=5@0; =0945= 2 <0;>AC;LD84=KE :20@F52KE @C40E, 70;530NI8E A@548 :0@1>=0B878@>20==KE B5@@835==KE ?>@>4. ?8AK205<K9 <8=5@0; @07<5@0<8 4> 0,07 << >1=0@C65= 2 AD0;5@8B5, :0: 2 2845 A0<>AB>OB5;L=KE 2:@0?;5=89, B0: 8 B5A=>< A@0AB0=88 A @54:8< <8=5@0;>< :5AB5@8B>< (2B>@0O =0E>4:0 2 /:CB88) 8 2KA>:>20=04852>9 (54% V) <8=5@0;L=>9 D07>9. 5=B35=>3@0D8G5A:85 8AA;54>20=8O <8=5@0;0, ?@>2545==K5 .. 0O:8=>9, 40NB A;54CNI85 >A=>2=K5 ;8=88 @5=B35=>3@0<<K, : 3,10 (10), 1,908 (5), 1,632 (1). > ..>20;5=:5@C 8 4@. [2], 4;O =5:@0A>28B0 E0@0:B5@=K A>>B25BAB2CNI85 40==K5 d (I): 3,09 (10), 1,89 (8), 1,62 (6). %8<8G5A:89 A>AB02 <8=5@0;0 >?@545;O;AO =0 <8:@>0=0;870B>@5 Camebax-micro ?@8 CA:>@ONI5< =0?@O65=88 20 : 8 B>:0E =0 >1@07F5 >B 20 4> 50<, ?@8 480<5B@5 7>=40 1 2 <:< (B01;8F0).  :0G5AB25 MB0;>=>2 8A?>;L7>20=K: E0;L:>?8@8B, A0<>@>4=K5 F8=:, >;>2>, 35@<0=89, A5@51@>, E0;L:>AB818B, 28A<CB8=, 30;5=8B, :04<>A5;8B, :>;>@04>8B. ;02=K< >B;8G85< <8=5@0;0 >B 8725AB=>3> =5:@0A>28B0 [2] O2;O5BAO 0=><0;L=> 2KA>:>5 A>45@60=85 F8=:0 8 >BACBAB285 2 53> A>AB025 AC@L<K 8 <KHLO:0, => ?@8 MB>< ?> :>=F5=B@0F88 >;>20 >?8AK205<K9 <8=5@0; 1>;55 1;87>: : :@09=5<C >;>2O=8AB><C G;5=C 87><>@D=>3> @O40 :>;CA8B-=5:@0A>28B.  40==>< A;CG05 8<5NB <5AB> 20@80F88 <564C A>45@60=8O<8 <548 8 F8=:0. >6=> ?@54?>;>68BL, GB> G0ABL Cu2+ 2 A>AB025 <8=5@0;0 70<5I05BAO Zn2+, 0 ?>78F8O % ?>;=>ABLN 70=OB0 >;>2><. 0=55 >B<5G0;>AL [3], GB> ?>78F88 >4=>- 8 42CE20;5=B=KE <5B0;;>2 ?@0:B8G5A:8 70=OBK >4=>9 Cu, => 2 =0H5< A;CG05 2KA>:85 :>=F5=B@0F88 F8=:0 ?@>B82>@5G0B MB><C. 1>1I5==0O D>@<C;0 <8=5@0;0 2K3;O48B A;54CNI8< >1@07><: Cu22,12Zn4,96V1,84 (Sn5,35 Ge0,09 Sb0,04)5,48Te0,09S31,51.  70:;NG5=85 <>6=> :>=AB0B8@>20BL, GB> 2 <8=5@0;0E 3@C??K :>;CA8B0 ACI5AB25==K5 87<5=5=8O <>3CB ?@>87>9B8 8 2 A>45@60=88 >4=>- 8 42CE20;5=B=KE <5B0;;>2 (!u, Zn, Fe) ?@8 AB018;L=>< ?>;>65=88 ?>78F88 %. "01;8F0 %8<8G5A:89 A>AB02 (<0A.%) <8=5@0;0 Chemical composition of the mineral (wt. %) 5@=>CuZnFeVSnAsSbTeGeS!C<<0139,728,96 2,9318,86 0,150,35 28,3399,30239,519,58 2,9118,27 0,120,45 28,3799,21338,44 11,08 2,7517,84 0,120,350,5828,92100,08439,009,86 2,5418,170,160,300,1028,8298,95540,938,652,5318,240,150,340,4529,37100,66640,668,672,43 18,600,130,4529,33100,27739,7610,312,4516,870,160,370,2929,0199,22840,348,772,5718,340,160,340,2328,9099,65940,958,022,7718,630,180,3527,9598,851041,008,742,5416,570,140,390,2428,5798,195:@0A>28B [2]44,100,113,922,0611,133,214,25  29,9199,16"5>@5B. A>AB0247,31 2,9220,39    29,38100,00@8<5G0=85. =0;87K (1 10) 2K?>;=5=K 2  ! . =0;8B8: !..>?>20. !28=5F, @BCBL, A5@51@>, <KHLO:, A5;5=, 65;57> 2 ?@545;0E GC2AB28B5;L=>AB8 0=0;870 =5 >1=0@C65=K. 8B5@0BC@0:1.=8A8<>20 .!, 8 4@. 5@20O =0E>4:0 F8=:8AB>9 @07=>284=>AB8 =5:@0A>28B0 //  A1.: 8=5@0;>38O  >A=>20 8A?>;L7>20=8O :><?;5:A=KE @C4. !1., 2001. !.26 28. 2.>20;5=:5@ .., 8 4@. 5:@0A>28B Cu26V2Sn6S32  =>2K9 <8=5@0; 3@C??K :>;CA8B0 // 8=. 6C@=., 1984. ".6. !2. !.88 97. 3.!?8@84>=>2 -., 0G0;>2A:0O .., 040;>2 .!. 07=>284=>AB8 :>;CA8B0, > 20=04852>< 8 20=04852>-<KHLO:>2>< 35@<0=8B5 // 5AB=8: #. !5@8O 35>;>38O, 1986. !3. !.60 69. 4.!?8@84>=>2 -.., 040;>2 .!., >20G52 .. !B818>:>;CA8B Cu26V2 (Sb,Sn,As)6S32  =>2K9 <8=5@0; // >:;. , 1992. ".234. !2. !.411 414. 5.!?8@84>=>2 -.., 8 4@. 5@<0=>:>;CA8B Cu26V2(Ge,As)6S32  =>2K9 <8=5@0; // 5AB=8: #. !5@8O 35>;>38O, 1992. !6. !.50. 6.Orlando P., e.a. Colusite: a new occurence and crystal chemistry // Can. Min., 1981. V.19. P.423 427.  ,+ !!" "  #/  ! "   "+%  % . !! @B5<5=:> . XE "@B5<5=:> ." ., @B5<5=:> .. XE "@B5<5=:> .."   #:@ , 3.!8<D5@>?>;L, #:@08=0, imr@utel.net.ua Artemenko V.M., Artemenko O.V. The mineral composition of the Carlin type gold mineralization in carbonaceous rocks of the South Donbass (CB UkrSGRI, Simferopol, Ukraine). On the basis of complex geological-structural and mineralogical-geochemical investigation in Upper-Paleozoic terrigenous-carbonaceous complexes of the South Donbas the existence of the long-term gold-mercurial mineralization has been established. Among ore minerals pyrite, zarely sphalerite, galenite, arsenopyrite, lollingite, cinnabar, chalcopyrite, tennantite, bornite, chalcosite, molybdenite, native gold are most widely spread. The native gold is of a dust-like, very fine and fine grade, it is represented by mercurious and cupreous varieties and also by segregations of high standard of fineness, which do not contain any impurities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"5==0=B8B  @54:89 <8=5@0; 4;O >=10AA0, 345 ?@5>1;0405B AC@L<O=0O @07=>284=>ABL 1;5:;>9 @C4K.  8AA;54C5<>< B5==0=B8B5 A>45@60=85 AC@L<K =5 ?@52KH05B 1,2%. 7 87><>@D=KE ?@8<5A59 4;O B5==0=B8B0 E0@0:B5@5= F8=:, A>45@60=85 :>B>@>3> 4>AB8305B 7,8%. >AB>O==>, ?@8ACBAB2C5B ?@8<5AL 65;570, :>;8G5AB2> :>B>@>3> A>AB02;O5B 1,9%. @><5 B>3>, 2 B5==0=B8B5 CAB0=>2;5=K ?@8<5A8 A28=F0, @BCB8, A5@51@0, 28A<CB0, B5;;C@0, A5;5=0 (<5=55 1%). !0<>@>4=>5 7>;>B> ?@54AB02;5=> ?@58<CI5AB25==> ?;5=>G=K<8 8 ?;0AB8=G0BK<8 2K45;5=8O<8, @565 :><:>20BK<8, C4;8=5==K<8 8 45=4@8B>284=K<8 75@=0<8. > @07<5@C 2K45;5=89 7>;>B8=K >B=>AOBAO : ?K;5284=><C (10 50 <:<), >G5=L <5;:><C (50 100 <:<), @565  <5;:><C (0,1 0,5<<) :;0AA0< (?> :;0AA8D8:0F88 ..5B@>2A:>9 [2]). AA;54>20=85 E8<8G5A:>3> A>AB020 A0<>@>4=>3> 7>;>B0 A ?><>ILN <8:@>7>=40 ?>:070;> ?@8ACBAB285 @BCB8AB>9 (A>45@60=85 @BCB8 4> 3,9%) 8 <548AB>9 (<548  4> 8,4%) @07=>284=>AB59, 0 B0:65 =0;8G85 2KA>:>?@>1=>3> 7>;>B0 (?@>1=>ABL 991 995), ?@0:B8G5A:8 =5 A>45@60I53> ?@8<5A59. @8ACBAB285 7>;>B>-@BCB=>3> >@C45=5=8O =0 C@>2=5 A>2@5<5==>3> M@>78>==>3> A@570 ?>2KH05B ?5@A?5:B82K 8AA;54C5<>3> @538>=0 4;O 2KA>:>MDD5:B82=>9 >B:@KB>9 (:0@L5@=>9) @07@01>B:8. 8B5@0BC@0: 1.@B5<5=:> .., 5154L .. >;>B>-@BCB=>5 >@C45=5=85 2 :0@1>=0B=KE ?>@>40E >:CG052A:>3> @C4=>3> @09>=0, .6=K9 >=10AA // 8=5@.@5AC@AK #:@08=K, 1996. !1. !.14 17. 2.5B@>2A:0O .. !0<>@>4=>5 7>;>B> (>1I0O E0@0:B5@8AB8:0, B8?><>@D87<, 2>?@>AK 35=578A0). .: 0C:0, 1973. 347A. 3.!B5?0=>2 .., >8A55=:> .. 5>;>38O 7>;>B0, A5@51@0 8 @BCB8. '0ABL1. >;>B>-@BCB=K5 <5AB>@>645=8O. ;0482>AB>:: 0;L=0C:0, 1993. 228A. !  "    + @B5<5=:> . XE "@B5<5=:> ." ., @B5<5=:> .. XE "@B5<5=:> .."  KA5=:> .. XE "KA5=:> .."   #:@ , 3.!8<D5@>?>;L, #:@08=0, imr@utel.net.ua Artemenko V.M., Artemenko O.V., Lysenko V.I. The native gold of the Upland Crimea (CB Ukr SGPI, Simferopol, Ukraine). In the south-western part of the Upland Crimea the native gold has been found on several sections in quartz gravel, occurring among Lower Cretaceous terrigenous sandy-argillaceous rocks, containing lenses of conglomerates and gritstones. The native gold is confined to a sugary-grained white and gray quartz in the association with pyrite, galenite, antimonite. The standard of fineness of the native gold is 660665. It is necessary to carry out the work, directed to revealing of native sources of gold-ore mineralization in the region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aupova@ilmeny.ac.ru Aupova N.R. The mineralogy of oxide-ferruginouse rocks of Uzelga sulfide-bearing field (the South Urals). (Institute of Mineralogy URB RAS, Miass, Russia). The transformation processes of primary hyaloclastic, sulphide and carbonate materials and relic minerals into oxide-ferruginouse rocks in Uzelga massive-sulphide-bearing field (the S.Urals) have been described. These processes are multi-stage. Every stage fixed in form of mineral associations. #75;L38=A:>5 :>;G540=>=>A=>5 ?>;5 @0A?>;>65=> 2 A525@=>9 G0AB8 03=8B>3>@A:>3> ?>3@C65=8O.  53> ?@545;0E =0E>4OBAO 452OBL :>;G540==KE <5AB>@>645=89 8 45AOB:8 @C4>?@>O2;5=89. >@87>=BK >:A84=>-65;578ABKE >B;>65=89 O2;ONBAO =081>;55 :@C?=K<8 4;O #@0;0 2 @C4>2<5I0NI8E @07@570E #75;L38=A:>3> :>;G540=>=>A=>3> ?>;O. 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"0:8< >1@07><, >:A84=>-65;578ABK5 >B;>65=8O #75;L38=A:>3> :>;G540=>=>A=>3> ?>;O O2;ONBAO @57C;LB0B>< 30;L<8@>;870 8 ?>A;54CNI8E 48035=5B8G5A:8E ?@5>1@07>20=89 8AE>4=>3> 25I5AB20. 60A?5@8BK >1@07>20;8AL 2 @57C;LB0B5 30;L<8@>;870 380;>:;0AB8G5A:>3> <0B5@80;0 2 ?@8ACBAB288 =57=0G8B5;L=>9 ?@8<5A8 :0@1>=0B=>3>. @8 D>@<8@>20=88 3>AA0=8B>2, :@><5 MB>3> >:8A;O;8AL AC;LD84K. #<1@8BK 2>7=8:0;8 2 :@>2;5 A;>52 3>AA0=8B>2 (8 460A?5@8B>2) 70 AG5B 48035=5B8G5A:>3> D@0:F8>=8@>20=8O 65;570 8 <0@30=F0. G5284=>, ?@>F5AA ?@52@0I5=8O <=>3>ABC?5=G0BK9. >2545=85 <=>38E :><?>=5=B>2 42>O:>: =01;N405BAO :0: 2K=>A, B0: 8 ?@82=>A, 2 7028A8<>AB8 >B AB0488 87<5=5=8O 8 <5=ONI8EAO D878:>-E8<8G5A:8E CA;>289 >:@C60NI59 A@54K. 0640O ABC?5=L 2 B>9 8;8 8=>9 <5@5 D8:A8@C5BAO 2 2845 <8=5@0;L=KE 0AA>F80F89. AA;54>20=8O 2K?>;=5=K ?@8 ?>445@6:5 $$ (3@0=B 02 05 64821). 8B5@0BC@0: 1.N?>20 . ., 5::5@ .  =0E>4:5 <0@ABC@8B0 2 C<1@8B0E #75;L38=A:>3> @C4=>3> ?>;O (.. #@0;). #@0;LA:89 35>;>38G5A:89 6C@=0;. 2001. !5(23). !.83 86. 2.0A;5==8:>2 .. !548<5=B>35=57, 30;L<8@>;87 8 M:>;>38O :>;G540=>=>A=KE ?0;5>384@>B5@<0;L=KE ?>;59 (=0 ?@8<5@5 .6=>3> #@0;0). 80AA: 5>BC@, 1999. 348A.  (""" ! #,! ' !" / (.+ # ) 15;>3C1 .., 22G0@>20 .!. 18= #@ , 3. 80AA, >AA8O, bel@imin.ac.ru; 256>75@=0O  , ?. 56o75@=K9, >AA8O 1Belogub E.V., 2Ovcharova E.S. Kronstedtite from Uzelga copper massive sulfide deposit (the South Urals). (1IMin UB RAS, Russia, 2Mezhozerniy GPC, Mezghozerniy, Russia). Kronstedtite (Fe2+3.93Fe3+1.88Ca0.09Mg0.05 Al0.04)5.99(Si2.31Fe3+1.69)4.00O10((OH)5.09O2.95)8.00 was found in the holes in pyrrothite ores from Uzelgas massive sulphide deposit as prysmatic, conic, barrel-like black crystals up to 34 sm in prolongation and 0.7 sm in section. It forms the beautiful radial growthing and single crystals, covered by siderite, fine pyrite, massive kronstedtite and hematite. Its Mooss hardness is 3.54. density 3.43 g/cm3, Nm( Ng = 1.720. Mineral is presented by the mixture of 2H1 and 2H2 politypes. Lattice constants indexed on orthogonal axes (): a= 5.510.01, b=9.540.02, c=14.220.02. Thermal behaviour and IR-spectrum are more similar to chlorite minerals like chamosite, then serpentine. This is the first description of kronstedtite from massive sulphide deposit. Its origin is connected with metamorphical disulfidisation of pyrrothite ores. #75;L38=A:>5 <54=>-F8=:>2>-:>;G540==>5 <5AB>@>645=85 @0A?>;>65==> 2 5@E=5C@0;LA:>< @C4=>< @09>=5, 2 1 :< : ! >B ?>A. 56>75@=K9 '5;O18=A:>9 >1;., 2 =0AB>OI55 2@5<O >B@010BK205BAO H0EB>9. C4K 70;530NB 2 <5B0A><0B8G5A:8 87<5=5==KE 40F8B0E.  A>AB025 @C4 ?@5>1;040NB ?8@8B, ?8@@>B8=, E0;L:>?8@8B, AD0;5@8B, 2AB@5G0NBAO 1;5:;0O @C40, <0@:078B, <5;L=8:>28B (3@5938B), 35<0B8B 8 4@. 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B. ! 4 ?@8 ?@>E>4:5 H0EBK. 8=5@0; 2AB@5G5= 2 2845 :@8AB0;;>2 C4;8=5==>3>, ?@87<0B8G5A:>3>, 1>G5=:>284=>3> 8;8 :>=CA>284=>3> >1;8:0 A >:@C3;>-87><5B@8G=K< A5G5=85<, 4>AB830NI8E 3 4 A< ?> C4;8=5=8N 8 1 7 << 2 ?>?5@5G=8:5. =8 >1@07CNB @0480;L=>-;CG8ABK5 8 ?0@0;;5;L=>-H5AB>20BK5 2K45;5=8O, A3CAB:8 A @07;8G=>9 >@85=B8@>2:>9 8=48284>2. @0=8 ?@87<0B8G5A:>3> ?>OA0 ?>:@KBK :><18=0F8>==>9 HB@8E>2:>9 ?0@0;;5;L=> C4;8=5=8N. 07>?8=0:>84 @0AI5?;5=. =5H=85 7>=K G0AB> A>45@60B 2@>AB:8 ?8@8B0 >:B0M4@8G5A:>3> 3018BCA0 @07<5@>< 0,n 1 <<. 0 :@>=HB54B8B =0@0AB05B <5;:89 ?8@8B, :>B>@K9 ?>:@K205BAO ;81> :@8?B>:@8AB0;;8G5A:8< ?;>B=K< 03@530B>< AB@C:BC@=> =5C?>@O4>G5==>3> :@>=HB54B8B0 (?), 35<0B8B0, ;81> :>@:>9 87 @><1>M4@8G5A:8E :@8AB0;;8:>2 75;5=>20B>-65;B>3> A845@8B0. 8@8B>2K5 8 A;82=K5  :@>=HB54B8B>2K5 8 35<0B8B>2K5 7>=K 8<5NB <>I=>ABL 0,2 0,3 << 8 <>3CB G5@54>20BLAO, >1@07CO 7>=0;L=K5 @C10H:8 2>:@C3 :@8AB0;;8G5A:>3> :@>=HB54B8B0. =5H=OO 8E ?>25@E=>ABL 8<55B A:>@;C?>20BK9 >1;8:, G0AB> ?>25@E=>ABL @0AA5G5=0 B@5I8=:0<8 A8=5@578A0. 564C 7>=0<8 8=>340 =01;N40NBAO ?@8AK?:8 ;8<>=8B0. !@>AB:8 :@>=HB54B8B0, ?>:@KBK5 ?8@8B>< 8 A845@8B><, @0A?>;030NBAO 2 ?CAB>B0E 2 4578=B53@8@>20==>9 @C45, 70?>;=5==KE @KE;K< G5@=K< ?>@>H:>20BK< <0B5@80;>< A A5@=8ABK< 70?0E><, 40NI8< =0 @5=B35=>3@0<<5 >A=>2=K5 >B@065=8O ?8@@>B8=0. 0 2>74CE5 ?8@@>B8= 1KAB@> >:8A;O5BAO 4> ?>@>H:>>1@07=>3> 35B8B0. 0:@>A:>?8G5A:8 :@>=HB54B8B G5@=K9, 2 B>=:8E >A:>;:0E 1C@>20B>-75;5=K9, G5@B0 1C@>20B>-75;5=0O. ?B8G5A:8 0=87>B@>?5=, C30A0=85 >B=>A8B5;L=> A?09=>AB8 ?@O<>5, AE5<0 04A>@1F88 >1@0B=0O, ?;5>E@>8@C5B >B B5<=>3> 1C@>20B>-75;5=>3> 4> 3CAB>3> 1C@>3>. Nm( Ng = 1,720. 7-70 >G5=L B5<=>3> F25B0 87<5@8BL Np =5 C40;>AL. ;>B=>ABL >?@545;5=0 C@02=>25H820=85< 75@=0 2 2>4=>< @0AB2>@5 684:>AB8 ;5@8G8 8 A>AB02;O5B 3,43 3/A<3. %8<8G5A:89 A>AB02 :@>=HB54B8B0, >?@545;5==K9 :;0AA8G5A:8< A?>A>1><, A;54CNI89 (<0A. %): SiO2 18,26; TiO2 <0,05; Al2O3 0,29; Fe2O3 37,45; FeO 31,11; MnO <0,01; MgO 0,25; CaO 0,67; Na2O 0,03; K2O 0,01; H2O+ 6,03; H2O 0,06; P2O5, CO2, S  =. >1=.;  100,16 (0=0;8B8:8 ..0=5520, ..0;O@5=>:, 8= #@ ). 0AG8B0==0O =0 10 :0B8>=>2 D>@<C;0 <8=5@0;0 =5 AB5E8><5B@8G=0: (Fe2+3,93Fe3+1,88Ca0,09Mg0,05 Al0,04)5,99(Si2,31Fe3+1,69)4,00O10((OH)5,09O2,95)8,00. 8A;>@>4 2:;NG5= 2 3@C??C 4>102>G=KE 0=8>=>2 =0 >A=>20=88 871KB:0 AC<<K ?>;>68B5;L=KE 70@O4>2. 8D@0:B>3@0<<0 C75;L38=A:>3> :@>=HB54B8B0 C4>2;5B2>@8B5;L=> A>>B25BAB2C5B ?@82545==>9 2 [3] 4;O ?>;8B8?0 2H1 A ?@8<5ALN 2H2. 0@0<5B@K M;5<5=B0@=>9 OG59:8 1K;8 @0AG8B0=K <5B>4>< =08<5=H8E :204@0B>2 4;O >@B>3>=0;L=>9 OG59:8 8 A>AB02;ONB (): a= 5,510,01; b=9,540,02; c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dyakiv@worldmailer.com Bornyak U.I., Dyakiv V.A. Stability of the organic-mineral aggregations of callstones under conditions in vitro (Ivan Franko National University of Lviv, Ukraine, dyakiv@worldmailer.com). Important questions of the biological mineralogy of gallstones have been considered: substances composition, morphology, microstructure and their evolution under condition in vitro. On the basis of biomineralogical and X-ray dVffractometry researches the presence of the insignificant changes, which do not influence stability of gallstones is proved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aCO3 (@><1. A8=3.), :0;LF8B  CaCO3 (B@83>=. 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[2, 3]. >A:>;L:C E>;5AB5@8= O2;O5BAO >A=>2=K< :><?>=5=B>< 2 25I5AB25==>< A>AB025 65;G=KE :0<=59, B> 53> A>45@60=85 8A?>;L7CNB 4;O :;0AA8D8:0F88 :>=:@5<5=B>2 [1,6]. %>;5AB5@8=>2K5 65;G=K5 :0<=8 3@C??K   A2KH5 70% E>;5AB5@8=0: G8AB> E>;5AB5@8=>2K5 :0<=8  99,2 99,4% E>;5AB5@8=0; :0@1>=0B-?83<5=B=K5-E>;5AB5@8=>2K5  77 95,9% E>;5AB5@8=0. !<5H0=K5 65;G=K5 :0<=8 3@C??K   20 70% E>;5AB5@8=0. 5;G=K5 :0<=8 3@C??K !  <5=LH5 20% E>;5AB5@8=0: :0@1>=0B-?83<5=B=K5 :0<=8  11,5 30,4% E>;5AB5@8=0. 5;G=K5 :0<=8 3@C??K D  :0<=8 A =87:8< A>45@60=85< E>;5AB5@8=0 8 2KA>:8< (13 42%) =5@0AB2>@8<>3> >AB0B:0: =5>@30=8G5A:85 :0<=8  A;54K 4,7% E>;5AB5@8=0. 7CG5=85 >A>15==>AB59 A>AB020 ?>72>;8;> A45;0BL 2K2>4K >1 CAB>9G82>AB8 65;G=KE :0<=59. 57C;LB0BK ?@>2545==KE =0<8 8AA;54>20=89 ?>:07K20NB 4><8=8@CNI55 ?@5>1;040=85 :0<=59 3@C??K  (B> 5ABL ?@58<CI5AB25==> E>;5AB5@8=>2KE). 83<5=B=K5 8 A<5H0==K5 :0<=8 2AB@5G0NBAO 7=0G8B5;L=> @565. AB@5G05<>ABL :0<=59 A :0@1>=0B=K< 8;8 D>AD0B=K< A>AB02>< =>A8B A?>@048G5A:89 E0@0:B5@. AE>4O 87 B>3> D0:B0, GB> E>;5AB5@8=>2K9 A>AB02=>9 :><?>=5=B :0<=59 ?@5>1;040; 2 1>;LH8=AB25 A;CG052, =0<8 ?@>2545=K =01;N45=8O 70 MB8<8 :0<=O<8 2 B5G5=85 4;8B5;L=>3> 2@5<5=8 (3 4 3>40). @>2545==K5 8AA;54>20=8O ?>:070;8, GB> 2 CA;>28OE 2=5H=59 A@54K 2 65;G=KE :0<=OE ?@>8AE>4OB >?@545;5==K5 =57=0G8B5;L=K5 87<5=5=8O. > A>45@60=8N :@8AB0;;870F8>==>9 2>4K 2K45;ONB <>=>384@0B 8 0=384@8B E>;5AB5@8=0 [4,5,7]. >=>384@0B E>;5AB5@8=0  C27H46O(H2O  B5@OO :@8AB0;;8G5A:CN 2>4C, ?5@5E>48B 2 0=384@8B E>;5AB5@8=0  C27H46O. "0:85 87<5=5=8O <>3CB ?@>8AE>48BL 8 2 >@30=87<5 G5;>25:0, 2 CA;>28OE, :>340 65;G=K5 :0<=8 2A;54AB285 @O40 ?@8G8= B5@ONB :>=B0:B A 65;GLN. -B> =5 2;8O5B =0 ?@>G=>AB=K5 E0@0:B5@8AB8:8 :0<=59. 7<5=5=8O, :>B>@K5 254CB : @0A?04C :0<=O, <>3CB ?@>8AE>48BL ?@8 =0;8G88 2 A>AB025 :0<=59 65;G=KE :8A;>B 8;8 A;>6=KE >@30=8G5A:8E A>548=5=89. 7 MB>3> A;54C5B, GB> 2 ?@5>1;040NI5< 1>;LH8=AB25 A;CG052 >@30=>-<8=5@0;L=K5 03@530BK 65;G=KE :0<=59 E>@>H> A>E@0=ONBAO 2 CA;>28OE in vitro 8 <>3CB 8A?>;L7>20BLAO 2 :0G5AB25 <8=5@0;>38G5A:8E M:A?>=0B>2 <C759=KE :>;;5:F89. 8B5@0BC@0: 1. 0=iB:528G /.. "8?8 6>2G528E E>;5AB5@8=>28E :>=:@5<5=Bi2 B0 45-O:i 70:>=><i@=>ABi iE D>@<C20==O // i:0@A. 71i@=. >2. A5@. L2i2, 1996. ".3. !.32 38. 2. C7C: $.. 5G>28==89 A:;04 6>2G528E :>=:@5<5=Bi2 // i=5@. 71. L2i2AL:. C=-BC. 1991. 8?.1. !.63 78. 3. >@03> .. 2545=85 2 18><8=5@0;>38N. !-1.: 54@0, 1992. 280A. 4. 02;>2AL:89 M.., 8 4@. 5=B5=>3@0DiG=i 4>A;i465==O 6>2G=8E :>=:@5<5=Bi2 // >?>2i4i  #:@0i=8. 1994. !9. !.154 158. 5. Craven B.M. Crystal structure of cholesterol monohydrate // Nature. V.260. ! 5553. P.727 729. 6. Iida M., 5.0. Gallstone classification and analysis of their constituents // Nippon. Rinsho. 1993. V.51. !7. P.1718 1724. 7.Shieh H.S., 5.0. Crystal structure of anhydrous cholesterol // J. Lipid Research, 1979. V.20. P.525 535. -!" !/ 257C280=0 A:0@=>2 8 @>48=38B>2 >@>28:>20 ... XE ">@>28:>20 ..." , C@06:>2A:0O .! XE "C@06:>2A:0O .!" ., ;D5@>20 .!. XE ";D5@>20 .!."  #, 3. >A:20, >AA8O, amurr@mail.ru Borovikova E.Yu., Kurazhkovskaya V.S., Alferova M.S. IR-Spectroscopy of skarn and rhodingite vesuvianites (MSU, Moscow, Russia). The new data on IR-specroscopy of low- and high-temperature vesuvianites are given. On the basis of IR-spectra skarn and rodingite ones are separated. Talnakh and Viluy vesuvianites occupy the intermediate site in spectra line. 57C280=  >@B>-48>@B>A8;8:0B A;>6=>3> A>AB020 A >1I59 AE5<0B8G5A:>9 D>@<C;>9 X19Y13Z18T0 5O68W10, 345 X  Ca 8 4@C385 :@C?=K5 :0B8>=K, 70?>;=ONI85 ?>78F88 A :>>@48=0F8>==K< G8A;><, @02=K< 8; Y  :0B8>=K, 70?>;=ONI85 >:B0M4@K 8 ?OB825@H8==8:8: Al, Mg, Fe, Ti 8 B.4.; Z  Si 2 B5B@0M4@0E; T  B 2 B@5C3>;L=8:0E 8 B5B@0M4@0E; W  OH 8;8 F [4]. 57C280=K, 2 7028A8<>AB8 >B C?>@O4>G5=8O 0B><>2 2 :0=0;0E AB@C:BC@K, <>3CB 8<5BL B@8 @07;8G=K5 ?@>AB@0=AB25==K5 3@C??K: P4/nnc, P4/n 8 P4nc [1, 2, 3]. KA>:>A8<<5B@8G=K5 @07=>284=>AB8 257C280=0 (?@. 3@. P4/nnc) >1@07CNBAO ?@8 B5<?5@0BC@0E 400 800C, =87:>A8<<5B@8G=K5  ?@8 B5<?5@0BC@0E <5=LH5 300(C. 5B>4>< -A?5:B@>A:>?88 1K;8 87CG5=K =5A:>;L:> >1@07F>2 257C280=0 87 A:0@=>2 "K@=K0C70, 8B:O@0=BK, 5@4OCH0, @>48=38B>2 065=>2:>3> <5AB>@>645=8O 8 E<0B>2A:>9 :>?8, 0 B0:65 >1@07FK 28;C8B0 A 8;N9A:>3> <5AB>@>645=8O 3@>AAC;O@0, 28;C8B0, 0EB0@0=48B0 8 257C280=0 87 @>48=38B878@>20==KE A:0@=>2 "0;=0E0. -A?5:B@K 2KA>:8E 8 =87:8E 257C280=>2 ?>4>1=K, >4=0:> 8<5NB A2>8 >B;8G8B5;L=K5 >A>15==>AB8, A2O70==K5 A 8E AB@C:BC@=K<8 @07;8G8O<8. @8 8AG57=>25=88 2 M;5<5=B0@=>9 OG59:5 AB@C:BC@K 25@B8:0;L=KE ?;>A:>AB59 A:>;L7OI53> >B@065=8O :0640O :@8AB0;;>3@0D8G5A:0O ?>78F8O @074208205BAO, =0?@8<5@: Z(1a) 8 Z(1b), Z(2a) 8 Z(2b) 8 B.4., 0 4;8=K A2O759 Si O 2 MB8E @0745;5==KE ?>78F8OE =5 >48=0:>2K [3]. 7<5=5=8O 2 AB@C:BC@5 >B@0605BAO 2 -A?5:B@0E. 07;8G8O  A?5:B@>2 2KA>:8E 8 =87:8E 257C280=>2 E>@>H> 70<5B=K 2 >1;0ABOE 0A8<<5B@8G=KE 20;5=B=KE 3 8 0A8<<5B@8G=KE 45D>@<0F8>==KE 4 :>;510=89. 0AI5?;5=85 :@8AB0;;>E8<8G5A:8E ?>78F89 ?@82>48B : @0AI5?;5=8N ?>;>A MB8E :>;510=89. KA>:>G0AB>B=0O ?>;>A0 3 :>;510=89 (990A< 1) A<5I05BAO 2 A?5:B@0E =87:8E 257C280=>2 =0 10 15A< 1 : 1>;55 =87:8< G0AB>B0<, ?> A@02=5=8N A> A?5:B@0<8 2KA>:8E 257C280=>2. =0 ;81> @0AH8@5=0, ;81> A>AB>8B 87 42CE 1;87:> @0A?>;>65==KE <0:A8<C<>2 980, 970 A< 1.  =87:>3;8=>75<8ABKE >1@07F0E @0AI5?;5=85 MB>9 ?>;>AK 4>AB8305B 15 20A< 1. 0AI5?;5=85 =87:>G0AB>B=>9 ?>;>AK 2 @09>=5 920A< 1 A>AB02;O5B >:>;> 30A< 1.  @57C;LB0B5 MB8E @0AI5?;5=89 8 A42830 A@54=8E =081>;55 8=B5=A82=KE ?>;>A 4@C3 : 4@C3C, @07=8F0 2 8E ?>;>65=88 ?>=8605BAO, ?> A@02=5=8N A 2KA>:8<8 257C280=0<8, ?@81;878B5;L=> =0 20 A< 1 8 A>AB02;O5B ( 50 A< 1. > 25;8G8=5 "3 A?5:B@K 2KA>:8E 8 =87:8E 257C280=>2 >BG5B;82> @07;8G0NBAO.  >1;0AB8 45D>@<0F8>==KE 4 :>;510=89 =87:>A8<<5B@8G=KE 257C280=>2 2KA>:>G0AB>B=0O ?>;>A0 640A< 1 ?@52@0I05BAO 2 ?;5G> 8, =0?@>B82, <0;>70<5B=0O 2 2KA>:8E 257C280=0E A@54=OO ?>;>A0 B@8?;5B0 2>7@0AB05B ?> 8=B5=A82=>AB8 8 =5<=>3> A<5I05BAO : 2KA>:8< G0AB>B0<. C1;5B ?>;>A @02=>9 8=B5=A82=>AB8 615, 585A< 1 O2;O5BAO >B;8G8B5;L=>9 G5@B>9 A?5:B@>2 =87:8E 257C280=>2.  >1;0AB8  :>;510=89 2KA>:85 8 =87:85 257C280=K B0:65 @07;8G0NBAO.  A?5:B@0E =87:8E 257C280=>2, :0: 2 ?>78F88 O(10), B0: 8 2 ?>78F8OE OH, =01;N40NBAO 1>;55 2KA>:>G0AB>B=K5 ?>;>AK ?> A@02=5=8N A 2KA>:>B5<?5@0BC@=K<8 @07=>284=>ABO<8, GB> 3>2>@8B > ?>=865==>< A>45@60=88 8>=>2 F [5,6]. > E0@0:B5@C -A?5:B@>2, 2A5 257C280=K A:0@=>2>3> ?@>8AE>645=8O <>6=> >B=5AB8 : 2KA>:>A8<<5B@8G=>9 @07=>284=>AB8, A?5:B@K >1@07F>2 87 @>48=38B>2 >4=>7=0G=> 3>2>@OB >1 8E =87:>9 A8<<5B@88. >;LH>9 8=B5@5A ?@54AB02;ONB -A?5:B@K >1@07F>2 28;C8B0 8 257C280=0 "0;=0E0.  >1;0AB8 20;5=B=KE 8 45D>@<0F8>==KE 0A8<<5B@8G=KE :>;510=89 >=8 ?>4>1=K A?5:B@0< 2KA>:>B5<?5@0BC@=>3> A:0@=>2>3> 257C280=0 A ?>2KH5==K< A>45@60=85< 1>;55 :@C?=KE, ?> A@02=5=8N A Al, :0B8>=>2 (Mg 8 Fe), GB> A>3;0AC5BAO A 40==K<8 >1 8E E8<8G5A:>< A>AB025. 48=AB25==K< <0;>70<5B=K< @07;8G85< O2;O5BAO =51>;LH>5 A1;865=85 42CE 2KA>:>G0AB>B=KE ?>;>A 3 :>;510=89.  >1;0AB8  :>;510=89 2 A?5:B@0E 28;N9A:>3> 257C280=0 =01;N405BAO >G5=L A;01K9 ?8: 3540A< 1, >B25G0NI89 A>G5B0=8N 2 A>A54=8E Y(2) 8 Y(3) >:B0M4@0E A>>B25BAB25==> :0B8>=>2 Al Mg 2 ?@8ACBAB288 F , GB> E0@0:B5@=> 4;O 2KA>:8E 257C280=>2. 0;0O 8=B5=A82=>ABL ?8:0 3>2>@8B > =51>;LH>< :>;8G5AB25 3@C?? , GB> A>3;0AC5BAO A ?@54;>65==>9 @>B>< AE5<>9 70<5I5=8O B + Mg = 2H + Al [4].  B0;=0EA:>< >1@07F5 2 >1;0AB8 :>;510=8O  -3@C?? =0@O4C A ?8:>< 3540A< 1 ?>O2;O5BAO E0@0:B5@=K9 4;O =87:8E 257C280=>2 ?8: :>;510=89 3610A< 1, A>>B25BAB2CNI89 A>G5B0=8N Al Al 2 >BACBAB285 8>=>2 F [5]. 10 ?8:0 8<5NB <0;CN 8=B5=A82=>ABL 87-70 ?@8ACBAB28O 7=0G8B5;L=>3> :>;8G5AB20 B.  B0;=0EA:8E, :0: 8 2 28;N9A:8E >1@07F0E =01;N40NBAO ?>;>AK :>;510=89 3@C?? [3] 8 [4]. > 40==K< E8<8G5A:>3> 0=0;870, 257C280= "0;=0E0 A>45@68B 4> 1,2 <0A.%F, GB> O2;O5BAO ?@><56CB>G=K< 7=0G5=85< ?> A@02=5=8N A 257C280=0<8 A:0@=>2 (4> 2 <0A. %) 8 @>48=38B>2 (4> 0,6<0A.%) [1,2]. ?8@0OAL =0 A?5:B@>A:>?8G5A:85 >A>15==>AB8 >A=>2=>9 >1;0AB8 A?5:B@0, <K >B=5A;8 MB8 257C280=K : ?@>AB@0=AB25==>9 3@C??5 P4/nnc. B0:, 40==K5 -A?5:B@>A:>?88, 2 >B;8G85 >B 48D@0:F8>==KE @5=B35=>2A:8E <5B>4>2, ?>72>;ONB 2K45;8BL 425 3@C??K 257C280=0: 2KA>:>B5<?5@0BC@=CN (A:0@=>2CN) 8 =87:>B5<?5@0BC@=CN (@>48=38B>2CN). %0@0:B5@=K<8 G5@B0<8 8 B>9 8 4@C3>9 3@C??K >1;040NB 28;N9A:85 8 B0;=0EA:85 >1@07FK, GB> ?>72>;O5B ?>AB028BL 2>?@>A >1 8E A?5F8D8G5A:>< ?@>8AE>645=88. 8B5@0BC@0: 1.Allen F.M., Burnham C.W. A comprensive structure  model for vesuvianite: symmetry valuations and crystal growth // Can. Min. 1992. V. 30. ! 1. P. 1 18. 2.Armburster T., Gnos E. P4/n and P4nc long  range ordering in low-temperature vesuvianites // Am. Min. 2000. V.85. ! 3 4. P.563 569. 3.Fitzgerald S. et al. Crystal structure of a non P4/nnc vesuvianite from Asbestos, Quebec // Am. Min. 1986. V.71. ! 11 12. P.1483 1488. 4.Groat L.A., Hawthorne F.C., Erict T.S. The chemistry of vesuvianite // Can. Min. 1992. V.30. ! 1. P. 19 48. 5. Groat L.A., et al. The infrared spectroscopy of vesuvianite in the OH region // Can. Min. 1995. V.33. ! 3. P.609 626. 6. Paluskiewich Cz., Zabinski W. H bearing in vesuvianite , a complex ortho-disilicate // Vibrational Spectroscopy. 1995. V. 8. P. 315 318. 0B@89! ) !!"+ !"  #% #  !" /  # (!   ,) @8B28= !.. XE "@8B28= !.." , >;5E>2A:89 ..!. XE ">;5E>2A:89 ..!."  !1#, 3. !.-5B5@1C@3, >AA8O,  HYPERLINK "mailto:sergey_britvin@mail.ru" sergey_britvin@mail.ru. #@0=>2>5 <5AB>@>645=85 0@:C @0A?>;>65=> =0 N3>-70?045 5A?C1;8:8 0@5;8O, 2 A525@>-2>AB>G=>9 G0AB8 @8;04>6LO [1]. <5I0NI85 C@0=>2>5 >@C45=5=85 ?>@>4K >B=>AOBAO : >A04>G=K< >1@07>20=8O< @8D5O  =86=59 ?>4A28B5 ?@8>75@A:>9 A28BK. 587<5=5==K5 M?835=5B8G5A:8<8 ?@>F5AA0<8 ?5AG0=8:8 8 3@025;8BK ?@54AB02;ONB A>1>9 ?A5D8B>2K5 8 ?A0<<8B>2K5 >B A5@>20B>-15652>3> 8 @>7>20B>-A25B;>-A5@>3> 4> B5<=>-A5@>3> F25B0 ?>@>4K, A;>65==K5 >:0B0==K<8 >1;><:0<8 :20@F0, 2 <5=LH59 AB5?5=8, ?>;52>3> H?0B0 A ?@58<CI5AB25==> 48::8B>2K< F5<5=B><. @><5 48::8B0, 2 ?>4G8=5==>< :>;8G5AB25 2 A>AB025 F5<5=B0 ?@8ACBAB2CNB :0>;8=8B 8 8;;8B. #@0=>2>5 >@C45=5=85, ?@54AB02;5==>5 =0ABC@0=>< 8 :>DD8=8B><, ?@8C@>G5=> : ?>4>H25 B>;I8 ?5AG0=8:>2 8 3@025;8B>2. @C45=5;K5 ?5AG0=8:8 8=B5=A82=> 384@>B5@<0;L=> ?5@5@01>B0=K A @0AB2>@5=85< :20@F0 8 70<5I5=85< E;>@8B>< :0>;8=8B-48::8B>2>3> F5<5=B0. 7 =5@C4=KE <8=5@0;>2 @0A?@>AB@0=5=K :20@F, :0;LF8B 8 Na-A>45@60I89 A;>8ABK9 A8;8:0B, 1;87:89 ?> AB5E8><5B@88 : E;>@8BC. -B>B  =5>1KG=K9 <8=5@0; G5@=>-75;5=>3>, G5@=>3> F25B0, A <0B>2K< 1;5A:><, O2;O5BAO >4=8< 87 3;02=KE :><?>=5=B>2 F5<5=B0 CG0AB:>2 @0728B8O C@0=>2>3> >@C45=5=8O. 5@2>=0G0;L=> >= ?@8=8<0;AO 70 E;>@8B, >4=0:> 40;L=59H85 <8:@>7>=4>2K5 8AA;54>20=8O 2KO28;8 ?@8ACBAB285 2 53> A>AB025 7=0G8B5;L=>3> :>;8G5AB20 =0B@8O (4> 3,5<0A.%Na2O). 8=5@0; >1@07C5B 03@530B=K5 A@0AB0=8O A :0;LF8B>< 8 B>=:>?;0AB8=G0BK< ?8@@>B8=><. 07<5@K G5HC9G0BKE 8=48284>2, A;030NI8E B0:85 03@530BK, =5 ?@52KH0NB 1<:<. 5=B35=>3@0<<0 ?>@>H:0 <8=5@0;0 8<55B AE>4AB2> A B0:>2>9 E;>@8B0, >4=0:> 1070;L=K9 @5D;5:A 14 ( E;>@8B>2K9 ) 4>AB8305B 14,5. >A;5 >1@01>B:8 MB8;5=3;8:>;5< 2 B5G5=85 2 G0A>2 48D@0:F8>==K5 <0:A8<C<K =0 @5=B35=>3@0<<5 8AG570NB, GB> A2845B5;LAB2C5B > @07@CH5=88 :@8AB0;;8G5A:>9 AB@C:BC@K 25I5AB20. > A>>B=>H5=8N FeO/MgO A>AB02 <8=5@0;0 87<5=O5BAO 2 H8@>:8E ?@545;0E, >B 0,3 4> 10, ?@8G5< :0:>9-;81> 70:>=><5@=>AB8 2 53> 20@80F8OE ?@>A;548BL =5 C40;>AL. >7<>6=>, 8<55B <5AB> @>AB>20O 7>=0;L=>ABL :@8AB0;;>2. A>15==>ABLN <8=5@0;0 O2;O5BAO 2KA>:0O ?>4286=>ABL 2 53> A>AB025 =0B@8O. "0:, ?@8 ?@83>B>2;5=88 ?@>7@0G=>-?>;8@>20==KE H;8D>2 ?> AB0=40@B=>9 <5B>48:5 (B.5. A 8A?>;L7>20=85< 2>4=KE ACA?5=789 01@0782>2) =0B@89 ?>GB8 ?>;=>ABLN 2K<K205BAO 87 <8=5@0;0, 2 A2O78 A G5< ?@8 40;L=59H5< <8:@>7>=4>2>< 8AA;54>20=88 A>7405BAO 8;;N78O ?@8ACBAB28O E;>@8B0. 4=0:> A?5F80;L=> ?@83>B>2;5==K5 (157 2>4K, A 8A?>;L7>20=85< :5@>A8=>2KE ACA?5=789 01@0782>2) ?@5?0@0BK 2KO2;ONB 2KA>:>5 A>45@60=85 =0B@8O. @C38< A2845B5;LAB2>< 2KA>:>9 ?>4286=>AB8 =0B@8O 2 <8=5@0;5 O2;O5BAO 53> 384@>;8B8G5A:>5 @07;>65=85 ?>4 2>7459AB285< 2;038 2>74CE0. >;8@>20==K5 0=H;8DK,  A25685 A?8;K 8 A:>;K ?>@>4 @C4=>3> 8=B5@20;0 2 B5G5=85 42CE-B@5E <5AOF52 ?>:@K20NBAO A=56=>-15;K<8 2KF25B0<8 8 AD5@>;8B0<8 B@>=K Na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lasov E.A., 1Ulyanov A.A., 2Mochalov A.G. Platinum-group element oxides from the placer of Ledyanoy stream, Koryakia, Russia (1MSU, Moscow, Russia, 2IGEM, Moscow, Russia). Two types of platinum-group elements (PGE) types of oxides were discovered in nuggets from the placer of Ledyanoy stream: Ir-Rh-Fe oxides containing variable amounts of oxygen (25 wt.%) and RuOsFe oxides with ca. 20 wt.% of oxygen. These phases occur either as inclusions in isoferroplatinum associated with tetraferroplatinum or as thin veins in kashinite. The PGE oxides may be crystallized with tetraferroplatinum or they are result of the alteration of early sulfides.  ?>A;54=85 3>4K 2 ;8B5@0BC@5 AB0;8 ?>O2;OBLAO 40==K5 > =0E>4:0E >:8A;>2 M;5<5=B>2 ?;0B8=>2>9 3@C??K (-).  >D8>;8B0E >2>9 0;54>=88 1K;8 2AB@5G5=K >:8A;K Pt Fe, Ir Fe Rh, Fe Rh Pt, Pt Ir Fe Rh, Ru Mn Fe [3]; 87 @>AAK?8 @. >=45@ >?8A0=K >:8A;K Pt Cu Fe, Pd Cu Fe; @565 2AB@5G0NBAO >:8A;K Os Ir Ru Fe 8 Ir Rh Fe [1]. >4>1=K5 D07K 1K;8 >1=0@C65=K =0<8 2 =5:>B>@KE 75@=0E H;8E>2>9 ?;0B8=K 87 @>AAK?8 @CG. 54O=>9. >AAK?L @CG. 54O=>9 ?@8C@>G5=0 : 0;L<>M=0=A:><C 7>=0;L=><C 4C=8B-:;8=>?8@>:A5=8B-3011@>2><C <0AA82C. ;02=K< :>@5==K< 8AB>G=8:>< <8=5@0;>2 ?;0B8=>2>9 3@C??K () @>AAK?59 O2;O5BAO <>I=>5 4C=8B>2>5 B5;> F5=B@0;L=>9 G0AB8 <0AA820. C=8BK 0;L<>M=0=A:>3> <0AA820 2 @07=>9 AB5?5=8 ?>425@3;8AL ?5@5:@8AB0;;870F8>==K< ?@>F5AA0<.  4C=8B0E >B<5G0NBAO =5>4=>:@0B=K5 =0E>4:8 87>D5@@>?;0B8=K, B5B@0D5@@>?;0B8=K 8 4@C38E , ?> 2A5< E0@0:B5@8AB8:0< A>>B25BAB2CNI8<  H;8E>2>9 ?;0B8=K @>AAK?59 [2]. @8 87CG5=88 H;8E>2>9 ?;0B8=K =0<8 1K;> 2K45;5=> 425 4><8=8@CNI85 0AA>F80F88 : 1) ?5@28G=0O, >1@07>20==0O B25@4K<8 @0AB2>@0<8 >A<8O, 8@848O 8 87>D5@@>?;0B8=>9; 2) 2B>@8G=0O, >1@07>20==0O, 2 >A=>2=><, B5B@0D5@@>?;0B8=>9, BC;0<8=8B>< 8 D07>9 Cu3Pt; ?@>8AE>645=85 2B>@8G=>9 0AA>F80F88 A2O70=> A ?@5>1@07>20=85< ?5@28G=KE . 7>D5@@>?;0B8=0 A;0305B >A=>2=CN <0AAC  H;8E>2>9 ?;0B8=K . 0: ?@028;>, >=0 =0E>48BAO 2 A@0AB0=8OE A E@><H?8=5;840<8. 565 2 87>D5@@>?;0B8=5 2AB@5G0NBAO 2:;NG5=8O >;828=0, A5@?5=B8=0, :;8=>?8@>:A5=0. ;O 87>D5@@>?;0B8=K E0@0:B5@=0 ?>AB>O==0O ?@8<5AL 8@848O (4> 9,9 <0A.%), B>340 :0: 4@C385 ?@8<5A=K5 ?;0B8=>84K ?@8ACBAB2CNB 2 7=0G8B5;L=> <5=LH8E :>;8G5AB20E.  87>D5@@>?;0B8=5 2AB@5G0NBAO <=>3>G8A;5==K5 2:;NG5=8O A0<>@>4=>3> >A<8O 8 A0<>@>4=>3> 8@848O, @565 2AB@5G0NBAO :0H8=8B, 7>=0;L=K5 :@8AB0;;K <8=5@0;>2 @O40 ;0C@8B M@;8E<0=8B. "C;0<8=8B, B5B@0D5@@>?;0B8=0 8 D070 Cu3Pt @072820NBAO 2 87>D5@@>?;0B8=5 ?> B@5I8=0<, >1@07CNB A;>6=K5 :09<K 2>:@C3 87>D5@@>?;0B8=K, ;81> ?>;=>ABLN 55 70<5I0NB. ! MB8<8 <8=5@0;0<8 0AA>F88@CNB 8@0@A8B, E>;;8=32>@B8B, A?5@@8;8B, @54:> 0@A5=84 @CB5=8O 8 M@;8E<0=8B.  87CG5==KE >1@07F0E H;8E>2>9 ?;0B8=K 2 @O45 75@5= =0<8 1K;8 4803=>AB8@>20=K >:8A;K Ir Rh Fe 8 Ru Os Fe. E8<8G5A:89 A>AB02 >:8A;>2 - >?@545;O;AO =0 M;5:B@>==>< <8:@>7>=45 CAMECA SX-50 A 2>;=>2K<8 A?5:B@><5B@0<8. 7<5@5=8O ?@>872>48;8AL 2 420 MB0?0: 1) - + Fe,Cu,Co,Ni,S,As (CA:>@ONI55 =0?@O65=85 20 :); 2)  (CA:>@ONI55 =0?@O65=85 10 :, B>: 30 nA).  :0G5AB25 MB0;>=>2 4;O  =0<8 8A?>;L7>20;8AL SnO2, MgO, Fe2O3 8 Cr2O3.  B01;8F5 ?@82>4OBAO A@54=85 7=0G5=8O  ?> G5BK@5< ?5@5G8A;5==K< AB0=40@B0<. @8 0=0;875 >:8A;>2 - CG8BK20;AO 04A>@18@>20==K9 >1@07F0<8 :8A;>@>4 8 =0 70:;NG8B5;L=>< MB0?5 @0AG5B0 22>48;0AL ?>?@02:0, A>AB02;ONI0O 0,5 <0A.%. "01;8F0 %8<8G5A:85 A>AB02K >:8A;>2 - (<0A.%). (Chemical compositions of platinum-group element oxides) NPtIrOsRuRhPdCuNiFeS0 A@.!C<<010,9464,150,000,1618,460,100,680,096,760,174,796,2520,9465,020,000,0718,290,080,600,186,450,145,296,9630,7858,040,000,0522,170,070,640,0611,150,164,497,5541,6864,830,000,1218,010,000,650,086,860,153,996,2950,0054,050,000,1122,000,220,530,2218,140,032,397,6260,0257,940,000,1320,860,000,500,1716,270,002,698,5170,732,7515,1756,901,680,170,240,145,310,0218,6101,6782,882,7314,6256,881,710,000,140,313,320,0217,499,98@8<5G0=85. CAMECA SX-50; 0=0;8B8: >=>=:>20 .. XE ">=>=:>20 .."  0==K5 >:8A=K5 D07K E0@0:B5@87CNBAO =87:>9 >B@060B5;L=>9 A?>A>1=>ABLN 8 4>AB0B>G=> E>@>H> 4803=>AB8@CNBAO 2 >1@07F0E H;8E>2>9 ?;0B8=K. 0: ?@028;>, 2K45;5=8O >:8A;>2 - ?@8C@>G5=K : B@5I8=0< 2 87>D5@@>?;0B8=5 8 : 3@0=8F0< <8=5@0;L=KE D07. :A84 Ir Rh Fe @0728205BAO 2 2845 ?@>68;:>2 ?> :0H8=8BC, >1@07C5B 2:;NG5=8O 2 87>D5@@>?;0B8=5 ;81> A@0AB0=8O A ?>@8AB>9 B5B@0D5@@>?;0B8=>9 @07<5@>< 4> 150 200<:<. 0==0O D070 E0@0:B5@87C5BAO =5@02=><5@=K< A>45@60=85< 65;570 8 :8A;>@>40. :A84 Ru Os Fe 1K; 2AB@5G5= 2 2845 2:;NG5=89 2 87>D5@@>?;0B8=5 @07<5@>< 4> 100 <:< 8, ?> A@02=5=8N A Ir Rh Fe >:8A;0<8, >= A>45@68B ACI5AB25==> 1>;LH5 :8A;>@>40.  >1I5<, 4;O 40==KE D07 E0@0:B5@=K =51>;LH85 ?@8<5A8 Cu 8 Ni, 2 @O45 A;CG052 D8:A8@CNBAO ?@8<5A8 V 8 Mn (4> 0,2 <0A.%). >=865==K5 0=0;8B8G5A:85 AC<<K E8<8G5A:8E 0=0;87>2 >:8A;>2 -, ?> =0H5<C <=5=8N, <>3CB A2845B5;LAB2>20BL > =0;8G88 2 =8E () 8;8 2. 1@07>20=85 >?8A0==KE >:8A;>2 ?@>8AE>48;>, 25@>OB=>, =0 AB0488 70<5I5=8O @0==59 87>D5@@>?;0B8=K 1>;55 ?>74=59 0AA>F80F859 BC;0<8=8B0, B5B@0D5@@>?;0B8=K 8 B.?. 2 CA;>28OE ?>2KH5==>9 DC38B82=>AB8 :8A;>@>40. :8A;K - >1@07>2K20;8 A0<>AB>OB5;L=K5 2K45;5=8O A B5B@0D5@@>?;0B8=>9, B0: 8 70<5I0;8 1>;55 @0==85 AC;LD84K: :0H8=8B 8 <8=5@0;K @O40 ;0C@8B-M@;8E<0=8B. @54?>;>65=85 > 70<5I5=88 :0H8=8B0 Ir Rh Fe >:8A;0<8 ?>4B25@6405BAO 1;87:8<8 >B=>H5=8O<8 Ir/Rh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uge T., Legendre O. Platinum-group element oxides from the Pirogues ofiolitic mineralization, New Caledonia: origin and significance // Econ. Geol., 1994. V.89. P. 1454 1468.  '! !!" ""  & " $' ! (.+ # ) 0;8520 . . XE "0;8520 . ."  =AB8BCB 35>;>388 #& , 3. #D0, >AA8O, ig@anrb.ru Galieva A.R. Mineralogical features of metabasites of metamorphic complex of Beloretsk, the South Urals (Institute of Geology USC RAS, Ufa, Russia). In this paper garnets from eclogites and amphibolites of the metamorphic complex of Beloretsk, SW Urals are described. 5;>@5F:89 <5B0<>@D8G5A:89 :><?;5:A () A;>65= @8D59A:8<8 >B;>65=8O<8, <5B0<>@D87>20==K<8 2 ?>74=525=4A:>5 2@5<O 8 2:;NG0NI8<8 2 A51O <5B01078BK, <5B0?5;8BK 8 <5B0<>@D87>20==K5 :0@1>=0B=K5 ?>@>4K 2 A>>B=>H5=88 1:6:3. 5B01078BK ?@54AB02;5=K M:;>38B0<8 8 3@0=0B>2K<8 0<D81>;8B0<8 2 =86=5@8D59A:>< O@CA5, 3@0=0B>2K<8 8 1573@0=0B>2K<8 0<D81>;8B0<8 2 A@54=5@8D59A:>< 8 25@E=5@8D59A:>< O@CA0E. 8=5@0;K 3@C??K 3@0=0B0 O2;ONBAO >4=8<8 87 =081>;55 E0@0:B5@=KE 8 206=KE <8=5@0;>2 2A5E <5B0<>@D8G5A:8E >1@07>20=89, 2:;NG0O M:;>38BK.  3@0=0B0E, ?> <5@5 =0@0AB0=8O C@>2=O <5B0<>@D87<0, >1KG=> C25;8G8205BAO A>45@60=85 <03=8O 8 C<5=LH05BAO 65;578AB>ABL, B.5. 3@0=0BK <>3CB A;C68BL :@8B5@85< 4;O 2KO2;5=8O B5@<>48=0<8G5A:8E CA;>289 D>@<8@>20=8O B5E 8;8 8=KE <5B0<>@D8G5A:8E :><?;5:A>2 [1,4]. @0=0BK 2  O2;ONBAO ?>@>4>>1@07CNI8<8 <8=5@0;0<8 M:;>38B>2, 3@0=0B>2KE 0<D81>;8B>2 8 3@0=0BA>45@60I8E @07=>AB59 :@8AB0;;8G5A:8E A;0=F52 8 ?@54AB02;5=K ?>@D8@>1;0AB>2K<8 2K45;5=8O<8 @07<5@>< 4> 1 2 << 2 480<5B@5 2 M:;>38B0E 8 4> 5 6 << 2 3@0=0B>2KE 0<D81>;8B0E. B=>A8B5;L=>5 A>45@60=85 3@0=0B>2 2 ?>@>40E :>;51;5BAO 2 7028A8<>AB8 >B ?0@035=578A>2. ;O M:;>38B>2 8 0<D81>;8B>2 >=> 87<5=O5BAO >B 20 4> 45% (2 :@8AB0;;8G5A:8E A;0=F0E >B 5 4> 25%) [2]. 5B>4>< @5=B35=>-A?5:B@0;L=>3> 0=0;870 2 ?@>7@0G=KE ?>;8@>20==KE H;8D0E =0 M;5:B@>==>< <8:@>0=0;870B>@5 JXA-8900 RWD =0<8 2 5>;>38G5A:>< 8=AB8BCB5 59=A:>-5ABD0;LA:>9 "5E=8G5A:>9 KAH59 H:>;K (3. 0E5=, 5@<0=8O) 1K;8 45B0;L=> 8AA;54>20=K 3@0=0BK 87 M:;>38B>2 8 3@0=0B>2KE 0<D81>;8B>2 15;>@5F:>3> :><?;5:A0. K;8 2K?>;=5=K <=>3>G8A;5==K5 <8:@>7>=4>2K5 0=0;87K 3@0=0B>2 2 A;CG09=KE B>G:0E 8 >:>;> 40 ?@>D8;59 G5@57 25AL :@8AB0;;. %8<8G5A:85 0=0;87K <8=5@0;>2 ?5@5AG8BK20;8AL =0 :@8AB0;;>E8<8G5A:85 D>@<C;K ?> >1KG=><C :8A;>@>4=><C <5B>4C [3]. A5 87CG5==K5 :@8AB0;;K 3@0=0B>2 >:070;8AL 2 B>9 8;8 8=>9 AB5?5=8 7>=0;L=K 8 ?@54AB02;5=K, 2 >A=>2=><, 0;L<0=48=>< (43 57%) A ?>4G8=5==K< A>45@60=85< ?8@>?>2>3> (14 27%), 3@>AAC;O@>2>3> 8 A?5AA0@B8=>2>3> :><?>=5=B>2. 0 <8:@>7>=4>2KE ?@>D8;OE (@8A.) ?>:070=> 87<5=5=85 A>AB02>2 3@0=0B>2 >B F5=B@0 : :@0N. A>15==>AB8 @0A?@545;5=8O :><?>=5=B>2 2 3@0=0B0E 87 M:;>38B>2 70:;NG0NBAO 2 B><, GB> 2 F5=B@0;L=KE G0ABOE 75@5= >B<5G0NBAO =57=0G8B5;L=K5 :>;510=8O 2 A>45@60=88 :><?>=5=B>2.  ?5@8D5@88 75@5= A>45@60=8O CaO 8 FeO C<5=LH0NBAO, 0 MgO  C25;8G8205BAO. !>45@60=8O F5;>< A>AB02;ONB >B 1,18 4> 8,27%, CaO  >B 13,84 4> 5,02%, FeO  >B 34,26 4> 20,30%. 0 :>=F5=B@0F8>==>9 :@82>9 @0A?@545;5=8O Ca =5B @57:> 2K@065==KE ?5@5381>2, >=0 8<55B 1>;55 ?;02=K5 >G5@B0=8O, 2 :@052KE G0ABOE :@8AB0;;0 >B<5G05BAO =57=0G8B5;L=>5 C25;8G5=85 A>45@60=8O :0;LF8O. !;54>20B5;L=>, 3@0=0BK <5B01078B>2  >1;040NB 2 >A=>2=>< ?@>AB>9, 0 2 =5:>B>@KE A;CG0OE A;>6=>9 D>@<>9 E8<8G5A:>9 7>=0;L=>AB8, :>B>@0O <>65B 1KBL >1JOA=5=0 ;8HL :@8AB0;;870F859 3@0=0B>2 =5 2 >48=, 0 2 420 MB0?0 <5B0<>@D87<0, B.5. <>6=> A45;0BL 2K2>4 > ?@>O2;5=88, ?> <5=LH59 <5@5, 42CE MB0?>2 548=>3> F8:;0 <5B0<>@D87<0 2 87CG05<>< @09>=5.  @57C;LB0B5 ?@>3@04=>3> <5B0<>@D87<0 >1@07>20;8AL M:;>38BK 8 3@0=0B>2K5 0<D81>;8BK, 0 2 @5B@>3@04=K9 MB0? <5B0<>@D87<0 ?@>8AE>48;8 =57025@H5==K5 ?@5>1@07>20=8O M:;>38B>2 A >1@07>20=85< 0?>M:;>38B>2KE 0<D81>;8B>2; MB><C MB0?C 8 A>>B25BAB2CNB =01;N40NI85AO 87@54:0 M;5<5=BK @53@5AA82=>9 7>=0;L=>AB8 2 C7:8E :@052KE >B>@>G:0E 3@0=0B0. 8B5@0BC@0: 1.2G5=:> .. 5B@>35=5B8G5A:0O 8=D>@<0B82=>ABL 3@0=0B>2 <5B0<>@D8G5A:8E ?>@>4. .: 0C:0, 1982. 103A. 2.;5:A552 .., ;5:A5520 .. >2K9 @09>= @0728B8O M:;>38B>2 =0 70?04=>< A:;>=5 .6=>3> #@0;0 // >:;.  !!! , 1979. ".248. !3. !.702 706. 3.C;0E .. XE "C;0E .."  C:>2>4AB2> 8 B01;8FK 4;O @0AG5B0 D>@<C; <8=5@0;>2. .: 54@0, 1982. 144A. 4.>1@5F>2 .., 8 4@. $0F88 <5B0<>@D87<0. .: 54@0, 1970. 432A.  !/  &/  ,! # / 1@8F5=:> ..., 1!?8@84>=>2 -.., 25;O:>2 !.., 2C;03>2 -.., 2!5@540 .. 1#, >A:20, 2   >@8;LA:89 =8:5;L 1Gritsenko J.D., 1Spiridonov E.M., 2Belakov S.N., 2Kulagov E.A., 2 Sereda E.V. Arsenides mineralisation of Norilsk region (1MSU Moscow, 2 RAS  Norilsk nickel ). Arsenides mineralisation of Norilsk region has been studied, the parameters of formation of this mineralisation have been determined and its genetic relation has been established. @>O2;5=8O Ni-Co-0@A5=84=>9 <8=5@0;870F88 2 >@8;LA:>< @C4=>< ?>;5 (0@A5=84=>-:0@1>=0B=K5 68;K A AC;LD840<8 Zn, Cu, Pb, Cd, Sb 8 ?>4G8=5==K<8 0=B8<>=840<8, A5:CI85 AC;LD84=K5 Cu-Ni @C4K, 8 2:@0?;5==>ABL 0@A5=84>2 2 MB8E @C40E) 8725AB=K 1>;55 50 ;5B; AG8B0;>AL, GB> MB>  384@>B5@<0;8BK, 7025@H0NI85 B@0??>2CN D>@<0F8N [1], [2]. 0<8 CB>G=5=K 35=5B8G5A:85 A2O78 40==>9 <8=5@0;870F88, 55 A>AB02 8 ?0@0<5B@K D>@<8@>20=8O. A5 ?@>872>4=K5 B@0??>2>9 D>@<0F88 P2 T1 >AB>G=>-!818@A:>9 ?;0BD>@<K  1070;LBK 8 BCDK ?>:@>2=>9 D0F88, 1070;LBK 8 4>;5@8BK 65@;>28= 8 A8;;>2, 3011@>84K 8=B@C782>2, <03<0B8G5A:85 AC;LD84=K5 Cu-Ni-Co 8 A:0@=>2K5 Fe @C4K, 2>7@0AB :>B>@KE 245(5 <;=. ;5B, 70E20G5=K M?835=5B8G=K< =87:>3@04=K< <5B0<>@D87<><. "@5=4 @538>=0;L=>3> <5B0<>@D87<0: 1 AB048O 2 CA;>28OE =87:>B5<?5@0BC@=>9 G0AB8 F5>;8B>2>9 D0F88 (232 196 <;=. ;5B); 2 AB048O 2 CA;>28OE 2KA>:>B5<?5@0BC@=>9 G0AB8 F5>;8B>2>9 D0F88 4> ?@5=8B-?C<?5;;88B>2>9 D0F88 (184 164 <;=. ;5B); 3 AB048O 2 CA;>28OE >B 2KA>:>B5<?5@0BC@=>9 4> =081>;55 =87:>B5<?5@0BC@=>9 G0AB8 F5>;8B>2>9 D0F88 (164 122 <;=. ;5B) [3]. @>O2;5=0 :;0AA8G5A:0O ?5B;O .. 5@GC:0. Rb/Sr 2>7@0AB 0?>D8;;8B0 0@A5=84=>-:0@1>=0B=KE 68; >@8;LA:>3> @C4=>3> ?>;O A2845B5;LAB2C5B >1 8E A2O78 A 3 AB04859 =87:>3@04=>3> <5B0<>@D87<0  0@A5=84=0O <8=5@0;870F8O <>;>65 B@0??>2>9 D>@<0F88 =0 90 100 <;=. ;5B. "5<?5@0BC@0 8 402;5=85, >?@545;5==K5 ?> 8=48284C0;L=K< D;N84=K< 2:;NG5=8O<, 0 2 :0;LF8B5  ?> 0@A5=84=>9 <8=5@0;870F88: >B 0,9 0,5 4> 0,1 :10@ 8 216 203 181 175 172 147 127 114(!, A>>B25BAB2CNB ?0@0<5B@0< D>@<8@>20=8O F5>;8B>2>9 D0F88. 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K45;ONBAO 425 @07=>284=>AB8 0;<070 A @57:> @07;8G0NI8<8AO A2>9AB20<8: 0;<07, A;030NI89 F5=B@0;L=CN G0ABL :@8AB0;;>2  ?@>7@0G=K9, 15AF25B=K9 >:B0M4@, 8 0;<07 ?5@8D5@89=>9 >1;0AB8, >1@07CNI89 <CB=CN, =5?@>7@0G=CN >1>;>G:C. @8AB0;;K 0;<070 ?5@2>3> B8?0, ?>-2848<><C, >B=>AOBAO : I @07=>284=>AB8 ?> :;0AA8D8:0F88 @;>20 8 : B8?C I2 ?> D878G5A:>9 :;0AA8D8:0F88. ;<07=>5 25I5AB2> >1>;>G5: <>6=> >B=5AB8 : III @07=>284=>AB8 ?> :;0AA8D8:0F88 @;>20. 0 >A=>20=88 ?@>2545==KE 8AA;54>20=89 ?@54;>65= <5E0=87< >1@07>20=8O 8AA;54C5<KE :@8AB0;;>2. >?>;=8B5;L=K5 07>B=K5 45D5:BK 2 0;<070E !@54=53> "8<0=0 8 4@C38E @538>=>2 >AA88 A05=:> !.. XE "A05=:> !.."  =AB8BCB 35>;>388 ><8 & #@ , 3. !K:BK2:0@, >AA8O, isaenko@geo.komisc.ru Isaenko S.I.Additional nitrogen defects in diamonds of Middle Timan and other regions of Russia. (Institute of Geology of Komi SC of Ural Division of RAN, Syktyvkar, Russia). The information about concentrations of N3-defects and specific composition of impurity additional nitrogen defects of nature diamonds from Ichetju placer (Middle Timan region), from placer of Krasnovisherskiy district (Permskaya region), from kimberlite pipes in the name of M.V.Lomonosov (Arhangelskiy region) and in the name of 23 Party Congress of KPSU (Saha region) are presented. The distinction of studied diamonds by character of distribution of N3-defects and by frequency of systems of nitrogen defects  N3, H3, H4, S1 are shown. Based on results of experiments and statistical data handling it is proposed that H4-system can be an indicator of postcrystallization transformation of diamonds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he saturation by N3-defects and division of spectra of photoluminescence (80 K) of diamonds by specifical composition of defects 5AB>@>645=85>;-2> >1@07F>280?07>=K (225@EC) 8 A@54=85 (2=87C) :>=F5=B@0F89 N3-45D5:B>2, 1017A< 3'0AB>B0 2AB@5G05<>AB8 A8AB5< 07>B=KE 45D5:B>2, %N3H3H4S1G5BJN 99EMBED Equation.39327120"@C1:0 8<. %%III 0@BAJ5740 !! 33EMBED Equation.3100309"@C1:0 8<. ..><>=>A>20 16EMBED Equation.36319019@0A=>28H5@A:85 @>AAK?814EMBED Equation.310021708B5@0BC@0: 1.NB>52.. XE "NB>52 .." , ;CE>2..., A05=:>!.. XE "A05=:> !.."  -?835==K5 07>B=K5 45D5:BK 8 <5B0;;8G5A:85 ?;5=:8 =0 ?>25@E=>AB8 0;<07>2 !@54=53> "8<0=0 // >:;. , 2000. ".375. !2. !.229 232. 2.NB>52 .., ;CE>2 ..., A05=:> !.. 048>35==K5 4-45D5:BK :0: ?@87=0: M?835==>3> 2=5<0=B89=>3> ?@>8AE>645=8O <5B0;;8G5A:8E ?;5=>: =0 ?>25@E=>AB8 0;<07>2 !@54=53> "8<0=0 // ;<07K 8 0;<07>=>A=>ABL8 "8<0=>-#@0;LA:>3> @538>=0. !K:BK2:0@: 5>?@8=B, 2001. !.153 155. 3.Isaenko S.I., Glukhov Y.V., Lutoev V.P. Structural H4-defects with Indications of Radiation Genesis // Abstracts of  Mineralogy and Spectroscopy: 4th European Conference , Paris, France / Bull.Liaison S.F.M.C, v.13, p.81 82. 8=5@0;L=K9 A>AB02 @538>=0;L=>9 8 7>=0;L=>9 ?>:@KH5: 25@E=53> 452>=0 "8<0=>-5G>@A:>9 ?@>28=F88 AB><8=0 .. XE "AB><8=0 .." , >9;> -.. XE ">9;> -.."  !1#, 3. !0=:B-5B5@1C@3, >AA8O, goilo@eg5812.spb.edu Istomina I.M., Goilo E.A. Mineral composition of regional and zonal seals of Higher Devonian of the Timan-Pechora province (SPbSU, Saint-Petersburg, Russia). 29 samples from regional and zonal Devonian seals of the Timan-Pechora region have been investigated by X-ray methods. X-ray phase analysis of silt (0,010,005mm) and clay (<0,002mm) fraction shows that all fractions are the polymineral mixtures of mica, kaolinite, chlorite, mixed layered phase (mica-smectite), quarts with admixture NaCa feldspars, some samples contain also calcite, dolomite, pyrite and siderite. The changes in symmetry and shape of 001 reflection of mica before and after saturation by glycol point on the increasing of smectite content in mixed layered phase in the deeper parts of the section of the regional seal and eastwards for the zonal seal. This fact is supposed to be conditioned by the means and ways of the hydrocarbon migration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a-Ca ?>;52KE H?0B>2, ?8@8B0 8 A845@8B0. @><5 B>3>, 2> 2A5E ?@>10E 7>=0;L=>9 ?>:@KH:8 8 2 2-E ?@>10E 87 25@E=59 G0AB8 @538>=0;L=>9 ?>:@KH:8 >B<5G5=K 7=0G8B5;L=K5 :>;8G5AB20 :0;LF8B0. > 2A5E >1@07F0E  @5?5@0  ?@8ACBAB2C5B 4>;><8B. !;N40 4803=>AB8@>20;0AL ?> d001=10,01 8 d002=4,98. !>>B=>H5=85 8=B5=A82=>AB59 MB8E ?8:>2 ?>72>;8;> >B=5AB8 55 : 48>:B0M4@8G5A:8< A;N40< A 45D8F8B>< <56A;>52KE :0B8>=>2 (0,65). %;>@8B E>@>H> >?@545;O;AO ?> @5D;5:A0< A d001=14,18, d003=4,47 8 d004=3,54. 803=>AB8:0 :0>;8=8B0 2 ?@8ACBAB288 E;>@8B0 70B@C4=O;0AL ?5@5:@KB85< 8E @5D;5:A>2 2 >1;0AB8 <0;KE C3;>2 2(, 345 2 (001) =14,38 :0>;8=8B0 8 2 (002) =14,52 E;>@8B0 ?@0:B8G5A:8 ?>;=>ABLN A>2?040;8.  MB>< A;CG05, :0>;8=8B CAB0=02;820;AO ?> @5D;5:AC 002 A 2 =29,02, :>B>@K9 >BG5B;82> >B45;O;AO >B 004 A 2=29,26 E;>@8B0 ?@8 AJ5<:5 =0 !>( 87;CG5=88. 5C?>@O4>G5==0O A<5H0=>A;>9=0O D070 A;N40-A<5:B8B 4803=>AB8@>20;0AL ?> =0;8G8N =5:@0B=KE 7=0G5=89 d 00L 8 0A8<<5B@88 ?@>D8;O @5D;5:A>2 00L, :>B>@0O >F5=820;0AL :0: >B=>H5=85 H8@8=K ;52>3> ?;5G0 ?8:0, 87<5@5==0O =0 ?>;C2KA>B5, : H8@8=5 ?@02>3>. >A;5 =0AKI5=8O >1@07F0 MB8;5=3;8:>;5< 0A8<<5B@8O @5D;5:A0 001 A<5H0=>A;>9=>9 D07K ?>O2;O;0AL =0 4@C3>9 AB>@>=5 ?8:0, 0 53> d C<5=LH0;>AL >B 10,01 4> 9,95, GB> ?>72>;8;> >?@545;8BL 2 =59 A>45@60=85 =01CE0NI59 :><?>=5=BK ((5 10%). 8: d100=4,25 :20@F0 2A5340 ?@8ACBAB2>20; =0 48D@0:B>3@0<<0E 8 A;C68; 2=CB@5==8< MB0;>=><, B>340 :0: 53> 1>;55 8=B5=A82=K9 <0:A8<C< A d101=3,34 >1KG=> ?5@5:@K20;AO A8;L=K< >B@065=85< 003 A;N4K 8 =5 8A?>;L7>20;AO 2 40;L=59H8E @0AG5B0E. Na-Ca ?>;52K5 H?0BK 1K;8 CAB0=>2;5=K ?> =0;8G8N @5D;5:A0 A d=3,20, :0;LF8B  ?> d102=3,85 8 d104=3,03, 4>;><8B  ?> d104=2,89, ?8@8B  ?> d200=2,71, 0 A845@8B  ?> d104=2,79. 1@0I05B =0 A51O 2=8<0=85 87<5=5=85 0A8<<5B@88 1070;L=KE @5D;5:A>2 A<5H0=>A;>9=>9 D07K, 0, A;54>20B5;L=>, 8 A>45@60=8O ?5@5A;0820NI8EAO A;N4O=>9 8 A<5:B8B>2>9 :><?>=5=B ?> @07@57C 8 ?;>I048 ?>:@KH5:. F5=:0 0A8<<5B@88 8 25;8G8=K A<5I5=8O ?8:0 A d=10,1 4> 8 ?>A;5 =0AKI5=8O ?@5?0@0B0 MB8;5=3;8:>;5< >?@545;5==> C:07K20;0 =0 C25;8G5=85 A>45@60=8O A<5:B8B0 2 A<5H0=>A;>9=>9 D075 =0 3;C18=C ?> @07@57C B8<0=A:>-A0@3052A:>9 ?>:@KH:8, 0 B0:65 =0 53> 1>;55 2KA>:>5 A>45@60=85 2 ?5;8B>2>9 D@0:F88, G5< 0;52@8B>2>9. #25;8G5=85 A<5:B8B>2>9 :><?>=5=BK 2 =081>;55 B>=:>9 D@0:F88 E>@>H> >1JOA=O5BAO 1>;55 1KAB@K< ?@5>1@07>20=85< 48A?5@A=>9 A;N4K 2 A<5:B8B 70 AG5B 2>7@>AH59 ?>25@E=>AB8 55 G0AB8F. !0<> 65 >1@07>20=85 A<5:B8B0 <>65B 1KBL 8=8F88@>20=> 87<5=5=85< >:8A;8B5;L=>-2>AAB0=>28B5;L=KE CA;>289 D>@<8@>20=8O >A04>G=>9 ?>@>4K. 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G5284=>, GB> G5< 2KH5 D;N84>C?>@=K5 A2>9AB20 ?>:@KH:8 8, A;54>20B5;L=>, =865 A:>@>AB8 <83@0F88 #, B5< @57G5 1C45B =0@0AB0BL A>45@60=85 =01CE0NI59 :><?>=5=BK =0 3;C18=C, 8 B5< :>=B@0AB=55 1C45B A>AB02 >1@07F>2 2 25@E=59 8 =86=59 G0AB8 ?>:@KH:8. >=OB=>, GB> AB5?5=L B@0=AD>@<0F88 3;8=8ABKE <8=5@0;>2 >B@0605B =5 B>;L:> 25@B8:0;L=CN, => 8 ;0B5@0;L=CN <83@0F8N #. F5=:0 0A8<<5B@88 ?8:0 001 A;N4K 4;O >1@07F>2 7>=0;L=>9 ?>:@KH:8 ?> ?;>I048 2KO28;0 C25;8G5=85 A>45@60=8O A<5:B8B0 2 A<5H0=>A;>9=>9 D075 2 =0?@02;5=88 A 70?040 =0 2>AB>:, GB>, 25@>OB=>, A2845B5;LAB2C5B > ?>ABC?;5=88 # A 2>AB>:0.  F5;><, >BACBAB285 2 >1@07F0E A<5:B8B0 :0: A0<>AB>OB5;L=>9 D07K 8 2KA>:>5 A>45@60=85 :0>;8=8B0 A2845B5;LAB2CNB A:>@55 >1 C4>2;5B2>@8B5;L=KE M:@0=8@CNI8E :0G5AB20E B8<0=A:>-A0@3052A:>9 ?>:@KH:8. ;O  @5?5@0  E0@0:B5@=K 1>;55 =87:85 A>45@60=8O :0>;8=8B0 8 2KA>:85 A>45@60=8O A;N4K. !;54>20B5;L=>, M:@0=8@CNI85 A2>9AB20 7>=0;L=>9 ?>:@KH:8 ;CGH5 @538>=0;L=>9, >=8 2>7@0AB0NB 2 2>AB>G=>< =0?@02;5=88, C:07K20O =0 >B=>A8B5;L=>5 C;CGH5=85 ?>B5=F80;L=KE :0G5AB2 ?@8@>4=>3> @575@2C0@0. 01>B0 2K?>;=5=0 ?@8 ?>445@6:5 ?@>3@0<<K #=825@A8B5BK >AA88 (?@>5:B !0867). 2B>@K 2K@060NB 1;03>40@=>ABL :.3.<.=. ..>268:>2C 70 ?>;57=>5 >1AC645=85 @57C;LB0B>2 @01>BK. 8B5@0BC@0: 1 >9;> -., !0?530 .$., =4@5520 .. 8=5@0;K 3;8= ?5;8B>2>9 D@0:F88 4>==KE >A04:>2 >;LA:>3> 70;820 8 0@5=F520 <>@O // , 2001. !2. !.101 111. 2.>9;> -.., >B>2 .., "C52 .. -:A?5@8<5=B0;L=0O 384@>A4N4870F8O 3;8=8ABKE <8=5@0;>2 2 ?@8ACBAB288 >@30=8G5A:8E :8A;>B //  A1. @8AB0;;>E8<8O 8 AB@C:BC@=K5 >A>15==>AB8 <8=5@0;>2. .: 0C:0, 1976. !.53 61. $;N>@8B>20O <8=5@0;870F8O 2 8725AB=O:0E C@02;520 ;>30 87 >:@5AB=>AB59 ?. 8A8< 0=>=5@>2 . . 86=5B038;LA:89 3>AC40@AB25==K9 <C759-70?>254=8: >@=>702>4A:>3> 45;0 !@54=53> #@0;0, >AA8O, museum@museum.unets.ru Kanonerov A.A. Fluorite mineralisation in limestones of the Zhuravleov ravine around of the settlement of Visim (Nizhny Tagil State Museum-reserve of Mining and Metallurgy in the Middle Urals. Nizhny Tagil, Russia). The discription of calcite veins in the middle Devonian dolomitized limestones containing fluorite and fossils is given. I5 14-;5B=8< H:>;L=8:>< A 8H59 (0@>2K< <K 32>745< 8;8 =>68G:>< 2K:>2K@820;8 D8>;5B>2K5 ?@>7@0G=K5 :0<5H:8 87 15;KE 68; ?@O<> 2 :@CB>< 15@53C @O4>< A 8A8<A:>9 H:>;>9 !7, 345 8 CG8;8AL. >:07K20O A2>8 C4828B5;L=K5 =0E>4:8 CG8B5;O<, <K B0: 8 =5 ?>;CG8;8 >B25B0, GB> MB>. ">;L:> G5@57 30 ;5B 701@>A8;0 <5=O AC4L10 2 @>4=K5 :@0O 4;O ?>8A:>2 40==>3> <8=5@0;0, >:0702H53>AO D;N>@8B>< (@8AC=>:). 0;LF8B>2K5 68;K A D;N>@8B>< =0945=K 2 2KE>40E 4>;><8B878@>20==KE 8725AB=O:>2. 5>;>38G5A:0O ?>78F8O: 452>= A@54=89 (D2) A 2AB@5G0NI59AO D0C=>9 Favosites, Athryi a ex gr. Reticularis L. [4]. 725AB=O:8 8 4>;><8BK A@54=53> 452>=0, 2 >1I5<, 154=K D0C=>9, :>B>@0O : B><C 65 >B;8G05BAO 8 25AL<0 ?;>E>9 A>E@0==>ABLN. B;>65=8O A@54=53> 452>=0 87CG0;8AL <=>38<8 8AA;54>20B5;O<8: .. 5;;5@>< (1876 3.), .. (BC:5=15@3>< (1890 3.), .. @0A=>?>;LA:8< (1887 1889 33.), .. /:>2;52K< (1906 3.), ?>74=55 .. $@545@8:A>< (1932 3.), => =8:B> 87 =8E =5 >B<5G05B =0E>4>: D;N>@8B0. 0?04=55 =0 :>=B0:B5 A :20@F8B0<8 2 4>;8=5 @5: 5652>9 #B:8 8 (09B0=:8 ;568B H8@>:0O ?>;>A0 8725AB=O:>2, 2 :>B>@>9 .. @0A=>?>;LA:8< 1K;0 :>=AB0B8@>20=0 A8;C@89A:0O D0C=0: 25@E=89 >B45; (S2) Calamopora fibrosa Gold f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ig. 1 Geological circuit of the area of the settlement of Visim (on materials of Frederiks G., Kuznetsov E.A., Kruglov M., is simplified with additions of the author. M 1:200 000). !@54=89 452>= (D2): 8725AB=O:8, 4>;><8BK 5@E=89 !8;C@  86=89 52>= (S2D1): 3;8=8ABK5, 8725AB:>2>-3;8=8ABK5, C3;8AB>-:@5<=8ABK5, ?5AG0=8:8 :20@F52K5, 8725AB=O:8 !8;C@ 5@E=89 >B45; (S2): 8725AB=O:8, 3;8=8ABK5 A;0=FK, ?5AG0=8:8 @4>28: 86=89 >B45; "5;L?>AA:0O A28B0 (O1tl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yanigp@mail.ru; 2, 3.>A:20, >AA8O, pkara@igem.ru 1Kotelnikov D.D., 1Zinchuk N.N., 2Gorshkov A.I. First find lizardite-saponite mixed-layers formation of from kimberlite of one kimberlite piper in south africa (1IANIGP CNIGRI, Mirny, Russia; 2IGEM, Moscow, Russia). In upper part of orebody of one kimberlite pipe marked similar regulated lizardite-saponite mixed-layers formation. Layers of lizardite-saponite is haracterized by large densite than above and bellow diposite kimberlite layers. It determine slow transform protomineral lizardite to stage of regulated mixed-layers formation only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~15 @071CE0NI8E A;>52. -B8 A;>8 2 AB@C:BC@5 @0AA<0B@8205<>3> A<5H0=>A;>9=>3> >1@07>20=8O A>45@60BAO, ?> 40==K< $C@L5-0=0;870, 2 A>>B=>H5=88 52:48. =B5=A82=0O ?>;>A0 ?>3;>I5=8O 45D>@<0F8>==KE :>;510=89 Si-O-Mg(Fe2+)VI  A2O78 A G0AB>B>9 443 460 A< 1 2 -A?5:B@5 >1@07F0 C:07K205B =0 B@8>:B0M4@8G5A:89 B8? A;>52, 2E>4OI8E 2 AB@C:BC@C A<5H0=>A;>9=>3> >1@07>20=8O, :>B>@>5 A>>B25BAB2C5B ;870@48B-A0?>=8BC. !C4O ?> =0;8G8N =0 48D@0:B>3@0<<0E ?>A;54>20B5;L=>AB8 >B@065=89 >B 7,28  (7,28; 3,62 & ) 2 :8<15@;8B0E A>45@68BAO B0:65 A>1AB25==> ;870@48B A ?0@0<5B@>< b, @02=K<, ?> M;5:B@>=>3@0D8G5A:8< 40==K<, 9,23 .  >1@07F5 ?@8ACBAB2C5B, :@><5 B>3>, =57=0G8B5;L=0O ?@8<5AL A0?>=8B0 (A;01K9 @5D;5:A ~15,5 , 7=0G5=85 :>B>@>3> C25;8G8205BAO 4> 16,9 8 17,8  A>>B25BAB25==>, ?>A;5 =0AKI5=8O >1@07F0 MB8;5=3;8:>;5< 8;8 3;8F5@8=><. "@8>:B0M4@8G5A:89 B8? 2A5E @0AA<>B@5==KE 2KH5 A;>8ABKE <8=5@0;>2 ?>4G5@:8205BAO 40==K<8 E8<8G5A:>3> A>AB020 D@0:F88 <5;LG5 0,001 << (2 %): SiO2  38,81; TiO2  0,17; Al2O3  1,75; Fe2O3  6,00; FeO  1,55; MnO  0,093; MgO  30,50; CaO  0,97; Na2O  0,13; K2O  0,073; H2O  3,30; H2O+  16,10; P2O5  0,11; Ni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g  21, Si  18,1, Al  1,17, Fe  1, Ca ~0,2, Na ~ 0,1. !;54C5B >B<5B8BL, GB> CAB0=>2;5=85 D>@<C;K A<5H0=>A;>9=>3> <8=5@0;0 A>?@>2>640;>AL >?@545;5==K<8 B@C4=>ABO<8. -B> A2O70=> A ?@8ACBAB285< 2 >1@07F5 2 2845 8=48284C0;L=>9 D07K A>1AB25==> ;870@48B0. >MB><C A=0G0;0 ?> 48D@0:B>3@0<<0< (A 8A?>;L7>20=85< :>MDD8F85=B>2 .8A:09O) 1K;> CAB0=>2;5=>, GB> ;870@48B0 2 >1@07F5 2 1,17 @07 1>;LH5, G5< A<5H0=>A;>9=>9 D07K. =0;87 ?>;CG5==>3> E8<8G5A:>3> A>AB020 MB8E 42CE 3;02=59H8E <8=5@0;>2 ?>:070;, GB> >1I8< 4;O =8E M;5<5=B>< O2;O5BAO Mg. -B> ?>72>;8;> 70?8A0BL A;54CNICN ?@>?>@F8N: [Mg(3x1,17=3,5)]-;870@48B+[Mg3-;870@48B+(Mg,Fe)3-A0?>=8B]  A<5H0=>A;>9=>5 >1@07>20=85. !C<<0 Ng+Fe @02=0 9,51. K;> A45;0=> 4>?CI5=85, GB> =081>;LH55 :>;8G5AB2> Fe, 0 B0:65 l 2E>48B 2 AB@C:BC@C A0?>=8B0. 0;55 >?@545;O;>AL 7=0G5=85 :>MDD8F85=B0 Mg+Fe=22:9,51=2,313. !>3;0A=> MB><C :>MDD8F85=BC >F5=820;>AL :>;8G5AB2> Mg 8 A2O70==>3> A =8< Si 2 A2>1>4=>< ;870@48B5. AB0;L=>9 Mg 8 A2O70==K5 A =8< Si, Fe 8 Al @0A?@545;O;8AL 2 AB@C:BC@=KE :><?>=5=B0E ;870@48B>2>9 8 A0?>=8B>2>9 G0AB59 A<5H0=>A;>9=>3> >1@07>20=8O. 3> D>@<C;0 2 2845 42CE :><?>=5=B>2 A A>>B=>H5=85<  & , ?>MB><C 70?8AK205BAO (157 CG5B0 E8<8G5A:8E M;5<5=B>2 <5;:8E ?@8<5A=KE D07) 2 A;54CNI5< 2845: (Mg3Si2)[Ca0,25(Mg2,6Fe0,4)(Si3,5Al0,5)O15(OH)6]nH2O. 0 >A=>20=88 MB>9 D>@<C;K 1K;0 ?>AB@>5=0 :@8AB0;;>E8<8G5A:0O <>45;L ;870@48B-A0?>=8B0, 345 ?> =>@<0;8 : A;>O< C?>@O4>G5==> G5@54CNBAO 1:1 A;>8 ;870@48B0 8 2:1  A0?>=8B0, @0745;5==K5 <56A;>52K<8 ?@><56CB:0<8 @07=>3> B8?0. @82545==K5 40==K5 ?>:07K20NB, GB> 70;530NI85 2 =86=59 G0AB8 87CG5==>3> @07@570 ?>@>4K 02B>;8B>2>9 :8<15@;8B>2>9 1@5:G88 8 ?5@5:@K20NI85 8E 2C;:0=>35==>->A04>G=K5 >1@07>20=8O ACI5AB25==> @07;8G0NBAO ?> >A>15==>ABO< A;>8ABKE <8=5@0;>2.  =86=59 G0AB8 ?@58<CI5AB25==> ;870@48B, :>B>@K9 (2> D@0:F88 <5;LG5 0,001 <<) 2 >B45;L=KE ?@>A;>OE =5 A>45@68B ?@8<5A8 4@C38E 48A?5@A8>==KE D07.  1>;LH59 65 G0AB8 MB>9 B>;I8 ;870@48B 0AA>F88@C5B A A0?>=8B><.  25@E0E B>;I8 02B>;8B>2>9 :8<15@;8B>2>9 1@5:G88 ;870@48B A>45@68BAO A>2<5AB=> A C?>@O4>G5==K< ;870@48B-A0?>=8B>2K< A<5H0=>A;>9=K< >1@07>20=85<.  >B;8G85 >B MB>3>, 2 >B;>65=8OE 2C;:0=>35==>->A04>G=>9 B>;I8 ?@8ACBAB2C5B 2 >A=>2=>< A0?>=8B c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i-A>45@60I85 <03=578>D>9B8B 8 4@028B 5@57>2A:>3> 7>;>B>@C4=>3> <5AB>@>645=8O, !@54=89 #@0; C4@O2F520 .. XE "C4@O2F520 .." , 0:H552 . XE "0:H552 ." . XE "0:H552 .."  #, >A:20, >AA8O, mineral@geol.msu.ru Kudryavzeva O.E. Baksheev I.A. Nickeloan magnesiofoitite and dravite from the Berezovskoe gold deposit, Central Urals (Moscow State University, Moscow, Russia). Nickeloan magnesiofoitite and dravite from veins related to the propylite-type talc-carbonate alteration within the Berezovskoye Au deposit, Central Urals are described. Ni contents reach 0,53 apfu. High Ni content in tourmaline and associated talc indicate high fO2 during mineralizing process.  ?@545;0E 5@57>2A:>3> 7>;>B>@C4=>3> <5AB>@>645=8O (!@54=89 #@0;) 2 @09>=5 CG0AB:0 #A?5=A:0O 3>@:0 2 <03=578B-:20@F52>9 68;5, A>?@O65==>9 A B0;L:-:0@1>=0B=K<8 <5B0A><0B8B0<8 ?@>?8;8B>2>9 D>@<0F88, =0<8 CAB0=>2;5= Ni-A>45@60I89 BC@<0;8= 2 0AA>F80F88 A =8:5;8ABK< B0;L:><. 8;0 4;8=>9 4> 20 < 8 <>I=>ABLN 2 @074C20E 4> =5A:>;L:8E <5B@>2 A>3;0A=> 70;5305B A@548 35<0B8B-B0;L:-<03=578B>2KE <5B0A><0B8B>2. > 40==K< 87CG5=8O 8=48284C0;L=KE ?5@28G=KE D;N84=KE 2:;NG5=89 2 :20@F5, 68;0 D>@<8@>20;0AL ?@8 B5<?5@0BC@0E 330 290(! (2 A@54=5< 310(!). 8:5;8ABK9 B0;L: A;0305B 3=5740 2 :20@F5 480<5B@>< 4> 5 A< 8 >1@07C5B A ?>A;54=8< 8=4C:F8>==K5 ?>25@E=>AB8 A>2<5AB=>3> @>AB0. !>45@60=8O =8:5;O A>AB02;ONB 10 11 <0A.% NiO. 03=578B A;0305B :@8AB0;;K @07<5@>< 4> =5A:>;L:8E A< 8, ?>4>1=> B0;L:C, >1@07C5B A :20@F5< 8=4C:F8>==K5 ?>25@E=>AB8 A>2<5AB=>3> @>AB0. 7-70 A8;L=KE 38?5@35==KE ?@5>1@07>20=89 45B0;L=> 87CG8BL E8<8G5A:89 A>AB02 <8=5@0;0 =52>7<>6=>. "C@<0;8= A>AB02;O5B >:>;> 5% >1J5<0 68;K, 53> A:>?;5=8O 2 >A=>2=>< ?@8C@>G5=K : 70;L10=40<, => >= B0:65 @0728B 8 2 >AB0;L=>< >1J5<5 68;K. 8=5@0; ?@54AB02;5= B5<=>-75;5=K<8 B>=:>-83>;LG0BK<8 :@8AB0;;0<8 4;8=>9 4> 1A<, 0 B0:65 8E 03@530B0<8, >1@07C5B 8=4C:F8>==K5 ?>25@E=>AB8 A>2<5AB=>3> @>AB0 A :20@F5< 8 2:;NG5=8O 2 =5<. > 40==K< <8:@>7>=4>2KE 0=0;87>2, BC@<0;8= ?@54AB02;5= 42C<O <8=5@0;L=K<8 2840<8 <03=578>D>9B8B>< 8 4@028B><. @8AB0;;K BC@<0;8=0 8=>340 >?B8G5A:8 7>=0;L=K 8 A5:B>@80;L=K. @8AB0;;K 7>=0;L=K 8 ?> E8<8G5A:><C A>AB02C. >;55 @0==89 <03=578>D>9B8B-I A;0305B O45@=K5 G0AB8 :@8AB0;;>2, E0@0:B5@87C5BAO =87:8<8 A>45@60=8O<8 Na (0,44 D.5.) 8 Ni (0,06 0,07 D.5.). @028B-I A;0305B ?@><56CB>G=K5 8 :@052K5 7>=K MB8E 65 :@8AB0;;>2, :>;8G5AB2> Na 2 =5< 20@L8@C5B >B 0,78 4> 0,90 D.5., A>45@60=8O Ni 87<5=ONBAO 2 ?@545;0E 0,07 0,35 D.5. "0:65 4@028B-I >1@07C5B 8=48284C0;L=K5 =57>=0;L=K5 :@8AB0;;K, E0@0:B5@87CNI85AO ?>2KH5==K< A>45@60=85< Cr (5,07 11,77 <0A.% Cr2O3), A>45@60=8O Ni A>AB02;ONB 0,05 0,17 D.5. >;55 ?>74=89 <03=578>D>9B8B-II A;0305B F5=B@0;L=K5 G0AB8 >?B8G5A:8 =57>=0;L=KE :@8AB0;;>2 8 >B;8G05BAO 2KA>:8< A>45@60=85< Ni (0,43 D.5.). @028B-II A;0305B :@052K5 7>=K MB8E :@8AB0;;>2 8 E0@0:B5@87C5BAO A>45@60=85< Na 8 Ni 0,59 D.5. 8 0,53 D.5., A>>B25BAB25==>.  F5;>< ?> E8<8G5A:><C A>AB02C 87CG5==K5 BC@<0;8=K 20@L8@CNB >B Cr-A>45@60I53> <03=578>D>9B8B0 8 Cr-Ni-A>45@60I53> <03=578>D>9B8B0 4> Cr-A>45@60I53> 4@028B0 8 Cr-Ni-A>45@60I53> 4@028B0. =8 E0@0:B5@87CNBAO =87:8< >B=>H5=85< Ca/(Ca+Na), 87<5=ONI8<AO >B 0 4> 2,2%. 5;578AB>ABL (Fe(/(Fe(+Mg)) 20@L8@C5B 2 H8@>:8E ?@545;0E: >B 10,1 4> 35,9%. 4=0:>, A;54C5B >B<5B8BL, GB> D83C@0B82=0O B>G:0 4;O =081>;55 2KA>:>65;578AB>3> BC@<0;8=0 =0 B@5C3>;L=8:5 Fe Al Mg ;568B =865 ;8=88 H5@; 4@028B (@8AC=>:) GB>, 25@>OB=>, A2845B5;LAB2C5B >1 >1>30I5==>AB8 <8=5@0;0 Fe3+. -B> ?>4B25@6405BAO 40==K<8 A?5:B@>A:>?8G5A:8E 8AA;54>20=89 CA@54=5==>9 ?@>1K BC@<0;8=0: 1>;LH0O G0ABL 65;570 =0E>48BAO 2 B@5E20;5=B=>9 D>@<5 Fe3+/Fe((I.=0,53. 0;8G85 :@8AB0;;>2 BC@<0;8=0, ?> :@09=59 <5@5, 42CE 35=5@0F89, 0 B0:65 7>=0;L=>ABL ?> E8<8G5A:><C A>AB02C, A2845B5;LAB2CNB >1 8E D>@<8@>20=88 2 B5G5=85 =5A:>;L:8E 8<?C;LA>2 384@>B5@<0;L=>9 45OB5;L=>AB8. KA>:>5 A>45@60=85 Cr 8 Fe 2 =5:>B>@KE :@8AB0;;0E <>65B 1KBL >1CA;>2;5=> 70<5I5=85< BC@<0;8=>< E@><H?8=5;84>2. 0@035=5B8G5A:0O 0AA>F80F8O BC@<0;8=0 A 35<0B8B>< 8 Ni-B0;L:><, 0 B0:65 >1>30I5==>ABL 53> Fe3+ 8 Ni A2845B5;LAB2CNB > 25AL<0 2KA>:>9 fO2 ?@8 >1@07>20=88 <8=5@0;0. 0;8G85 <03=578>D>9B8B0, 25@>OB=>, C:07K205B =0 =87:CN 25;8G8=C pH <8=5@0;>>1@07CNI8E D;N84>2. 87:>5 >B=>H5=85 Ca/(Ca+Na) 8 ?0@035=57 A :0@1>=0B>< A2845B5;LAB2C5B > 2KA>:>9 fCO2 2 <8=5@0;>>1@07CNI8E @0AB2>@0E. "C@<0;8=K #A?5=A:>9 3>@:8 ?@54AB02;ONB 8=B5@5A, B0: :0: 2KO2;5==K5 2KA>:85 A>45@60=8O 2 =8E =8:5;O (4> 0,53 D.5.) ACI5AB25==> @0AH8@ONB ?@54AB02;5=8O > :@8AB0;;>E8<88 <8=5@0;0. >2K5 40==K5 > E8<8G5A:>< A>AB025 BC@<0;8=0 8 0AA>F88@CNI8E <8=5@0;>2 87 <5AB>@>645=89 #@0;LA:8E 7C<@C4=KE >?59 1C4@O2F520 .., 1$8@A>20 .., 10:H552 .., 2>?>2 .. 1#, >A:20, >AA8O mineral@geol.msu.ru; 2#, :0B5@8=1C@3, >AA8O 1Kudryavzeva O.E., 1Firsova N.P., 1Baksheev I.A., 2Popov M.P. New data on chemistry of tourmalines and associated minerals from the Emerald Mines, Central Urals (1Moscow State University, Moscow, Russia; USGGA, Ekaterinburg, Russia) Tourmalines from the Emerald Mines are oxy-, fluor- and hydroxy-dravites. They are zoned by fluor contents which increase from crystal cores to rims. Tourmalines have been formed at 450550oC. 0<8 87CG5=K BC@<0;8=K 87 @07;8G=KE <8=5@0;L=KE 0AA>F80F89 <5AB>@>645=89 #@0;LA:8E 7C<@C4=KE >?59. >=B0:B A;N48B>2 8 E@><8B8B>2. "C@<0;8= >1@07C5B A@>AB:8 B>=:>-83>;LG0BKE 75;5=KE 8 A25B;>-:>@8G=52KE :@8AB0;;>2 @07<5@>< 4> 4 <<. 8=5@0; 0AA>F88@C5B A F-A>45@60I8< ?0@03>=8B>< (0,94 1,26 <0A.% F) 8 DB>@-D;>3>?8B>< (6,20 6,46 <0A.% F). $;>3>?8B :@09=5 =87:>65;578ABK9; 65;578AB>ABL [f=Fe/(Fe+Mg)] A>AB02;O5B 0,4 0,7%. > E8<8G5A:><C A>AB02C BC@<0;8=K 20@L8@CNB >B 15765;578AB>3> 4> 25AL<0 =87:>65;578AB>3> (f 1,2%) DB>@-4@028B0, A>45@60=85 Ni 0,1 0,4 <0A.%. NiO, >B=>H5=85 C0/(Na+Ca) A>AB02;O5B 1,0 22,8%. 7CG5==K5 4@028BK ACI5AB25==> @07;8G0NBAO ?> A>45@60=8N Cr: 1,1 3,4 <0A.% Cr2O3 2 75;5=>< 8 0,8 1,3 <0A.% Cr2O3 2 A25B;>-:>@8G=52><. "5<?5@0BC@0 D>@<8@>20=8O 0AA>F80F88, >F5=5==0O ?> 18>B8B-BC@<0;8=>2><C B5@<><5B@C [1], A>AB02;O5B 4500!. 7C<@C4>=>A=K5 A;N48BK A;>65=K <5;:>G5HC9G0BK< D;>3>?8B><, BC@<0;8=><, =57=0G8B5;L=K< :>;8G5AB2>< ?;038>:;070 8 4@C38E <8=5@0;>2. $;>3>?8B A;0305B 75;5=>20B>-A5@K5 4> 1C@>20B>-:>@8G=52KE G5HC9:8 @07<5@>< 4> 1 <<. > E8<8G5A:><C A>AB02C MB> 65;578ABK9 (f 12,4 24,9%), ?@0:B8G5A:8 157B8B0=8ABK9 DB>@A>45@60I89 D;>3>?8B (3,43 3,74 <0A.% F). "C@<0;8= A;0305B G5@=K5 :@8AB0;;K 4;8=>9 0,5 2,5 A<. @8AB0;;K 1@5:G8@>20=K 8 ?> B@5I8=0< 70<5I0NBAO 03@530B0<8 ?;038>:;070, :20@F0, @CB8;0 8 AC;LD84>2. > E8<8G5A:><C A>AB02C MB> >:A8-, DB>@- 8 384@>:A8; 4@028B A f 17,4 27,7%, A>45@60I89 Ti (4> 1,3 <0A.% "iO2) 8 =5 A>45@60I89 Cr 8 Ni, >B=>H5=85 Ca/(Ca+Na) 2KA>:>5 14,9 39,0%. !>45@60=85 F (<0A. %) 2>7@0AB05B >B F5=B@0 :@8AB0;;>2 : :@0N >B 0 1,2 4> 0,2 1,5. "5<?5@0BC@0 D>@<8@>20=8O 0AA>F80F88, >F5=5==0O ?> 18>B8B-BC@<0;8=>2><C B5@<><5B@C [1], A>AB02;O5B 470(!. $;>3>?8B-E;>@8B>2K5 <5B0A><0B8BK A;>65=K 7>;>B8AB>-1C@K< <5;:>?;0AB8=G0BK< 03@530B>< D;>3>?8B0 8 E;>@8B0 8 :@8AB0;;0<8 BC@<0;8=0. "C@<0;8= >1@07C5B =51>;LH85 G5@=K5 8 B5<=>-1C@K5 :@8AB0;;K 4;8=>9 4> 15 <<, >1KG=> 2 3 << 8 8E A@>AB:8. > E8<8G5A:><C A>AB02C MB> 65;578ABK9 4@028B (f 17,1 28,5%), A>45@60=85 Ti A>AB02;O5B 0,8 1,2 <0A.% TiO2, A>45@60=8O Cr 8 Ni =57=0G8B5;L=K, >B=>H5=85 Ca/(Ca+Na)  24,6 28,5%. @8AB0;;K A;01>7>=0;L=K ?> E8<8G5A:><C A>AB02C: >B F5=B@0 : :@0N =5A:>;L:> C25;8G8205BAO 65;578AB>ABL. ;L18B-0<D81>;-BC@<0;8=>2K5 <5B0A><0B8BK A;>65=K 03@530B>< 0<D81>;0, 0;L18B0 8 BC@<0;8=0. <D81>; ?@54AB02;5= 0:B8=>;8B>2>9 @>3>2>9 >1<0=:>9 (Al D.5. 0,91, f 15,3%), A;030NI59 2:;NG5=8O 2 BC@<0;8=5, 8 <03=578>-3>@=1;5=48B>< (Al D.5. 2,30, f 25,7%), >1@07CNI8< B5A=K5 A@0AB0=8O A BC@<0;8=><. ;L18B (!07 9) >1@07C5B <5;:85 75@=0 2 >A=>2=>9 <0AA5 ?>@>4K. "C@<0;8= A;0305B B5<=>-:>@8G=52K5 >?B8G5A:8 7>=0;L=K5 :@8AB0;;K @07<5@>< 4> 1A<. > E8<8G5A:><C A>AB02C  MB> DB>@A>45@60I89 384@>:A8;-4@028B A (f 15,3 22,0%), A>45@60=8O Cr, Ni 8 Ti =57=0G8B5;L=K. 8=5@0; 7>=0;5= ?> E8<8G5A:><C A>AB02C: >B F5=B@0 : :@0N :@8AB0;;>2 C25;8G8205BAO A>45@60=85 F (<0A.%) 8 >B=>H5=85 Ca/(Ca+Na): >B 0 0,04 4> 0,20 0,30 8 >B 11,2 22,0% 4> 21,7 27,9% A>>B25BAB25==>. "C@<0;8=-<0@30@8B>2K5 <5B0A><0B8BK A D;>3>?8B><. 0@30@8B ?@54AB02;5= <5;:8<8 15AF25B=K<8 G5HC9:0<8. %8<8G5A:89 A>AB02 <8=5@0;0 (D.5.): (!00,75 0,98Na0,11 0,17K0,00 0,04)0,91 1,09(Al1,89 1,96 Mg0,02 0,24Fe0,01 0,12)1,98 1,99[Al1,36 1,94Si2,04 2,11O10](OH1,13 1,78F0,20 0,27O0,00 0,07)2,00, f 30,2 44,7%. "C@<0;8= >1@07C5B B5<=>-:>@8G=52K5 C4;8=5==K5 :@8AB0;;K @07<5@>< 4> 0,5 A<. > E8<8G5A:><C A>AB02C  MB> DB>@-4@028B A f 18,6 29,0%, A>45@60=8O Ti, Cr 8 Ni 2 =5< =57=0G8B5;L=K. 8=5@0; 7>=0;5= ?> E8<8G5A:><C A>AB02C. B F5=B@0 :@8AB0;;0 : :@0N C<5=LH05BAO f >B 22,0 29,0% 4> 20,5 24,8% 8 2>7@0AB0NB A>45@60=8O F (<0A.%) 8 >B=>H5=85 Ca/(Ca+Na) >B 0,7 0,9 4> 0,9 1,5 8 >B 5,5 11,5% 4> 6,4 12,4% A>>B25BAB25==>. "5<?5@0BC@0 D>@<8@>20=8O 0AA>F80F88, >F5=5==0O ?> 18>B8B-BC@<0;8=>2><C B5@<><5B@C [1], A>AB02;O5B 550(!.  A>AB025 B>?07-?0@03>=8B>2KE 68; 8 ?@>68;:>2, :@><5 B>?070 8 ?0@03>=8B0, B0:65 @0728BK 15@8;;, D;N>@8B, <0@30@8B, D;>3>?8B 8 BC@<0;8=. 0@03>=8B A;0305B <5;:85 15AF25B=K5 G5HC9:8. 3> E8<8G5A:89 A>AB02 >B25G05B D>@<C;5 (Na0,80!a0,08)0,88(Al1,96Mg0,02Fe0,01)1,99 [Al1,21Si2,79O10](OH1,58F0,15)1,73, f 27,2%. 0@30@8B ?@54AB02;5= 15AF25B=K<8 2K45;5=8O<8. %8<8G5A:89 A>AB02 (D.5.) (Ca0,75Na0,23)0,98 (Al1,98Mg0,01Fe0,01)2,00 [Al1,99Si2,01O10](OH1,50F0,24)1,74, f 49%. "C@<0;8= A;0305B 2:;NG5=8O 2 B>?075 8 3@0=8FK A>2<5AB=>3> @>AB0 A =8<. ;8=0 >B45;L=KE 2K45;5=89 4>AB8305B 7 <<. &25B <8=5@0;0 2 @07=KE :@8AB0;;0E 87<5=O5BAO >B 1;54=>-3>;C1>3> 4> 65;B>20B>-75;5=>20B>3> 8 A25B;>-1C@>3>. > E8<8G5A:><C A>AB02C A25B;>-1C@K9 BC@<0;8= >B=>A8BAO : 2KA>:>65;578ABK< DB>@-4@028B0< (f 24,2 31,8%), A>45@68B Ti (4> 0,3 <0A.% TiO2) 8 Ni (4> 0,3 <0A.% NiO), A>45@60=85 Cr =57=0G8B5;L=>. B=>H5=85 A>AB02;O5B Ca/(Ca+Na) 4,5 14,6%. 0@1>=0B-BC@<0;8=-E;>@8B-<CA:>28B>2K5 ?@>68;:8. %;>@8B A;0305B <5;:85 :@8AB0;;K 8 >1@07C5B B5A=K5 A@0AB0=8O A BC@<0;8=>< 8 <CA:>28B>< 8 >B=>A8BAO : 2KA>:>3;8=>75<8AB><C (Alx 1,2) 65;578AB><C (f 32%) ?8:=>E;>@8BC. !25B;0O A;N40 >1@07C5B <5;:85 15AF25B=K5 G5HC9:8. > E8<8G5A:><C A>AB02C  MB> <CA:>28B 8 D5=38B-<CA:>28B  Si3,09 3,17, A>45@60=85 ?0@03>=8B>2>3> :><?>=5=B0 4,3 6,3 <>;.%, f 55 64%. 0@1>=0B A;0305B >G5=L <5;:85 :@8AB0;;K 8 >1@07C5B B5A=K5 A@0AB0=8O A A8;8:0B0<8. 0G5AB25==K9 <8:@>7>=4>2K9 0=0;87 A2845B5;LAB2C5B, GB> E8<8G5A:89 A>AB02 <8=5@0;0 1;87>: <03=578BC. "C@<0;8= ?@>68;:>2 ?@54AB02;5= G5@=K<8 :@8AB0;;0<8 @07<5@>< 4> =5A:>;L:8E <<. > E8<8G5A:><C A>AB02C  MB> 2KA>:>65;578ABK9 4@028B (f 24,5 37,4%), A>45@6I89 Ti (4> 0,5 <0A.% TiO2), A>45@60=8O Cr 8 Ni =57=0G8B5;L=K. > A@02=5=8N A 4@028B0<8 87 D;>3>?8B-E;>@8B>2KE <5B0A><0B8B>2, >= E0@0:B5@87C5BAO 1>;55 2KA>:>9 65;578AB>ABLN 8 =5A:>;L:> 1>;55 =87:8<8 A>45@60=8O<8 Ti. B=>H5=85 Ca/(Ca+Na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a 2 ?@>B>;8B5 (48>@8BK, <5B0<>@D8BK). A5 87CG5==K5 BC@<0;8=K 7>=0;L=K: >B F5=B@0 :@8AB0;;0 : :@0N C25;8G8205BAO A>45@60=85 DB>@0, GB> <>65B A2845B5;LAB2>20BL >1 C25;8G5=88 fF2 2 ?@>F5AA5 :@8AB0;;870F8. "C@<0;8=A>45@60I85 0AA>F80F88 D>@<8@>20;8AL A CG0AB85< >B=>A8B5;L=> 2KA>:>B5<?5@0BC@=KE (450 550(!) @0AB2>@>2. 8B5@0BC@0: 1.Colopietro M.R., Friberg L.M. // GSA, 1987 Abstracts. !140176. 2.Cathelineau M. // Clay Min. 1988. V. 23. P. 471 485. 3.>B>2 .. // >:;. !!! . 1975. ". 222. N3. !.701 704. !!" #"  !#,$+%   " , / # (! -""'! % ") C7=5F>20 .. XE "C7=5F>20 .." , ?>;;>=>2 .. XE "?>;;>=>2 .." , 8:5=BL52 .. XE "8:5=BL52 .." , @8=>2 .. XE "@8=>2 .." , >E>2 .. XE ">E>2 .."  1 , 3.>A:20, >AA8O, ok@igem.ru KuznetsovaO.Yu, ApollonovV.N., VikentevI.V., Krinov D.I., Mokhov A.V. Peculiarites of isocubanite from the sulphide basins of hydrothermal field Reinbou (Mid-Atlantic backbone) (IGEM RAS, Moscow, Russia). Isokubanite is a cubic polymorph of cubanite CuFe2S3. We have studied samples of isocubanites from deposit Reinbou. Isocubanites occur in associations with sphalerite, chalcopyrite, troilite, pyrrhotite and may contain the inclusions of chalcopyrite and sphalerite. The unit cell parameters of natural isocubanites (00 = 5.302 and V = 149.05 3; 00 = 5.308 and V =14952 3) exceed the one of artificial isokubanite (00 =5.283 and V = 147.5 3). 4=8< 87 >A=>2=KE @C4>>1@07CNI8E <8=5@0;>2 384@>B5@<0;L=KE ?>;59 !525@=>9 B;0=B8:8, ?> A2>4:5 >;O@=>9 <>@A:>9 35>;>3>@07254>G=>9 M:A?548F88 (19993.), O2;O5BAO 87>:C10=8B. @><5 B>3>, 87>:C10=8B 70D8:A8@>20= =0 ?>;83>=5 0C F5=B@0;L=K9 (10AA59= 0C, N3>-70?04=0O G0ABL "8E>3> >:50=0) [1]. 7>:C10=8B O2;O5BAO ?>;8<>@D=>9 :C18G5A:>9 <>48D8:0F859 :C10=8B0 CuFe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ink ISIS, ?>:070;> =0;8G85 2:;NG5=89 AD0;5@8B0 2 =5A:>;L:8E 75@=0E 87>:C10=8B0. >;8G5AB2> AD0;5@8B0 <0;>, B.:. =0 @5=B35=>3@0<<5 53> ;8=88 =5 ?@>O28;8AL. 0AG5B ?0@0<5B@>2 :C18G5A:>9 M;5<5=B0@=>9 OG59:8 B0:>3> 87>:C10=8B0 40; A;54CNI85 @57C;LB0BK: 0> = 5,308 ; V = 149,523. !J5<:0 >1@07F0 ?@>2>48;0AL =0 48D@0:B><5B@5  -3, MB0;>=>< O2;O;AO :@5<=89. >;LH8=AB2> 8AA;54>20==KE 75@5= 87>:C10=8B0 2:;NG5=89 =5 A>45@68B, => 8E <0;K9 @07<5@ 8 B5A=0O 0AA>F80F8O A 4@C38<8 <8=5@0;0<8 =5 40NB 2>7<>6=>AB8 B>G=> @0AAG8B0BL ?0@0<5B@K M;5<5=B0@=KE OG55: B0:8E 2K45;5=89 87>:C10=8B0. > 40==K<, ?@82>48<K< 2 ASTM (:0@B>G:0 ! 27 166), 4;O 8A:CAAB25==> ?>;CG5==>3> 87>:C10=8B0 ?0@0<5B@ 00 :C18G5A:>9 OG59:8 @025= 5,283 , 0 >1J5< 55 A>AB02;O5B 147,53. ?@545;5=85 E8<8G5A:>3> A>AB020 87>:C10=8B>2 59=1>C 25;>AL =0 M;5:B@>==>< <8:@>A:>?5 JSM-5300. => ?>:070;> =0;8G85 :>10;LB0 (4> 4 %) 2> 2A5E 8AA;54>20==KE B>G:0E (26 B>G5: 2 12 75@=0E 87 4 >1@07F>2) 8 =0;8G85 =8:5;O (4> 1%) 2 5 B>G:0E 87 2 >1@07F>2. 8B5@0BC@0: 1.>@B=8:>2 .!., $54>@>2 ."., C@02L52 .. 8=5@0;L=K9 A>AB02 8 CA;>28O >1@07>20=8O AC;LD84=KE ?>AB@>5: 10AA59=0 0C (N3>-70?04=0O G0ABL "8E>3> >:50=0) // 5>;. @C4=. <-=89, 1993. ".35. ! 6. !.528 543. 2.Caye R., et al. Isocubanite, a new definition of the cubic polymorph of cubanite CuFe2S3 // Min. Mag., 1988. V.52. P.509 514. % "#  "+% "  "% /  #  1C;8:>20 .., 20@;0<>2 .. 1=AB8BCB 5>;>388 ><8 & #@ , !K:BK2:0@, kulikova@geo.komisc.ru; 2- , '5@=>3>;>2:0, dima@iem.ac.ru 1Kulikova K.V., 2Varlamov D.A. The find of telluride of platinum group metal in basites of the Polar Urals (1Institute of Geology, Komi SC RAS, Syktyvkar; 2 IEM RAS, Chernogolovka). Telluride of platinum group metals belonging to moncheite-merenskite-melonite mineral group (Pd,Pt,Ni)(Te,Bi)2 was discovered for the first time in plagioclase-bearing pyroxenites from hyperbasite-basite complex of east slope of Polar Ural. They are present by micro grains (size 2-6 mkm) located on boundaries of chalcopyrite grains. Composition of these tellurides shows almost equal parts of palladium, platinum and nickel in formula and also significant impurity of bismuth (up to 6,5%, see below) that specifies similarity of these minerals on low-sulfide PtPd ores from North Karelia and Kola Peninsula rhythmically layered plutons and also on another massifs of olivinite-ferroclinopyroxenite-hornblendite-gabbro formations of Ural palladium-bearing belt. @8 ?@>2545=88 <8:@>7>=4>2KE 0=0;87>2 <8=5@0;>2 87 ?;038>:;07A>45@60I8E ?8@>:A5=8B>2 >;O@=>3> #@0;0 2?5@2K5 1K;8 >1=0@C65=K <8:@>A:>?8G5A:85 2K45;5=8O B5;;C@840 ?;0B8=>2KE <5B0;;>2 A<5H0==>3> A>AB020, >B25G0NI53> A@54=8< A>AB020< 87><>@D=KE @O4>2 <>=G58B (PtTe2) % <5@5=A:88B (Pd[Te,Bi]2) % <5;>=8B (NiTe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n70), 87 @C4=KE 2AB@5G0NBAO 2 =51>;LH8E :>;8G5AB20E E0;L:>?8@8B, ?8@8B, 8;L<5=8B 8 E@><<03=5B8B A ?@8<5ALN 20=048O. 7CG5==K9 <8=5@0; ?@54AB02;5= >G5=L <5;:8<8 (2 6 <:<) 87><5B@8G=K<8, => 157 2848<>9 >3@0=:8 75@=0<8, ?@8C@>G5==K<8 : <5675@=>2K< 3@0=8F0< E0;L:>?8@8B0. 80?07>=K A>AB020 <8=5@0;0 ?@82545=K 2 B01;8F5. "01;8F0 PtPdRhTeBiFeCuNiS14,8 14,999,01 9,160,0 0,3861,41 61,725,78 6,381,36 1,430,92 1,214,25 4,680,12 0,250=0;87K A45;0=K =0 M;5:B@>==>< <8:@>A:>?5 JEOL-820 A M=5@3>48A?5@A8>==>9 0=0;8B8G5A:>9 ?@8AB02:>9 Link-AN10000 =0 :0D54@5 <8=5@0;>388 # @>G85 ?;0B8=>84K =5 2KO2;5=K. 5A<>B@O =0 <0;K9 @07<5@ 75@5= (A>?>AB028<K9 A @07<5@>< 7>=K 2>71C645=8O M;5:B@>==>3> ?CG:0), ?>GB8 ?>;=>5 >BACBAB285 A5@K 2 0=0;875 <8=5@0;0 (=0E>4OI53>AO 2 E0;L:>?8@8B>2>9 <0B@8F5) C:07K205B =0 4>AB0B>G=CN :>@@5:B=>ABL 0=0;87>2. !;54C5B >B<5B8BL, GB> 87CG5==K5 75@=0 2K3;O4OB 3><>35==K<8 2 >B@065==KE M;5:B@>=0E A 25I5AB25==K< :>=B@0AB><. 0AG5B=0O D>@<C;0 <8=5@0;0: (Pd0,31 0,33Ni0,27 0,29Pt0,29Fe0,09Cu0,07Rh0,01)1,05(Te1,79 1,83Bi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udson D.R. Platinum-group minerals from the Kambalda nickel deposits, Western Australia // Econ.Geol., 1986. V.81. !6. .1218 1225. 2. 5>;>38O 8 35=578A <5AB>@>645=89 ?;0B8=>2KE <5B0;;>2 // .: 0C:0, 1994. 302 A. 3. >;G5=:> ..., >@>B552 .. ;0B8=><5B0;L=>5 >@C45=5=85 ?0;5>>AB@>2>4C6=KE :><?;5:A>2 #@0;0: ?;0B8=>=>A=K5 8 ?0;;0485=>A=K5 ?>OA0 //  A1.: 5B0;;>35=8O 8 35>48=0<8:0 #@0;0. :0B5@8=1C@3, 2000. !.94 98. + +  &$" 1>2A:0O .., 15:>2 .., 2>=>=:>20 .. 1#, >A:20, >AA8O, mineral@geol.msu.ru, 2% , >A:20, >AA8O 1Lovskaya E.V., 1Pekov I.V., 2Kononkova N.N. new data on zeophyllite (1Moscow State University, Moscow, Russia, 2GEOKHI, Moscow, Russia). &5>D8;;8B  2>4=K9 DB>@A8;8:0B :0;LF8O, @54:89 <8=5@0; 384@>B5@<0;8B>2, A2O70==KE A >A=>2=K<8 MDDC782=K<8 ?>@>40<8, ?@8G5<, :0: ?@028;>, ?>2KH5==>9 I5;>G=>AB8. 0E>4:8 F5>D8;;8B0 2 4@C38E >1AB0=>2:0E 5I5 1>;55 @54:8. -B> 15AF25B=K9 8;8 15;K9 <O3:89 A;N4>?>4>1=K9 <8=5@0; A ?5@;0<CB@>2K< 1;5A:><. B:@KBK9 2 =0G0;5 XX 2, F5>D8;;8B 4>;3>5 2@5<O >?8AK20;AO A D>@<C;>9 Ca4Si3O8(OH,F)4(6H2O. 57C;LB0BK AB@C:BC@=>3> 8AA;54>20=8O ?@825;8 : 8450;878@>20==>9 D>@<C;5: Ca12[Si10O28]F6(OH)2(6H2O [1]. 4=0:>, @50;L=K5 A>AB02K F5>D8;;8B0 ?@0:B8G5A:8 2A5340 >B;8G0NBAO ?>=865==K< A>45@60=85< Si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i: 25;8G8=0 (Si+Al)/(Ca+Sr+Na+K+Mg) :>;51;5BAO >B 0,59 4> 0,81 ?@8 B5>@5B8G5A:>9 0,83. -B> 3>2>@8B > B><, GB> =5 ?@8<5AL :0;LF8B0 2 AB0@KE E8<8G5A:8E 0=0;870E [2] ?@82>48;0 : 70=865=8N :>;8G5AB20 Si, 0 A:>@55 2A53> A?@0254;82K< O2;O5BAO ?@54?>;>65=85 !.5@;8=> [1] > 2>7<>6=>AB8 @50;870F88  384@>3@0=0B>2>9 AE5<K 87><>@D87<0 2 F5>D8;;8B5: (SiO4) ( 4(OH). A5 E818=A:85 >1@07FK F5>D8;;8B0 >:070;8AL 2KA>:>DB>@8ABK<8: >B 9,7 4> 10,3 <0A.%F, GB> >B25G05B 7,7 8,8 D>@<. 54. ?@8 @0AG5B5 :0: =0 AC<<C :0B8>=>2, @02=CN 22, B0: 8 =0 (Si+Al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r.  >1@07F5 87 8@>2A:>3> @C4=8:0 >= =5 >1=0@C65=, <0B5@80; A 3. 0A2C<G>@@ 8 3;C1>:8E 3>@87>=B>2 3..:A?>@ A>45@68B 0,4 0,5 <0A.% SrO, 0 2 <C759=>< >1@07F5 F5>D8;;8B0- D>H0;;0A8B0 87 >2G>@@8B>2>3> @C4=8:0 CAB0=>2;5=> <0:A8<0;L=>5 4;O MB>3> <8=5@0;0 A>45@60=85 SrO: 3,6% 2 A@54=5<, 0 2 >B45;L=KE B>G:0E 4> 4,3%. 5@>OB=>, MB8 @07;8G8O A2O70=K A @0A?@545;5=85< Sr <564C A>ACI5AB2CNI8<8 <8=5@0;0<8.  >1@07F0E 87 ?5@2KE B@5E <5AB>=0E>645=89 F5>D8;;8B B5A=> 0AA>F88@C5B A F5>;8B0<8  MDD5:B82=K<8 :>=F5=B@0B>@0<8 Sr, 2 B>< G8A;5 A B><A>=8B><, :>B>@K9 >B;8G05BAO >A>15==> A8;L=K< A@>4AB2>< : MB><C :0B8>=C [7]. -B> >1JOA=O5B >B=>A8B5;L=CN >154=5==>ABL B0:>3> F5>D8;;8B0 Sr-E0@0:B5@=K< M;5<5=B>< 2KA>:>:0;LF852KE 384@>B5@<0;8B>2 [6].  ?@>68;:0E 87 >2G>@@8B>2>3> @C4=8:0 F5>;8BK >BACBAB2CNB, GB> A:>@55 2A53>, 8 AB0;> ?@8G8=>9 >1>30I5=8O F5>D8;;8B0 745AL AB@>=F85<.  70:;NG5=85 >B<5B8<, GB> %818=K, 25@>OB=>, O2;ONBAO A0<K< 1>30BK< <5AB>=0E>645=85< F5>D8;;8B0 2 <8@5. 8B5@0BC@0: 1.Merlino S. The crystal structure of zeophyllite // Acta Cryst. 1972. V. 28. P. 2726 2732. 2.8=5@0;K. !?@02>G=8: (?>4 @54.$..'CE@>20). ., 1992. T. IV. K?. 2. 662A. 3.>=HB54B -.., 8 4@. 8=5@0;K %818=A:8E 8 >2>75@A:8E BC=4@. .-., 1937. 563A. 4.0@A0=>2 .., (525;520 ..  B0: =07K205<>< D>H0;;0A8B5 ..'8@28=A:>3> // "@. 8=5@. C75O  !!! . 1949. K?. 1. !. 55 59. 5.>@D<0=..., 8 4@. >2K5 40==K5 > F5>D8;;8B5 87 %818=A:>3> I5;>G=>3> <0AA820 // "@. 8=5@. C75O  !!! . 1976. K?. 25. !. 153 157. 6.>2A:0O ., 8 4@. 8=5@0;>38O, 35>E8<8O 8 35=578A ?>74=8E 2KA>:>:0;LF852KE 384@>B5@<0;8B>2 %818=A:>3> <0AA820, >;LA:89 ?>;C>AB@>2 // . 2002. ! 2. !. 18 31. 7.5:>2 ., 8 4@. "><A>=8B-Sr (Sr,Ca)2Na[Al5Si5O20](6 7H2O  =>2K9 F5>;8B 87 %818=A:>3> <0AA820 (>;LA:89 ?>;C>AB@>2) 8 87><>@D=0O A5@8O B><A>=8B Ca  B><A>=8B Sr // . 2001. ! 4. !. 46 55. @82>3@0==K5 0;<07K 8 A>?CBAB2CNI85 <8=5@0;K =5 CAB0=>2;5==>3> 35=578A0 87 @>AAK?59 !L5@@0-5>=5 0A;5==8:>20 .. XE "0A;5==8:>20 .." ., $5@C78 .. XE "$5@C78 .."  #, >A:20, julia_mas@hotbox.ru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mailto:meyx@mail.ru meyx@mail.ru Meyksina Yu.L. Micas of Emerald Mines, the Urals (S bSU, Saint-Petersburg, Russia). Chemical composition and polytypic modification of micas were studied. Heterogeneity of their forming was established. The early mica composition corresponds to phlogopite with variable ferruginosity enriched with MgO, FeO, Fe2O3 (phlogopite- biotite). Late micas are presented as muscovite with the increased contents of MgO (2,54,5 wt. %). Entering scheme of Mg and mechanism of charge compensation are needed the additional investigations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uK(((1)) 2KO28;8 A<5=C ?>;8B8?=KE <>48D8:0F89 A;N4. =8 ?>:070;8, GB> D;>3>?8B 8<55B 1-?>;8B8?=CN <>48D8:0F8N, 0 4;O <CA:>28B0 >1KG5= 21-?>;8B8?. -B> >1AB>OB5;LAB2> C:07K205B, GB> 8 A0<>AB>OB5;L=K5 2K45;5=8O <CA:>28B0, 8 53> 03@530BK, @0728BK5 ?> D;>3>?8BC, =5 =0A;54CNB AB@C:BC@=KE >A>15==>AB59 ?@54H5AB2CNI8E A;>8ABKE <8=5@0;>2 8, A;54>20B5;L=>, =5 B>;L:> 35B5@>E@>==K D;>3>?8BC, => 8 35B5@>35==K 5<C. "01;8F0 %8<8G5A:89 A>AB02 A;N4 7C<@C4=KE :>?59 #@0;0 (<0A.%) * Chemical composition of the mica from the Ural Emerald mines (wt. %) * ><?>=5=BK1D2D3D**4D***5D**6<7<8<9<**10<***SiO239,4337,0540,7643,6439,2946,9847,6349,3645,8045,22TiO20,550,130,280,001,120,350,140,180,250,00Al2O314,0113,3116,0811,6110,6426,3529,5439,3229,9136,30Fe2O30,000,001,131,846,872,151,430,530,720,93FeO4,763,066,655,1614,250,000,000,001,920,68MnO0,280,380,161,384,000,080,200,000,080,05MgO20,8920,5621,5420,839,374,874,122,453,431,49!00,000,001,180,440,470,000,000,900,470,60Cr2O30,000,150,000,000,000,000,080,140,000,00Na2O0,460,401,981,161,640,300,430,190,000,98K2O10,0410,297,769,708,7711,0810,819,4711,269,38Li2O  0,490,00      F  2,002,08    0,62 H2O+  1,021,763,17   4,934,38H2O   0,100,140,16   1,031,10!C<<0:90,4285,33101,13100,0999,7592,1694,37102,52100,42100,14O=  F2 0,81 0,87 0,26100,3299,22100,16@8<5G0=85: 1D  A@54=575@=8ABK9 D;>3>?8B :>@8G=520B>3> F25B0 87 A;N48B0; 2D  D;>3>?8B 87 :>=B0:B>2>9 7>=K A >B0;L:>20==K< A5@?5=B8=8B><; 3D  D;>3>?8B 87 7>=K  45A8;8F8@>20==KE ?53<0B8B>2 A ?;038>:;078B>2K<8 ;8=70<8; 4D  18>B8B 87 :>=B0:B0 0<D81>;>2>3> 3=59A0 A ?53<0B8B><  G8AB>9 ;8=88 ; 5D  D;>3>?8B 87 A;N48B>2; 6<  :@C?=>G5HC9G0BK9 <CA:>28B, @072820NI89AO ?> D;>3>?8BC 87 A;N48B0; 7<  D;>3>?8B, 70<5I05<K9 <CA:>28B><; 8<  <CA:>28B 87 @5;8:B>2>3> 75@=0 ?;038>:;070; 9<  <CA:>28B 87 D;N>@8B-<CA:>28B>2>3> ?@>68;:0, A5:CI53> 48>@8B; 10<  <CA:>28B 87 0;L18B878@>20==KE ?53<0B8B>2; *  0=0;87 ;01>@0B>@88   5E0=>1@-=0;8B , >?5@0B>@ ... @5F5@;**  ?> .. ;0A>2C, .. CBC:>2>9 (1960);***   8=5@0;K , B.4 57C;LB0BK 87CG5=8O E8<8G5A:>3> A>AB020 A;N4 (  5E0=>1@-=0;8B , <8:@>7>=4 CamScan, >?5@0B>@ ... @5F5@) ?@82545=K 2 B01;8F5. E ?5@5AG5B ?@82>48B : A;54CNI8< :@8AB0;;>E8<8G5A:8< D>@<C;0< D;>3>?8B0: (K0,97Na0,07)1,04(Mg2,38Fe0,30Al0,27Ti0,03Mn0,02)3,00[(Si3,01Al0,99)4,00O10](O1,22(OH,F)0,78)2,00 (K1,06Na0,06)1,12(Mg2,48Al0,27Fe0,21Mn0,03Ti0,01Cr0,01)3,01[(Si3,00Al1,00)4,00O10](O1,16(OH,F)0,84)2,00 8 <CA:>28B0: (K0,74(H3O)0,24Na0,02)1,00(Al1,82Mg0,22Fe0,02Ti0,01Cr0,01)2,08[(Si3,00Al1,00)4,00O10]((OH,F)1,98O0,02)2,00 #AB0=>2;5==K5 @07;8G8O 2 A>AB025 A;N4 ?>:07K20NB, GB> =081>;55 @0==85 87 =8E A;>65=K D;>3>?8B>< ?5@5<5==>9 65;578AB>AB8. !;N4K 87 2<5I0NI8E 0<D81>;>2KE 3=59A>2 8;8 48>@8B>2 >1>30I5=K MgO, FeO, Fe2O3 8 ?@81;860NBAO ?> A>AB02C : 18>B8BC. 081>;55 ?>74=85 A;N4K ?@54AB02;5=K <CA:>28B><, A>AB02 :>B>@>3> >B;8G05BAO 2KA>:8< A>45@60=85< MgO (2,5(4,5% 8 1>;55) ?@8 :>;510=8OE :>=F5=B@0F89 SiO2 2 ?@545;0E (45,8(49,3% (B01;.) 8 >BACBAB288 ?@O<>9 :>@@5;OF88 MB8E 25;8G8=. KOA=5=85 AE5< 2E>645=8O B0:8E :>;8G5AB2 MgO 2 @5H5B:C <CA:>28B0 8 <5E0=87<0 :><?5=A0F88 70@O4>2 2 =59 B@51C5B ?>AB0=>2:8 A?5F80;L=KE 8AA;54>20=89. 8B5@0BC@0: 1.;0A>2 .., CBC:>20 .. 7C<@C4=K5 >?8 // .:  !!! , 1960. 2.8@ #.., %0C8 .., CA<0= 6. >@>4>>1@07CNI85 <8=5@0;K // .: 8@, 1965, 1966. ". 1, 3, 4. 3.5@=0:>2 .. #@0;LA:85 7C<@C4=K5 >?8 // 725AB8O #>2, 1993. ! 4. 4.8=5@0;K. .: 0C:0, 1992. ".4. K?.1. 5.>?>2 . 8 4@. #@0;LA:85 7C<@C4=K5 :>?8: 8AB>@8O 87CG5=8O, 35>;>38G5A:89 >G5@:, <8=5@0;>38G5A:89 :040AB@, 181;8>3@0D8O. :0B5@8=1C@3: #, 1998. 6."@535@ .. ?B8G5A:>5 >?@545;5=85 ?>@>4>>1@07CNI8E <8=5@0;>2. .: 54@0, 1980. 7.'868: .., 5:CE ..  35=578A5 87C<@C4>2 2 <5AB>@>645=8OE A;N48B>2>3> B8?0. .:0C:0, 1980. 8.(5@ABN: .. !;N48B>2K5 :><?;5:AK 8 8E :;0AA8D8:0F8O. // , 1965. K?. 1. >;>B>-AC;LD>0@A5=84=K5 @C4K H:8=8=A:>3> :>10;LB-<54=>-:>;G540==>3> <5AB>@>645=8O (.6=K9 #@0;) 15;5:5AF520 ..., 209:>2 .. 1=AB8BCB <8=5@0;>388 #@ , 3. 80AA, >AA8O,  HYPERLINK mailto:melekestseva@ilmeny.ac.ru melekestseva@ilmeny.ac.ru, 2.6=>-#@0;LA:89 3>AC40@AB25==K9 C=825@A8B5B, 3. 80AA, >AA8O,  HYPERLINK mailto:zaykov@ilmeny.ac.ru zaykov@ilmeny.ac.ru 1Melekestseva I.Yu., 2Zaykov V.V. Gold-sulphoarsenide ores of Ishkininskoe cobalt-copper-sulphide deposit, the South Urals (1Institute of mineralogy, Urals branch, RAS, Miass, Russia; 2South-Urals State University, Miass, Russia). Arsenopyrite and gold in sulphide-sulphoarsenide ore type of Ishkininskoe cobalt-bearing sulphide deposit have been investigated. Its shown that arsenopyrite differs from the studied arsenopyrites of other sulphide and hydrothermal deposits. Its very enriched in nickel (up to 11,62%). The intermediate phase between arsenopyrite and gersdorffite has been determined. It let to suggest the existing of an isomorphic sequence arsenopyrite-gersdorffite. A close association of gold with sulphoarsenides of iron, cobalt and nickel was established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amebax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e0,76Ni0,25Co0,05)1,06As1,11S0,89  4> (Fe0,87Ni0,08Co0,03)0,98As1,08S0,92 @8G5< 87 @8A. 284=>, GB> D83C@0B82=K5 B>G:8 ?@0:B8G5A:8 =5 ;>60BAO 2 CAB0=>2;5==>5 4;O =8E ?>;5. @><5 MB>3>, <8:@>7>=4>2K5 0=0;87K ?>:07K20NB =0;8G85 ?@><56CB>G=>9 D07K <564C 0@A5=>?8@8B>< 8 35@A4>@D8B><, >B25G0NI59 ?> A>AB02C (Fe0,49Ni0,45Co0,07)1,01As1,39S0,61. >;>B> 2 @C40E <5AB>@>645=8O O2;O5BAO >4=8< 87 @54:8E <8=5@0;>2 8 A@54=55 A>45@60=85 ?> @C4=K< B5;0< A>AB02;O5B 2,87 3/B. 4=0:> 2 MB>< B8?5 @C4K 53> A>45@60=8O 4>AB830NB 16,9 3/B, 8 =0E>48BAO >=> 2 B5A=>9 A2O78 A 0@A5=>?8@8B><, 345 G0AB> =01;N405BAO 2 2845 <5;:8E M<C;LA85284=KE 2:;NG5=89 @07<5@>< 4> 4 8 <:<. -;5:B@>==>-<8:@>A:>?8G5A:8 1K;> CAB0=>2;5=>, GB> 2>:@C3 =53> 8<55BAO =8:5;LA>45@60I0O >B>@>G:0, GB> >B@0605B 7>=0;L=>5 @0A?@545;5=85 =8:5;O 2 0@A5=>?8@8B5. A;54AB285 <0;KE @07<5@>2 75@5= 8 A8;L=>3> 2;8O=8O 2<5I0NI53> 0@A5=>?8@8B0 <8:@>7>=4>2K< 0=0;87>< >?@545;5=K B>;L:> A>>B=>H5=8O 7>;>B0 8 A5@51@0, 20@L8@CNI85 >B 1:4 4> 1:6 [2]. @><5 0@A5=>?8@8B0, 7>;>B> A2O70=> A :>10;LB8=><, =8:5;8=>< 8 35@A4>@D8B>< [2]. AE>4O 87 2KH587;>65==>3>, <>6=> ?@54?>;>68BL ACI5AB2>20=85 87><>@D=>3> @O40 =5 B>;L:> <564C 0@A5=>?8@8B>< 8 0;;>:;078B><, :>10;LB8=>< 8 35@A4>@D8B><, => 8 <564C 0@A5=>?8@8B>< 8 35@A4>@D8B><. @><5 MB>3>, 2 @C40E, A>45@60I8E AC;LD>0@A5=84K 65;570, :>10;LB0 8 =8:5;O, CAB0=>2;5=0 0AA>F80F8O 7>;>B0 A MB8<8 <8=5@0;0<8. 01>BK 2K?>;=5=K ?@8 ?>445@6:5 $$ (3@0=BK 01 05 65329 8 02 05 06473-<0A) 8 3@0=B0 #=825@A8B5BK >AA88 (09.01.014). 8B5@0BC@0: 1.>@8H0=A:0O .!., 8=>3@04>20 .., @CB>2 .. 8=5@0;K =8:5;O 8 :>10;LB0 // 74-2> #, 1981. !. 39 46. 2. 5;5:5AF520 .., >;4K@520 ., 09:>2 . >;>B> 2 :><?;5:A=KE @C40E H:8=8=A:>3> <54=>-:>10;LB>2>3> <5AB>@>645=8O (.6=K9 #@0;) //  8=5@0;>38O  >A=>20 8A?>;L7>20=8O :><?;5:A=KE @C4 . "578AK 4>:;04>2 >48G=>3> A>1@0=8O  , !0=:B-5B5@1C@3, 2001. !. 70 72. 3. 5;5:5AF520 ..., 09:>2 .. 8=5@0;K :>10;LB0 8 =8:5;O 2 @C40E H:8=8=A:>3> :>10;LB-<54=>-:>;G540==>3> <5AB>@>645=8O // =0AB>OI89 A1>@=8:. 4.5;5:5AF520 ..., 09:>2 .. 8@8B-?8@@>B8=>2K5 @C4K H:8=8=A:>3> <54=>-:>10;LB>2>3> <5AB>@>645=8O (.6=K9 #@0;) // 5B0;;>35=8O 4@52=8E 8 A>2@5<5==KE >:50=>2 2001. 80AA:  #@ , 2001. !.149 156. 5.!?@02>G=8:->?@545;8B5;L @C4=KE <8=5@0;>2 2 >B@065==>< A25B5. .: 54@0, 1988. !. 176 181. 8=5@0;K :>10;LB0 8 =8:5;O 2 @C40E H:8=8=A:>3> :>10;LB-<54=>-:>;G540==>3> <5AB>@>645=8O (.6=K9 #@0;) 15;5:5AF520 ..., 209:>2 .. 1=AB8BCB <8=5@0;>388 #@ , 3. 80AA, >AA8O, melekestseva@ilmeny.ac.ru, 2.6=>-#@0;LA:89 3>AC40@AB25==K9 C=825@A8B5B, 3. 80AA, >AA8O, zaykov@ilmeny.ac.ru 1Melekestseva I.Yu., 2Zaykov V.V. Minerals of cobalt and nickel in ores of Ishkininskoe cobalt-copper-sulphide deposit, the South Urals (1Institute of mineralogy, Urals branch, RAS, Miass, Russia,  HYPERLINK mailto:melekestseva@ilmeny.ac.ru melekestseva@ilmeny.ac.ru, 2South-Urals State University, Miass, Russia). Minerals of cobalt and nickel of Ishkininskoe cobalt-bearing sulphide deposit have been investigated. They are represented by cobaltite, niccolite, gersdorffite, pentlandite, two varieties of violarite and nickel mineral similar to linnaeite group. Two associations of minerals: the primary cobaltite, niccolite, gersdorffite, pentlandite, and the secondary relatively to the previous consisted of violarite-I and II and nickel mineral similar to linnaeite group. The second group of minerals is developed after pyrrhotite and pentlandite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xiolab D8@<K Karl Zeiss (=AB8BCB <8=5@0;>388 #@ ), A>AB02 <8=5@0;>2 >?@545;O;AO =0 <8:@>7>=4>2KE 0=0;870B>@0E JEOL JCXA-733 (=AB8BCB <8=5@0;>388 #@ ), JEOL JXA-8900RL ($@0915@3A:0O 3>@=0O 0:045<8O, $@0915@3, 5@<0=8O) 8 Camebax (C759 5AB5AB25==>9 8AB>@88, >=4>=, 5;8:>1@8B0=8O). 8=5@0;K :>10;LB0 8 =8:5;O =0 <5AB>@>645=88 ?@54AB02;5=K :>10;LB8=><, =8:5;8=><, 35@A4>@D8B><, ?5=B;0=48B><, 28>;0@8B>< 42CE @07=>284=>AB59 8 <8=5@0;>< =8:5;O, 1;87:8< : 3@C??5 ;8==58B0. >10;LB8= =01;N405BAO 2 2845 E>@>H> >1@07>20==KE >B45;L=KE 87><5B@8G=KE :@8AB0;;>2 :C18G5A:>3> 8 >:B0M4@8G5A:>3> 3018BCA>2. =>340 2AB@5G0NBAO A:5;5B=K5 :@8AB0;;K 8 A@>AB:8. >2>;L=> G0AB> :>10;LB8= >1@07C5B A:>?;5=8O, ?@8C@>G5==K5 : :0@1>=0B=K< 68;:0<. 07<5@K 75@5= 8 03@530B>2 :>;51;NBAO >B 0,1 4> 1 <<. ! 4@C38<8 <8=5@0;0<8 2A5340 8<55B G5B:85 8 @>2=K5 3@0=8FK. '0AB> A>45@68B 2:;NG5=8O E0;L:>?8@8B0, <03=5B8B0, 7>;>B0 8 83>;LG0BKE :@8AB0;;>2 =5@C4=KE <8=5@0;>2. AA>F88@C5B A =8:5;8=><, 2KABC?0O 2 @>;8 <8=5@0;0-E>7O8=0. =>340 =01;N405BAO 70<5I5=85 :>10;LB8=0 E0;L:>?8@8B><. @0:B8G5A:8 2A5340 7>=0;5=, 2 F5=B@5 :@8AB0;;>2 =01;N40NBAO ?>=865==K5 A>45@60=8O :>10;LB0 (23%) 8 ?>2KH5==K5 =8:5;O (4>9 14%) (Co0,66Ni0,26Fe0,12)1,04As1,01S0,96.  ?5@8D5@88 A>45@60=8O :>10;LB0 ?>2KH0NBAO (4> 27%), 0 =8:5;O C<5=LH0NBAO (4> 5 6%) (Co0,75Ni0,16Fe0,12)1,03As0,96S1,01 (?@O<0O 7>=0;L=>ABL). "0:65 =01;N405BAO >1@0B=0O (A>45@60=8O :>10;LB0 ?>=860NBAO >B F5=B@0 : ?5@8D5@88, =8:5;O  2>7@0AB0NB), G5@54CNI0OAO 8 0AA8<5B@8G=0O 7>=0;L=>AB8.  =5:>B>@KE :>10;LB8=0E, ?@8C@>G5==KE : :0@1>=0B=K< 68;:0<, >B<5G0NBAO :@8AB0;;K E@><H?8=5;84>2, @0A?>;>65==K5 2 7>=0E @>AB0 :>10;LB8=>2. 8:5;8= 2AB@5G05BAO 2 2845 75@5= =5?@028;L=>9 D>@<K 8 0;;>B@8><>@D=>75@=8ABKE 03@530B>2 @07<5@>< >B 4>;59 4> 2 3 <<, 0AA>F88@C5B A :>10;LB8=><, 345 =0E>48BAO 2 2845 >B45;L=KE <5;:8E 75@5=-2:;NG5=89, A 35@A4>@D8B>< 8 7>;>B>< 2 2845 :@C?=KE 03@530B>2. > E8<8G5A:><C A>AB02C =8:5;8= 2A5340 >4=>@>45= 8 A>>B25BAB2C5B (Ni1,06Co0,01)1,07As0,99. 5@A4>@D8B >1@07C5B :@8AB0;;8G5A:85 03@530BK (4> 0,5 1 <<) 2 0AA>F80F88 A =8:5;8=><, >B45;L=K5 :@8AB0;;K @54:8. %8<8G5A:89 A>AB02 20@L8@C5B >B (Ni0,47Co0,25Fe0,22)0,94As1,09S0,91 4> (Ni0,61Co0,25Fe0,23)1,09As1,05S0,95. 5=B;0=48B ?@54AB02;5= <5;:>75@=8ABK<8 03@530B0<8, >4=0:> ?>:0 =5 8AA;54>20= <8:@>7>=4>2K<8 <5B>40<8. 8>;0@8B ?@54AB02;5= 42C<O @07=>284=>ABO<8. 8>;0@8B-I 2AB@5G05BAO 2 2845 B>=:8E (4> 15 20 <:<) ;0<5;;59 2 E0;L:>?8@8B5.  0=H;8D0E 8<55B 3;04:CN 8 @>2=CN ?>25@E=>ABL 157 B@5I8=. %8<8G5A:89 A>AB02 E0@0:B5@87C5BAO 1;87:8<8 A>45@60=8O<8 =8:5;O 8 65;570, A>>B25BAB2C5B (Fe1,54Ni1,48)3,02S4. 8>;0@8B-II >1@07C5B <5;:85 (4> 0,13 0,15 <<) B@5I8=>20BK5 75@=8ABK5 03@530BK, ?;0AB8=:8, @072820OAL ?> 3@0=C;><>@D=><C 8 ?;0AB8=G0B><C ?8@@>B8=C. 0728205BAO 8 ?> ?5=B;0=48BC (2 548=8G=KE A;CG0OE >1=0@C68205BAO @5;8:B>20O A?09=>ABL). =0G8B5;L=> >1>30I5= :>10;LB>< (4> 16%) ?> A@02=5=8N A ?@54K4CI59 @07=>284=>ABLN 8 ?> A@02=5=8N A 40==K<8 !.!. >@8H0=A:>9 [1], 345 ?@82>48BAO <0:A8<0;L=> CAB0=>2;5==>5 A>45@60=85 :>10;LB0 2 28>;0@8B5 13%. > A>AB02C =5AB5E8><5B@8G5=  (Fe0,94(Ni1,38Co0,81)2,19)3,13S4. 8=5@0; 3@C??K ;8==58B0, B>G=> =54803=>AB8@>20==K9, >1@07C5B B>=G09H85 (4> 3 <:<) 2KBO=CBK5 @07>@20==K5 (?;0<5=5284=K5) ;0<5;;8 2 E0;L:>?8@8B5. ?B8G5A:8 E0@0:B5@87C5BAO @>7>20B>-A8@5=52K< <5@F0NI8< F25B><.  5@F0=85 <>65B 1KBL >1JOA=5=> 53> B>=:>7>=0;L=K< AB@>5=85< 8 >B;8G85< 7>= ?> F25BC 8 >B@065=8N. > A>AB02C =5AB5E8><5B@8G5=  (Fe1,05Ni0,40)1,45S2, => ?> A>>B=>H5=8N AC<<K :0B8>=>2 : A5@5 1;87>: : <8=5@0;0< 3@C??K ;8==58B0. "0:8< >1@07><, 2 @C40E H:8=8=A:>3> <5AB>@>645=8O :>10;LBA>45@60I8E AC;LD84=KE @C4 =01;N405BAO 425 0AA>F80F88 <8=5@0;>2 =8:5;O 8 :>10;LB0: ?5@28G=0O :>10;LB8=, =8:5;8=, 35@A4>@D8B, ?5=B;0=48B, 8 2B>@8G=0O ?> >B=>H5=8N : ?@54K4CI59, :C40 2E>4OB 28>;0@8B-I 8 II 8 =54803=>AB8@>20==K9 <8=5@0;, 1;87:89 : 3@C??5 ;8==58B0. B>@0O 3@C??0 <8=5@0;>2 @0728205BAO ?> ?8@@>B8=C 8 ?5=B;0=48BC. 01>BK 2K?>;=5=K ?@8 ?>445@6:5 $$ (3@0=BK 01 05 65329 8 02 05 06473-<0A) 8 3@0=B0 #=825@A8B5BK >AA88 (09.01.014). 8B5@0BC@0: 1. >@8H0=A:0O .!. 8 4@. 8=5@0;K =8:5;O 8 :>10;LB0 // 74-2> #, 1981. !. 39 46. 2.09:>2 . 8 4@. 8@@>B8=>2K5 8 7>;>B>-0@A5=>?8@8B>2K5 @C4K H:8=8=A:>3> <5AB>@>645=8O (;02=K9 #@0;LA:89 @07;><) // 5B0;;>35=8O 4@52=8E 8 A>2@5<5==KE >:50=>2  99. 80AA: 8=, 1999. !.92 95. !!" !  # !    >8A5520 .. XE ">8A5520 .."  #, >A:20, >AA8O,  HYPERLINK "mailto:dotch@mail.ru" dotch@mail.ru. Moiseeva O.A. Features of corundum genesis from North Karelia (MSU, Moscow, Russia). Two deposits of North Karelia red corundum (ruby)  Hitostrov and Dadina Gora have been studied. Mineral paragenesis of corundum rocks, chemical composition associations with corundum minerals and characteristics of corundum crystals have been established. Analysis of mineral paragenesises and chemical composition of minerals allow reconstructing TP-conditions of mineral generation. The attempt was made of sources of Al and Cr ions necessary for formation gem variety of corundum.  E>45 40==KE 8AA;54>20=89 ?@54?@8=OB0 ?>?KB:0 @5:>=AB@C:F88 CA;>289 >1@07>20=8O 1;03>@>4=KE @07=>284=>AB59 :>@C=40 42CE ?@>O2;5=89 !525@=>9 0@5;88  %8B AB@>2 8 O48=0 >@0. 0 >A=>25 0=0;870 ?0@035=578A>2 8 E8<8G5A:>3> A>AB020 :>@C=40 8 A>ACI5AB2CNI8E A =8< <8=5@0;>2 ?@54?@8=OB0 ?>?KB:0 CAB0=>28BL 8AB>G=8: 0;N<8=8O 8 E@><0, =5>1E>48<KE 4;O >1@07>20=8O 1;03>@>4=KE @07=>284=>AB59 :>@C=4>2. @>O2;5=85 :>@C=40 %8B>AB@>2 =0E>48BAO 2 <5B0<>@D8G5A:8E 3=59A0E =0 :>=B0:B5 ?;038>:;07>2KE 0<D81>;8B>2 8 :8A;KE 3=59A>2 [1]. 8=5@0;K, A>ACI5AB2CNI85 A :>@C=4><, 8<5NB A;54CNI89 A>AB02 (B01;.): ?;038>:;07 ?@54AB02;5= >;83>:;07>< ! 22 24, >4=0:>, 2AB@5G0NBAO 8 @5;8:B>2K5 75@=0 ;01@04>@0 !66, 3@0=0B ?@54AB02;5= ?@><56CB>G=K<8 G;5=0<8 @O40 ?8@>?-0;L<0=48=: 0;L<0=48=>20O A>AB02;ONI0O 4>AB8305B 60%, ?8@>?>20O 28 31%, A;N40 D;>3>?8B, ?@0:B8G5A:8 ?>AB>O==>3> A>AB020, >B;8G0NI89AO 2KA>:>9 3;8=>75<8AB>ABLN A 2KA>:8< A>45@60=8O 0;N<8=8O :0: 2 >:B0M4@8G5A:8E B0: 8 B5B@0M4@8G5A:8E ?>78F8OE. >@C=4, :0: ?@028;>, ?@8C@>G5= : ?;038>:;07>2K< CG0AB:0< ?>@>4, >1@07C5B ?@87<0B8G5A:85 AB>;1G0BK5 8;8 87><5B@8G=K5 :@8AB0;;K >B 2 << 4> 5 A<, G0AB> A 2:;NG5=8O<8 ?;038>:;070, D;>3>?8B0 8 3@0=0B0.  ?>@>40E B0:65 2AB@5G0NBAO :@8AB0;;K 48AB5=0 8 0<D81>;0. B<5G5==0O ?>GB8 2> 2A5E 3;02=KE ?>@>4>>1@07CNI8E <8=5@0;0E :>@C=4-A>45@60I8E ?>@>4 ?>2KH5==0O 3;8=>75<8AB>ABL 8 <03=5780;L=>ABL :>A25==> C:07K205B =0 2KA>:>5 402;5=85, 8<52H55 <5AB> ?@8 8E :@8AB0;;870F88. E 25;8G8=K, @0AAG8B0==K5 ?> 35>10@><5B@0< .. 5@GC:0, A>AB02;ONB >B 7 4> 9 :10@, 0 B5<?5@0BC@K 600 650(!. 7 2KH587;>65==KE 40==KE A;54C5B, GB> >1@07>20=85 :>@C=40 A2O70=> A ?@>F5AA0<8 ?@5>1@07>20=8O <8=5@0;L=>3> A>AB020 ?>@>4 =0 :>=B0:B0E >A=>2=KE (?;038>:;07>2KE 0<D81>;8B>2) 8 :8A;KE 3=59A>2.  E>45 MB8E ?@>F5AA>2 0<D81>; 8 ;01@04>@ 70<5I0NBAO D;>3>?8B><, >;83>:;07><, 3@0=0B><, 48AB5=>< 8 :>@C=4>< 157 ACI5AB25==>3> ?@82=>A0-2K=>A0 8=5@B=KE :><?>=5=B>2. 5>1E>48<K9 4;O >1@07>20=8O :>@C=40, 0 B0:65 2KA>:>3;8=>75<8AB>3> D;>3>?8B0 8 48AB5=0 871KB>G=K9 0;N<8=89 2KA2>1>640;AO 2 @57C;LB0B5 ?@>F5AA>2 450=>@B870F88 ;01@04>@0 !66, 70<5I05<>3> >;83>:;07>< !23. 71KB>G=K9 :0;LF89 8 0;N<8=89 D8:A8@>20;8AL 3@0=0B><, 2 :>B>@>< 65;57> 8 <03=89 708<AB2>20;8AL ?@8 >4=>2@5<5==>< 70<5I5=88 0<D81>;>2. 4=0:> 1>;LH0O G0ABL 2KA2>1>6405<>3> ?@8 70<5I5=88 0<D8<1>;>2 <03=8O 8 65;570, 0 B0:65 G0ABL 0;N<8=8O 87 ;01@04>@0 CA20820;0AL D;>3>?8B><. 0AA5O==K9 2 0<D81>;8B0E E@>< ?5@5@0A?@545;O;AO <564C D;>3>?8B><, 3@0=0B>< 8 :>@C=4>< =5@02=><5@=>, A O2=K< ?@54?>GB5=85< 2 ?>;L7C :>@C=40. 5@5@0A?@545;5=85 65;570 2 MB8E 65 <8=5@0;0E, =0>1>@>B, A<5I5=> 2 AB>@>=C A8;8:0B>2, >A>15==> 3@0=0B0. >MB><C E@><>D>@=K5 A2>9AB20 E@><0 2 :>@C=45 ?@>O28;8AL 157 ACI5AB25==>3> 30AOI53> 2;8O=8O 65;570.  A8;8:0B0E 65 MB0 DC=:F8O >:070;0AL ?>;=>ABLN 70BCH520==>9 87-70 2KA>:>3> A>45@60=8O 65;570. >@C=4-A>45@60I85 ?>@>4K, A;030NI85 ?@>O2;5=85 O48=0 3>@0, ?@54AB02;5=K 3@0=0B>2K<8 0<D81>;8B0<8, :>B>@K5 =0E>4OBAO =0 :>=B0:B5 3011@> 8 3;8=>75<8ABKE 3=59A>2 [1]. <D81>;8BK A>AB>OB, 2 >A=>2=><, 87 0<D81>;0, D;>3>?8B0 A 2:@0?;5==K<8 75@=0<8 3@0=0B0, :80=8B0 8 :>@C=40 8 :0@1>=0B0. 7CG5=85 E8<8G5A:>3> A>AB020 <8=5@0;>2 ?>:070;> (B01;.), GB> 0<D81>; ?@54AB02;5= 2KA>:><03=5780;L=K< G5@<0:8B>< 87 :0;LF852>9 3@C??K 0<D81>;>2. %0@0:B5@=> ?>2KH5==>5 A>45@60=85 0;N<8=8O :0: 2 >:B0M4@8G5A:8E, B0: 8 2 B5B@0M4@8G5A:8E ?>78F8OE. @0=0B ?@54AB02;5= ?@><56CB>G=K<8 G;5=0<8 @O40 0;L<0=48=-?8@>?, A>>B=>H5=85 0;L<0=48=>2>3> 8 ?8@>?>2>3> <8=0;>2 2:1, A>45@60=85 3@>AAC;O@>2>3> <8=0;0 4>AB8305B 15%.  A>AB025 H?8=5;8 87 42CE20;5=B=KE :0B8>=>2 ?@8ACBAB2C5B <03=89 8 65;57>, 0 87 B@5E20;5=B=KE 2 >A=>2=>< 0;N<8=89 8 =51>;LH0O ?@8<5AL E@><0. >@C=4 >1@07C5B :A5=><>@D=K5 2K45;5=8O, 8=>340 2 A@0AB0=88 A :80=8B><, @07<5@>< 4> =5A:>;L:8E A<. &25B 75@5= >B @>7>2>3> 4> @>7>2>-:@0A=>3>. > 2:;NG5=8OE 2AB@5G05BAO 0<D81>; 8 H?8=5;L. "01;8F0 8=5@0;L=K5 0AA>F80F88 :>@C=4A>45@60I8E ?>@>4 Mineral associations of rocks with corundum @>O2;5=85 :>@C=408=5@0;K!@54=89 A>AB02%8B>AB@>2 (!525@=0O 0@5;8O);038>:;07(Na0,78Ca0,24)1,02[(Al1,26Si2,74)4,00O8](Na0,33Ca0,66)0,99([Al1,67Si2,32]3,99O8)$;>3>?8B(K0,64Na0,24)0,88(Mg1,76Fe0,66 Al0,46Ti0,09Cr0,02)2,99[(Al1,33Si2,67)4,00O10](OH,F)2@0=0B(Fe2+1,70Mg0,92Ca0,33Mn0,01)2,96(Al1,91Fe3+0,09)2[Si3,00O12]O48=0 3>@0 (!525@=0O 0@5;8O)<D81>;(Ca1,63Na0,36K0,02)2,01(Mg3,17Fe0,91Al0,75Cr0,11Ti0,05)4,99[(Si6,48Al1,52)8,00O22](OH,F)2@0=0B(Fe2+1,41Mg0,98Ca0,50Mn0,09)2,98(Al2,02Cr0,02)2,04[Si3,00O12](?8=5;L(Mg0,81Fe2+0,19)1,00(Al1,98Cr0,02)2,00O480=8B(Al1,98Fe0,01Cr0,01)2SiO5@8<5G0=85. @8AB0;;>E8<8G5A:85 D>@<C;K @0AAG8B0=K ?> @57C;LB0B0< <8:@>7>=4>2KE 0=0;87>2 (Camebax SX 50) !>AB02 <8=5@0;L=KE 0AA>F80F89 ?@>O2;5=8O O48=0 >@0 >?@545;O5BAO A;54CNI8<8 >A=>2=K<8 D0:B>@0<8: A>AB02>< 8AE>4=KE ?>@>4, 0 B0:65 D878:>-E8<8G5A:8<8 CA;>28O<8 8 8=B5=A82=>ABLN ?@>O2;5=8O @07;8G=KE <5B0A><0B8G5A:8E D0F89 2 548=>< ?@>F5AA5.  40==>< ?@>O2;5=88 ?@5>1;040NI5< @0728B85< ?>;L7CNBAO <8=5@0;L=K5 0AA>F80F88 >1>30I5==K5 Mg, Fe, Al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mailto:mv@ilmeny.ac.ru mv@ilmeny.ac.ru Muftakhov V.A. Heterogeneities of aeshenite chemical composition from mine 210 of Ilmeny reservation (Institute of Mineralogy of RAS, Miass, Russia) The heterogeneities of chemical composition of aeshenite crystals from feldspathic zone in miaskite pegmatite of Ilmeny reservation have been investigated. The %-ray spectral microanalysis JCXA-733 was used for study of it. It is established that the contents of Nb2O5, TiO2, ThO2, TR2O3 are different in center and periphery of crystals. The contents Nb2O5, ThO2 are more and TiO2, TR2O3 are less in the periphery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m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m < 110> A>45@60=85 B8B0=0 C1K205B ?> =0?@02;5=8N >B F5=B@0 :@8AB0;;0 : ?5@8D5@88 8 2>7@0AB05B ;8HL 2 :@09=59 B>G:5 1m , 0 A>45@60=85 =8>18O A>>B25BAB25==> 2>7@0AB05B, C1K20O =0 ?5@8D5@88 :@8AB0;;0. 4>;L ?@>D8;O m<110> 87<5=5=8O :>=F5=B@0F88 B8B0=0 8 =8>18O =57=0G8B5;L=K (@8A.40,1). 7<5=5=85 A>45@60=89 B>@8O 8 @54:>75<5;L=KE M;5<5=B>2 2708<>>1@0B=K. >;8G5AB2> B>@8O 2>7@0AB05B : ?5@8D5@88 :@8AB0;;0 A 17 4> 20 22 <0A.%, 0 -  C1K205B A 23 4> 20 <0A.% (@8A. 4). !>45@60=85 65;570 8 B0=B0;0 24>;L MB8E ?@>D8;59 =5 <5=O5BAO. > 40==K< 0=0;87>2 <8=5@0; A>>B25BAB2C5B MH8=8BC-(!5) [2] A =5A:>;L:> ?>2KH5==K< A>45@60=85< =8>18O. @8 ?5@5AG5B5 @57C;LB0B>2 ?>;CG5=K A;54CNI85 M<?8@8G5A:85 D>@<C;K (@0AG5B =0 3 :0B8>=0): (TR0,53Th0,27Ca0,20)1,00(Ti1,07Nb0,89Fe0,03Ta0,01)2,00O5,97  4;O 0=0;870 A <8=8<0;L=K< A>45@60=85< =8>18O; (TR0,52Th0,28Ca0,21)1,01(Nb1,04Ti0,89Fe0,05Ta0,01)1,99O6,00  4;O 0=0;870 A <0:A8<0;L=K< A>45@60=85< =8>18O. "0:8< >1@07><, 2 :@8AB0;;0E MH8=8B0 =01;N405BAO =0?@02;5==>5 87<5=5=85 @0A?@545;5=8O M;5<5=B>2 >B F5=B@0;L=>9 G0AB8 :@8AB0;;>2 : :@052K< 7>=0<. 4=0:> 25;8G8=0 MB8E 87<5=5=89 =57=0G8B5;L=0. 8A. 4 @0D8:8 @0A?@545;5=8O TiO2, Nb2O5, ThO2 8 TR2O3 2 ?8@0<840E =0@0AB0=8O m<110> (0) 8 m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nik@ilmeny.ac.ru Nickandrov S.N., Kobyashev Yu.S., Valizer P.M. List of the Ural s amphiboles (Ilmen State Reserve, Ural. Div. RAS, Miass, Russia). The analysis of the published data on the Ural amphibole compositions was taken on the base of the matrix model of amphibole nomenclature. There are 52 end members from them 42 normative amphiboles, 10 analogues. The Ural amphiboles present in practice all known for today series excluding nybite series. Short characteristics of some series are given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aluminobarroisite); 5==KE .., 1966: (Na,25K,07),32(Ca1,09Na,91)2[(Mg2,62Fe2+,79)3,41(Al1,04Fe3+,51Ti,04)1,59]5(Si7,18Al,82)8O22(OH1,75O,25)2 ;N<8=><03=578>A040=0308B (alumino-magnesiosadanagaite); >;5A=8: ..., 1976: (Na,61K,10),71(Ca1,59Mg,41)2[(Mg2,55Fe2+,60Mn,04)3,19(Al,99Fe3+,68Ti,14)1,81]5(Si5,34Al2,66)8O22(OH)2 ;N<8=><03=578>B0@0<8B (alumino-magnesiotaramite); #4>2:8=0 ,., 1962: K,12(Ca1,21Na,75)1,96[(Fe2+1,96Mg1,46Mn,01)3,43(Al,80Fe2+,67Ti,10)1,57]5(Si6,63Al1,37)8O22(OH)2,13 ;N<8=>D5@@>10@@C078B (alumino-ferrobarroisite); CB8= .., 1974: (Na,15K,04),19(Ca1,81Na,19)2[(Fe2+1,75Mg1,67Mn,03)3,45(Al1,13Fe3+,30Ti,12)1,55]5(Si6,30Al1,70)8O22(OH)2 ;N<8=>D5@@>G5@<0:8B (alumino-ferrotschermakite); >@8=52A:89 .. 8 4@., 2001: (Na,15K,04),19(Ca1,81Na,19)2[(Fe2+1,75Mg1,67Mn,03)3,45(Al1,13Fe3+,30Ti,12)1,55]5(Si6,30Al1,70)8O22(OH)2 ;N<8=>G5@<0:8B (aluminotschermakite); 528=A>=-5AA8=3 $..., 1900: Na,38(Ca1,52Na,48)2[(Mg2,44Fe2+,56)3,0(Al1,06Fe3+,94)2,0]5(Si6,10Al1,90)8O22(OH)2 =B>D8;;8B (anthophyllite); !8<>=>2 .., 1949: %(Mg5,72Fe2+1,04Fe3+,14Ca,10)7,(Si7,85Fe3+,15)8O22(OH)2 @D254A>=8B (arfvedsonite); 065=>2 .. 8 4@., 2001: (Na,49K,26),75(Na1,81Ca,19)2[(Fe2+3,13Mn,35Mg,06)3,54(Fe3+1,31Ti,15)1,46]5(Si7,55Al,35Fe3+,10)8O22 (OH1,77F,23)2 8=G8B (winchite); 0;875@ .. XE "0;875@ .."  8 4@., 1982: K,07(Ca,68Na1,28)1,95[(Mg2,55Fe2+,78Mn,01)3,34(Al1,29Fe3+,28Ti,09)1,66]5(Si7,57Al,43)8O22(OH)2 0AB8=3A8B (hastingsite); 065=>2 .. 8 4@., 1982: (Na,42K,36),78(Ca1,82Na,18)2[(Fe2+2,0Mg1,69Mn,12)3,81(Fe3+,87Al,14Ti,18)1,19]5(Si6,08Al1,92)8O22 (OH1,78F,17O,05)2 ;0C:>D0= (glaucophane); '5A=>:>2 .., 1961: (Na,02K0,01),03(Na1,74Ca,26)2[(Mg2,33Fe2+,51Mn,02)2,76(Al1,63Fe3+,59Ti,01Cr,01)2,24]5(Si7,67Al,33)8O22(OH)2 @N=5@8B (grunerite); '51>B0@520 .., 1974: Na,04(Fe2+4,23Mg2,36Fe3+,14Ca,10Mn,05Al,02)7,(Si7,80Al,20)8O22(OH)2 54@8B (gedrite); >@8=52A:89 .., 1997: Na,34(Mg3,49Fe2+1,36Ca,08Mn,06Na,01)5(Al1,03Fe3+,95Ti,02)2(Si6,46Al1,54)8O22(OH,O)2 0;8930AB8=3A8B (potassichastingsite); 528= ./., 1974: (K,50Na,45),95(Ca1,54Na,46)2[(Fe2+1,85Mg1,59Mn,10)3,54(Fe3+1,01Al,28Ti,17)1,46]5(Si6,02Al1,98)8O22 (OH1,86O,14)2 0;89A040=0308B (potassicsadanagaite); 065=>2 .. 8 4@., 1999: (K,65Na,27),92(Ca1,72Na,28)2[(Fe2+2,15Mg,55Mn,25)2,95(Fe3+1,11Al,75Ti,19)2,05]5(Si5,31Al2,69)8O22 (OH1,39F,40O,41)2,20 0;89D5@@8<03=578>:0B>D>@8B (potassic-ferri-magnesiokatophorite); >B<0= .-., 1956: (K,28Na,27),55(Ca1,29Na,71)2[(Mg3,0Fe2+1,21Mn,12)4,33Fe3+,67]5(Si7,04Al,88Ti,08)8O22(OH)2 0;89D5@@8B0@0<8B (potassic-ferritaramite); 528= ./., 1974: (K,45Na,39),84(Ca1,36Na,64)2[(Fe2+2,02Mg1,13Mn,07)3,22(Fe3+1,17Al,52Ti,09)1,78]5(Si5,84Al2,16)8O22 (OH1,50F,35O,15)2 0;89D5@@>?0@30A8B (potassic-ferropargasite); 02B>@A:85 40==K5, 2002: (K,43Na,24)0,67Ca2,05[(Fe2+1,88Mg1,73)3,61(Al,81Fe3+,41Ti,17)1,39]5(Si5,54Al2,46)8O22(OH)2 C<<8=3B>=8B (cummingtonite); '51>B0@520 .., 1974: (Na,05K,01),09(Mg5,72Fe2+1,14Ca,11Al,03)7(Si7,96Al,04)8O22(OH)2 03=578>0@D254A>=8B (magnesio-arfvedsonite); =4@552 ..., 1957: (Na,35K,32),67(Na1,79Ca,19Mg,02)2[(Mg3,68Fe2+,26)3,94Fe3+1,06]5(Si7,94Al,03Fe3+,03)8O22(OH)2,40 03=578>30AB8=3A8B (magnesiohastingsite); >B<0= .-., 1956: (Na,62K,27),89Ca2,02[(Mg2,40Fe2+1,54Mn,04)3,98(Fe3+,71Ti,28Al,03)1,02]5(Si6,31Al1,69)8O22(OH1,46F,54)2 03=578>3>@=1;5=48B (magnesiohornblende); #4>2:8=0 .., 1962: (Na,30K,11),41(Ca1,61Na,39)2[(Mg3,65Fe2+,49Mn,01)4,15(Al,74Fe3+,06Ti,03Cr,02),85]5(Si6,78Al1,22)8O22(OH)2 03=578>:0B>D>@8B (magnesiokatophorite); KAB8= .. 8 4@., 1983: (Na,53K,12),65(Ca1,46Na,54)2[(Mg2,02Fe2+1,52)3,54(Al1,07Fe3+,25Ti,14)1,46]5(Si6,61Al1,39)8O22(OH)2 03=578>@815:8B (magnesioriebeckite); D8<>2 .$. 8 4@., 1973: K,38(Na1,58Ca,26)1,84[(Mg2,07Fe2+1,05Mn,12)3,24(Fe3+1,51Al,15Ti,10)1,76]5(Si7,94Al,06)8O22(OH1,39F,33O,28)2 03=578>A040=0308B (magnesiosadanagaite); >;5A=8: ..., 1976: (Na,50K,12),62(Ca1,68Mg,32)2[(Mg3,12Mn,02)3,14(Fe3+1,05Al,76Ti,05)1,86]5(Si5,47Al2,53)8O22(OH)2 0=30=>:C<<8=3B>=8B (manganocummingtonite); 5;:>2A:89 .. 8 4@., 1977: (Na,02K,01),03(Mn2+1,64Ca,36)2(Mg3,80Fe2+,70Mn2+,48Al,02)5(Si7,99Al,01)8O22(OH,O)2 0B@89654@8B (sodicgedrite); KAB8= .., 1978: Na,53(Mg3,39Fe2+2,12Ca,09Mn,03)5,63(Al1,07Fe3+,25Ti,04)1,36(Si6,35Al1,65)8O22(OH,O)2 0B@89D5@@8654@8B (sodic-ferrigedrite); 20=>2 .., 1997: (Na,50K,30),80(Mg5,30Fe2+,80Ca,08Mn,02)6,20(Fe3+,50Ti,20Al,10V,01),81(Si6,46Al1,54)8O22(OH1,60F,04)1,64 0@30A8B (pargasite); >;5A=8: ..., 1976: (Na,84K,17)1,01[(Ca1,92Na,08)2(Mg3,29Fe2+1,03Mn,02)4,34(Al,63Ti,03),66]5(Si6,48Al1,52)8O22(OH)2 815:8B (riebeckite); 5;:>2A:89 .. 8 4@., 1974: (K,33Na,10),43(Na1,94Ca,06)2[(Fe2+2,67Mg,14Li,11Mn,01)2,93(Fe3+1,83Ti,13Al,11)2,07]5(Si7,69Al,31)8O22 (OH1,89F,04)1,93 8EB5@8B (richterite); >B<0= .-., 1956: (Na,38K,15),53(Ca1,0Na1,0)2(Mg2,64Fe2+1,37Mn,10Fe3+,87Ti,02)5(Si7,53Al,45Ti,02)8O22(OH)2 !040=0308B (sadanagaite); 065=>2 .. 8 4@., 1988: (Na,52K,46),98(Ca1,87Na,13)2[(Fe2+2,46Mg,76Mn,21)3,43(Fe3+,75Al,64Ti,18)1,57]5(Si5,39Al2,61)8O22(OH)2 "@5<>;8B (tremolite); @H8=>2 .., 1936: %(Ca1,97Na,03)2(Mg4,77Fe2+,22Mn,11)5(Si7,87Al,11Fe3+,02)8O22(OH)2 $5@@810@@C078B (ferribarroisite); >B<0= .-., 1956: (Na,31K,06),37(Ca1,36Na,64)2[(Mg3,0Fe2+,36Mn,13)3,49Fe3+1,51]5(Si6,96Al0,75Fe3+0,23Ti,06)8O22(OH,O)2 $5@@828=G8B (ferriwinchite); 065=>2 .. 8 4@., 1982: K,11(Ca,68Na1,32)2[(Mg2,79Fe2+,97Mn,07)3,83(Fe3+1,0Al,16Ti,01)1,17]5(Si7,76Al,24)8O22(OH1,45F,33O,22)2 $5@@8<03=578>3>@=1;5=48B (ferri-magnesiohornblende); ><8=8:>2A:89 .., 1971: (Na,19K,06),25(Ca1,81Na,19)2[(Mg2,18Fe2+1,78Mn,04)4(Fe3+,55Al,29Ti,16)1]5(Si6,52Al1,48)8O22(OH,O)2 $5@@8<03=578>:0B>D>@8B (ferri-magnesiokatophorite); 528= ./., 1974: (Na,40K,20),60(Ca1,0Na1,0)2[(Mg2,93Fe2+1,13Mn,04)4,10(Fe3+,80Ti,10),90]5(Si7,50Al,50)8O22(OH1,30F,40O,30)2 $5@@8<03=578>B0@0<8B (ferri-magnesiotaramite); 065=>2 .. 8 4@., 1982: (Na,39K,35),74(Ca1,48Na,52)2[(Mg1,85Fe2+1,34Mn,23)3,42(Fe2+1,45Ti,10Al,03)1,58]5(Si6,20Al1,80)8O22 (OH1,75F,25)2 $5@@8B0@0<8B (ferritaramite); >=5=A>= .., 1966: (Na,58K,43)1,01(Ca1,42Na,58)2[(Fe2+1,71Mg1,38Mn,22)3,31Fe3+1,69]5(Si6,17Al1,83)8O22(OH1,91O,09)2 $5@@8D5@@>10@@C078B (ferri-ferrobarroisite); 5;:>2A:89 .. 8 4@., 1981: (K,37Na,01),38(Ca1,47Na,53)2[(Fe2+2,91Mg,13Mn,05)3,09(Fe3+1,0Al,80Ti,11)1,91]5(Si6,62Al1,38)8O22(OH,O)2 $5@@8D5@@>G5@<0:8B (ferri-ferrotschermakite); /:>2;520 .., 1941: (K,11Na,05),16(Ca1,67Na,33)2[(Fe2+2,10Mg1,17Mn,04)3,31(Fe3+1,10Al,55Ti,04)1,69]5(Si6,47Al1,53)8O22(OH)2 $5@@8G5@<0:8B (ferritschermakite); $8H<0= .. 8 4@., 1966: (K,06Na,03),09(Ca1,54Na,46)2[(Mg2,74Fe2+,20Mn,02)2,96(Fe3+1,40Al,55Ti,09)2,04]5(Si6,24Al1,76)8O22(OH,O)2 $5@@>0:B8=>;8B (ferro-actinolite); A>;>4:8=0 .., 1973: K,01(Ca1,88Na,04Mg,07)2(Fe2+2,33Mg2,07Mn,17Al,43)5(Si7,63Al,37)8O22(OH)2 $5@@>3;0C:>D0= (ferroglaucohane); >1@5F>2 .., 1974: Na,08(Na1,77Ca,23)2[(Fe2+1,64Mg1,36)3(Al1,74Fe3+,26)2]5(Si7,80Al,20)8O22(OH,O)2 $5@@>3>@=1;5=48B (ferrohornblende); 5;:>2A:89 .. 8 4@., 1981: K,31(Ca1,39Na,43)1,82[(Fe2+3,22Mg,20Mn,10)3,52(Al,90Fe3+,48Ti,10)1,48]5(Si6,90Al1,10)8O22(OH)2 $5@@>M45=8B (ferro-edenite); 065=>2 .. 8 4@., 1982: (Na,45K,29),74(Ca1,75Na,25)2(Fe2+3,75Mn,24Mg,23Fe3+,36Al,29Ti,13)5(Si6,73Al1,27)8O22(OH,F)2 $B>@>:0;8930AB8=3A8B (fluoro-potassichastingsite); 065=>2 .., 1992: (K,51Na,43),94(Ca1,58Na,42)2[(Fe2+2,01Mg1,60Mn,20)3,81(Fe3+,93Al,17Ti,09)1,19]5(Si6,31Al1,69)8O22 (F1,13OH,87)2 $B>@>:0;89@8EB5@8B (fluoro-potassicrichterite) 20=>2 .. 8 4@., 1978: (K,31Na,29),60(Ca1,16Na,84)2(Mg2,14Fe2+1,65Mn,14Fe3+,88Al,13Ti,06)5(Si7,55Al,45)8O22(F,77O,67OH,56)2 $B>@><03=578>0@D254A>=8B (fluoro-magnesio-arfvedsonite); 065=>2 .. 8 4@., 2000: (Na,42K,16),58(Na1,50Ca,50)2[(Mg3,82Fe2+,34Mn,05)4,21(Fe3+,77Ti,02),79]5(Si7,76Al,21Fe3+,03)8O22 (F1,29OH,49)1,78 $B>@>@8EB5@8B (fluororichterite); 065=>2 .. 8 4@., 1993: (Na,44K,20),64(Ca1,27Na,73)2(Mg3,93Fe2+,64Mn,08Fe3+,35)5(Si7,78Al,20Ti,01Fe3+,01)8O22(F1,50OH,50)2 $B>@>D5@@>M45=8B (fluoro-ferro-edenite); 065=>2 .., 1992: (Na,80K,32)1,12(Ca1,87Na,13)2(Fe2+2,37Mg2,24Mn,07Fe3+,30Ti,02)5(Si6,54Al1,40Ti,06)8O22(F1,13OH,87)2 -45=8B (edenite); !8<>=>2 .., 1949: (Na,43K,10),53(Ca1,76Na,24)2(Mg4,67Fe2+,06Mn,03Fe3+,23Ti,01)5(Si7,46Al,42Fe3+,12)8O22(OH)2 %0@0:B5@8AB8:0 =5:>B>@KE A5@89 0<D81>;>2: A5 0<D81>;K #@0;0, >?8A0==K5 ?>4 =0720=85<  654@8B , A>>B25BAB2CNB =0B@89654@8BC, 548=AB25==K9 :>@@5:B=K9 0=0;87 654@8B0 ?@82545= >@8=52A:8< .. 2 19973. (A<. A?8A>:).  =><5=:;0BC@5 8:0 [4] 8 2  <0B@8G=>9 <>45;8 [2] 4;O A5@88 =0B@89654@8B0 ?@82>48BAO 420 :>=5G=KE G;5=0: =0B@89654@8B 8 =0B@89D5@@>654@8B, ?@8 =><5=:;0BC@=>< 0=0;875 C@0;LA:8E 0<D81>;>2 CAB0=>2;5= B@5B89 G;5= (?> B@5E20;5=B=><C :0B8>=C ?>78F88 !)  =0B@89D5@@8654@8B, B5< A0<K< >B:@K205BAO ?>;=0O A5@8O =0B@89654@8B0. -45=8BK, @0=55 AG8B02H85AO A><=8B5;L=K<8 (A<. A?@02>G=8:  8=5@0;K , ". III, K?. 3), =0 #@0;5 ?@54AB02;5=K ?>;=>9 A5@859, @54:>ABLN =5 O2;ONBAO. !5@8O A040=0308B0 ?@54AB02;5=0 B@5<O :>=5G=K<8 G;5=0<8 8 E0@0:B5@=0 4;O I5;>G=KE :><?;5:A>2. ;O A5@88 3>@=1;5=48B0 2 =><5=:;0BC@5 8:0 [4] ?@82>4OBAO 420 :>=5G=KE G;5=0  >10 H8@>:> @0A?@>AB@0=5=K =0 #@0;5.   <0B@8G=>9 <>45;8 [2] MB0 A5@8O 4>?>;=5=0 5I5 42C<O :>=5G=K<8 G;5=0<8, >48= 87 :>B>@KE, D5@@8<03=578>3>@=1;5=48B, B0:65 O2;O5BAO @0A?@>AB@0=5==K<. !5@8O G5@<0:8B0 ?@54AB02;5=0 G5BK@L<O =>@<0B82=K<8 :>=5G=K<8 G;5=0<8. !5@8O :0B>D>@8B0 ?@54AB02;5=0 42C<O 4>AB>25@=> CAB0=>2;5==K<8 :>=5G=K<8 G;5=0<8. !5@8N B0@0<8B0 ?@54AB02;NB B@8 =>@<0B82=KE G;5=0 8 >48= 0=0;>3  :0;89D5@@8B0@0<8B, 0=0;878@>20==K9 5;O=:8=K< .!. 2 1909 3>4C. !5@8O 10@@C078B0 ?@54AB02;5=0 G5BK@L<O =>@<0B82=K<8 :>=5G=K<8 G;5=0<8, 87 =8E 4;O D5@@8D5@@>10@@C078B0 8725AB5= 548=AB25==K9 0=0;87. !5@8N M:5@<0==8B0-0@D254A>=8B0 ?@54AB02;O5B @O4 <03=578>0@D254A>=8B0-0@D254A>=8B0. 03=578>0@D254A>=8B 8725AB5= 2 ?@><KH;5==KE :>;8G5AB20E (<5AB>@>645=8O 3>;C1KE 0A15AB>2 =0 !@54=5< #@0;5).  ;8B5@0BC@5 ?> #@0;C H8@>:> ?@8<5=O5BAO =0720=85  0@D254A>=8B , => ?5@2K9 0=0;87 53> ?@54AB02;5= 065=>2K< .. B>;L:> 2 2001 3>4C.  2000 3>4C 2 :0G5AB25 =>2>3> <8=5@0;L=>3> 2840  CB25@645= DB>@><03=578>0@D254A>=8B. <D81>;K A5@88 3;0C:>D0=0-@815:8B0 O2;ONBAO @0A?@>AB@0=5==K<8, E0@0:B5@=K 4;O 35>;>38G5A:8E >1J5:B>2 D0F89 2KA>:8E 402;5=89. AA;54>20=8O ?>445@60=K $$ 8 4<8=8AB@0F859 '5;O18=A:>9 >1;. (?@>5:B 01 05 96418). 8B5@0BC@0: 1.8:0=4@>2!., 0;875@., >1OH52..! 0B@8G=0O <>45;L =><5=:;0BC@K 0<D81>;>2 // 72. '5;O1. =0CG=>3> F5=B@0, 1999. K?. 1. !. 40 47. 2.8:0=4@>2!.., >1OH52..!., 0;875@.. 0B@8G=0O <>45;L ?@54AB02;5=8O 0<D81>;>2 // , 2000. ! 4. !.105 112. 3.8:0=4@>2!.., >1OH52..!., 0;875@.. <D81>;K ;L<5=>3>@A:>3> :><?;5:A0. 80AA:  #@ , 2000. 120A. 4.Leak B. E. et al. Nomenclature of amphiboles: report of the Subcommittee on amphiboles of the International Mineralogical Association, Commission on new minerals and mineral names // Can. Min. 1997. V. 35. N1. P.219 246. "# -!#,$ !      '-"'!% #  +! # // (.+ # ) >2>A5;>2 .. XE ">2>A5;>2 .." , 5;>3C1 .. XE "5;>3C1 .." , >B;O@>2 .. XE ">B;O@>2 .."  8= #@ , 3. 80AA, >AA8O, const@ilmeny.ac.ru, bel@ilmeny.ac.ru Novoselov C.A., Belogub E.V., Kotlyarov V.A. Telluride-sulphide of copper and silver from pyretic-polimetallic ores of Babarykino manifistation, the South Urals (IMin UB RAS, Russia). The telluride-sulphide of copper and silver with average (for 9 mycroprobe analysis) formula (Cu0.49Ag1.49)1.98(S0.67Te0.33)1.00 was discovered at the first in banded shpalerite-barite ores with accessory galena, bornite and tennantite. Mineral has a greenish gray color, imRref=34.5% (white light), It is characterized with theabsence of internal reflections, very low anisotropy in oil, VHN10= 44.5:3A/<<2. It may be presented as mixture of hessite, chalcosite and akantite and need of future crystal-chemical study. 010@K:8=A:>5 :>;G540==>-?>;8<5B0;;8G5A:>5 @C4>?@>O2;5=85 @0A?>;>65=> 2 ;5:A0=4@8=A:>< @C4=>< @09>=5 ('5;O18=A:0O >1;.), >B:@KB> 2 19493. .6=>9  B@5AB0  0H7>;>B> ?> M;N280;L=>-45;N280;L=K< @0720;0< 1C@KE 65;57=O:>2. !?;>H=K5 <54=>-F8=:>2K5 @C4K 1K;8 ?>4A5G5=K ?@8 ?>8A:>2>-@07254>G=KE @01>B0E ?>4 @C:>2>4AB2>< .C.(B59=15@30.  20013. ;5:A0=4@8=A:>9   =0 @C4>?@>O2;5=88 1K;8 8=8F88@>20=K >F5=>G=K5 @01>BK, 402H85 C=8:0;L=K9 <8=5@0;>38G5A:89 <0B5@80;. C4K ?@54AB02;5=K ?@58<CI5AB25==> 2:@0?;5==K<8, ?@>68;:>2>-2:@0?;5==K<8 8, @565, A?;>H=K<8 ?>;>AG0BK<8 @07=>ABO<8. > <8=5@0;>38G5A:><C A>AB02C @0745;ONBAO =0 ?8@8B>2K5, ?8@8B-30;5=8B-E0;L:>?8@8B-AD0;5@8B>2K5, AD0;5@8B-10@8B>2K5, ?8@8B-10@8B>2K5. ;02=K5 @C4=K5 <8=5@0;K: AD0;5@8B, E0;L:>?8@8B, 1>@=8B, 10@8B, ?8@8B; 2B>@>AB5?5==K5: 30;5=8B, B5==0=B8B; @54:85: A0<>@>4=>5 7>;>B> 8 D070 A>AB020 Ag Te !u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ref D>B><5B@8G5A:8< A?>A>1>< =0 <8:@>A:>?5 NU2 (Carl Zeiss) >A=0I5==>< A5;5=>2K< D>B>M;5<5=B>< 8 30;L20=><5B@><. 7<5@5=8O ?@>2>48;8AL 2 8<<5@A88 (Cargille) 4;O 15;>3> A25B0. 0 MB0;>= CA;>2=> 1K; ?@8=OB ?8@8B (Rst=53%). > @57C;LB0B0< 87<5@5=89 Rref=34,52%. &25B 2 >B@065==>< A25B5 A5@K9 A> A;01K< 75;5=>20BK<, 3>;C1>20B>-75;5=>20BK< >BB5=:><. -DD5:B>2 0=87>B@>?88 8 42C>B@065=8O 2 2>74CE5 =5 =01;N405BAO =8 2 >4=>< 87 87CG5==KE A5G5=89.  <0A;5 0=87>B@>?8O >G5=L A;010O, 2>7<>6=>, 2K720=0 45D5:B0<8 ?>;8@>2:8. =CB@5==85 @5D;5:AK =5 >B<5G0;8AL =8 2 2>74CE5, =8 2 <0A;5. 5;L5D =5A:>;L:> =865 30;5=8B0. B?5G0B>: ?8@0<84:8 8::5@A0 ?@O<>9 8;8 A;01>2K?C:;K9, 2>:@C3 >B?5G0B:0 =01;N405BAO :>=F5=B@8G5A:8-@0:>28AB0O B@5I8=>20B>ABL. !@54=OO <8:@>B25@4>ABL, 87<5@5==0O 4;O =03@C7:8 103, A>AB02;O5B VHN10= 44,5:3A/<<2 8 20@L8@C5B >B 40,7 4> 47,2:3A/<<2. >MDD8F85=B 0=87>B@>?88 B25@4>AB8 KVHN 1;87>: : 1. "01;8F0 %8<8G5A:89 A>AB02 Ag Cu S Te <8=5@0;0 !0B@8F0SCuAgTeFormula1B8,0413,4461,0217,56(Cu0,54Ag1,46)2,00(S0,65Te0,35)1,002B8,1114,4060,5917,00(Cu0,59Ag1,45)2,05(S0,65Te0,35)1,003G8,4311,2863,5016,77(Cu0,45Ag1,49)1,94(S0,67Te0,33)1,004Bg8,2511,6763,1616,91(Cu0,47Ag1,50)1,97(S0,66Te0,34)1,005G8,6811,4363,7116,26(Cu0,45Ag1,48)1,93(S0,68Te0,32)1,006Bg8,5111,7464,2615,61(Cu0,48Ag1,54)2,02(S0,68Te0,32)1,007Bg8,5213,6061,4216,76(Cu0,54Ag1,43)1,97(S0,67Te0,33)1,008B8,1912,0964,1115,81(Cu0,50Ag1,57)2,07(S0,67Te0,33)1,009G8,7610,0565,0716,09(Cu0,40Ag1,51)1,91(S0,68Te0,32)1,00!@54=558,3912,1962,9816,53(Cu0,49Ag1,49)1,98(S0,67Te0,33)@8<5G0=85: <0B@8F0 B  1>@=8B, G  30;5=8B, BG  >10 <8=5@0;0 !>AB02 <8=5@0;0 (@8A., B01;.), >?@545;5==K9 =0 M;5:B@>==>< <8:@>A:>?5 --2 A M=5@3>48A?5@A8>==>9 ?@8AB02:>9 (0=0;8B8: ..>B;O@>2), =5 ?>72>;O5B 845=B8D8F8@>20BL <8=5@0; =8 A >4=8< 87 8725AB=KE. !>AB02 <8=5@0;0 =5 7028A8B >B 2<5I0NI59 53> <0B@8FK. $>@<C;0 E>@>H> @0AG8BK205BAO =0 (Ag,Cu)2(S,Te)1 8 <>65B 1KBL ?@54AB02;5=0 :0: A<5AL B@5E <8=0;>2: 35AA8B0, 0@35=B8B0 8 E0;L:>78=0. 0 B@5C3>;L=>9 4803@0<<5 2 C:070==KE :>>@48=0B0E B>G:8 A>AB02>2 ;>60BAO 2 :><?0:B=>5 ?>;5, A 2K45@60==K<8 A>>B=>H5=8O<8 <564C <8=0;0<8. 0B@8F0 ?@54AB02;5=0 30;5=8B>< (1), 1>@=8B>< (2) 8 >1>8<8 <8=5@0;0<8 (3). 7><>@D87< <564C 35AA8B><, 0@35=B8B>< 8 E0;L:>78=>< 2 ;8B5@0BC@5 =5 @0AA<0B@8205BAO, E>BO AB@C:BC@K C:070==KE A>548=5=89 >B=>AOBAO : >4=><C :;0AAC ?A524>87><5B@8G5A:8E (?> >AB>2C) 8 2A5 C:070==K5 A>548=5=8O E0@0:B5@87CNBAO 1>;LH8< :>;8G5AB2>< ?>;8<>@D=KE <>48D8:0F89. !>3;0A=> =0H8< 40==K<, =0E>4:0 B5;;C@84>-AC;LD840 A5@51@0 8 <548  ?5@20O 8 =C6405BAO 2 3;C1>:>< 87CG5=88 A :@8AB0;;>E8<8G5A:8E ?>78F89. 2B>@K 1;03>40@=K 3;02=><C 35>;>3C   ..3552C 8 ../<I8:>2>9 70 A>459AB285 ?>;52K< @01>B0<. =0;8B8G5A:85 @01>BK D8=0=A8@>20;8AL 70 AG5B 3@0=B0 MinUrals !!"  -" !!"  $+% $& !0!3  % !!&&  '+% /% 0;LG8: .. XE "0;LG8: .." , >;<>3>@>2 ... XE ">;<>3>@>2 ..." , !B>;?>2A:0O .. XE "!B>;?>2A:0O .." , @5:>20 .!. XE "@5:>20 .!." , 8@>H=8G5=:> ..  ! , >2>A818@A:, >AA8O,  HYPERLINK "mailto:nadezhda@uiggm.nsc.ru" nadezhda@uiggm.nsc.ru Palchik N.A., Kolmogorov Yu.P., Stolpovskaya V.N., Grekova G.S., Miroshnichenko L.V. Peculiarities of microelement composition of CaCO3 polymorphous modifications and their association in callstones (OIGGM SB RAS, Novosibirsk, Russia). Three polymorphous modifications of calcium carbonates calcite, aragonite, vaterite, are known in nature and are identified in pathogenic formations in human organism and are the most frequent mineral components of gallstones. The analysis of the phase composition and abundance of various CaCO3 polymorphs showed that the frequency of any polymorphous form in gallstones is directly opposite of that in the natural systems. The carbonates in gallstones have a different extent of perfection of crystal lattice as a result of various deposition conditions of the minerals and nonhomogeneity of their composition. The result of element analysis showed, that in aragonite-pigment stones the content of Sr, Pb, Zn, Cu and Fe are higher in some times, than in cholesterol-vaterite and cholesterol-calcite stones. We meet only one pure carbonate stone with all three CaCO3 forms simultaneously. 0@1>=0B :0;LF8O (!0!3)  @0A?@>AB@0=5==>5 2 ?@8@>45 A>548=5=85 A H8@>:> ?@>O2;ONI8<AO ?>;8<>@D87<>< [1]. >O2;5=85 8 A>E@0==>ABL B>9 8;8 8=>9 ?>;8<>@D=>9 <>48D8:0F88 >?@545;ONBAO A?5F8D8:>9 D878:>-E8<8G5A:8E 8 :8=5B8G5A:8E D0:B>@>2 <8=5@0;>>1@07CNI8E A@54. 06=0O @>;L >B2>48BAO :>=F5=B@0F88 !3 2 @0AB2>@5, :0B0;8B8G5A:>9 8 8=3818@CNI59 @>;8 @07;8G=KE M;5<5=B>2 8 >@30=8G5A:>3> 25I5AB20, 0 B0:65 F5;><C @O4C 4@C38E ?0@0<5B@>2, 2KOA=5=85 :>B>@KE A?>A>1AB2C5B ?>=8<0=8N <5E0=87<>2 A>>B25BAB2CNI8E ?@>F5AA>2 8 8<55B =5?>A@54AB25==>5 35>;>38G5A:>5 7=0G5=85.  ?@8@>45 2AB@5G0NBAO B@8 ?>;8<>@D=K5 <>48D8:0F88 !0!3  :0;LF8B, 0@03>=8B 8 D0B5@8B. 0;LF8B O2;O5BAO 1>;55 CAB>9G82>9 8 @0A?@>AB@0=5==>9 <>48D8:0F859. @03>=8B <5=55 AB018;5=, 8 2AB@5G05BAO G0I5 2 682KE >@30=87<0E. $0B5@8B <5B0AB018;5= ?> >B=>H5=8N : :0;LF8BC 8 0@03>=8BC 8 2 ?@8@>4=KE <8=5@0;L=KE A8AB5<0E >1=0@C68205BAO @54:>. ><8<> ?@8@>4=KE A8AB5< 8 682KE >@30=87<>2 :0@1>=0B :0;LF8O 2E>48B 2 A>AB02 ?0B>35==KE >1@07>20=89 2 >@30=87<5 G5;>25:0.  65;G=KE :0<=OE !0!3 A0<0O @0A?@>AB@0=5==0O =5>@30=8G5A:0O A>AB02;ONI0O [2]. @>2545==K9 =0<8 0=0;87 A>AB020 8 ?0@035=578A>2 38 :0@1>=0BA>45@60I8E 65;G=KE :0<=59 8 @0A?@>AB@0=5==>AB8 @07;8G=KE ?>;8<>@D=KE <>48D8:0F89 !0!3 2 =8E 2KO28; >?@545;5==K5 70:>=><5@=>AB8. :070;>AL, GB> G0AB>B0 2AB@5G05<>AB8 B>9 8;8 8=>9 <>48D8:0F88 :0@1>=0B0 :0;LF8O 2 65;G=KE :0<=OE ?@O<> ?@>B82>?>;>6=0 B0:>2>9 2 ?@8@>4=KE A8AB5<0E. $0B5@8B CAB0=>2;5= 2 87% ?@>0=0;878@>20==KE :0<=59, 2 55% ?@8ACBAB2>20; 0@03>=8B 8 B>;L:> 2 45% >1=0@C65= :0;LF8B. @8 MB>< 2 :0G5AB25 548=AB25==>9 ?>;8<>@D=>9 <>48D8:0F88 D0B5@8B ?@8ACBAB2>20; 2 34% >1@07F>2 2 0AA>F80F88 A E>;5AB5@8=><, 0@03>=8B 2 42CE ?83<5=B=KE :0<=OE 8 :0;LF8B 2 42CE E>;5AB5@8=>2KE.  >AB0;L=KE :>=:@5<5=B0E >B<5G0;>AL =0;8G85 42CE 8;8 B@5E ?>;8<>@D=KE D>@< >4=>2@5<5==> 2 @07=KE :>;8G5AB25==KE A>>B=>H5=8OE. 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r, Pb, Zn, Cu 8 Fe 2 =5A:>;L:> @07 2KH5, G5< 2 D0B5@8B- 8 :0;LF8B-E>;5AB5@8=>2KE. 0:A8<0;L=>5 :>;8G5AB2> Mn CAB0=>2;5=> 2 >1@07F5, A;>65==>< B>;L:> B@5<O D>@<0<8 !0!3 8 2 B0:>3> 65 A>AB020 G5@=>9 2=CB@5==59 7>=5 >4=>3> 87 :0<=59 A;>8AB>3> AB@>5=8O, 4@C385 7>=K :>B>@>3> 8<5NB 8=>9 <8=5@0;>38G5A:89 8 M;5<5=B=K9 A>AB02. !>3;0A=> @57C;LB0B0< M;5<5=B=>3> 0=0;870, <>6=> A45;0BL ?@54?>;>65=85 > ?@8G8=5 0AA>F80F88 0@03>=8B0 A ?83<5=B><. 5@>OB=> 7=0G8<>5 :>;8G5AB2> B0:8E <8:@>M;5<5=B>2 :0: AB@>=F89, A28=5F 8 4@. 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C738= .., ><;520 .. !B@C:BC@0 8 M2>;NF8O 65;G=KE :0<=59 // 0?. , 1987. ! 3. !.347 357. 4. Sutor D.J., Wooley S.E. Gallstone of Unusual Composition: Calcite, Aragonite, and Varetite // Science, 1968. v.159. .1113 1114. &"+ ! -""+% !"  !  %!"  (!  15:>2 .., 1"C@G:>20 .., 2>=>=:>20 .., 38:15@3 . 1#, >A:20, >AA8O, mineral@geol.msu.ru; 2% , >A:20, >AA8O; 3Euroatom Safeguards Directorate, N:A5<1C@3 1Pekov I.V1, 1Turchkova A.G., 2Kononkova N.N., 3Lyckberg P. Zeolites in scarn magnetite deposits of Northern Kazachstan and Swedish Lappland (1Moscow State University, Moscow, Russia; 2GEOKHI, Moscow, Russia; 3Euroatom Safeguards Directorate, Luxembourg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a, H01078B-Na, =0B@>;8B, A:>;5F8B, B><A>=8B-!0, ;><>=B8B, 359;0=48B-!0, D8;;8?A8B-Na, D8;;8?A8B-Ca, 0=0;LF8<.  A525@=>< 1>@BC !>:>;>2A:>3> :0@L5@0 2 ?>;>ABOE 0=4@048B>2KE A:0@=>2 A 35<0B8B><, :0;LF8B><, ?8@8B>< @0728B :><?;5:A :0;LF852KE F5>;8B>2. 081>;55 @0A?@>AB@0=5= AB5;;5@8B A>AB020 (Ca3,56Na,28K,12)(3,96(Al7,84Si28,24)(36,08O72(nH2O, 40NI89 I5B:8 :>@8G=52KE 4> 65;B>->@0=652KE ?@87<0B8G5A:8E :@8AB0;;>2 4> 1 A<. %0@0:B5@=>9 >A>15==>ABLN :@8AB0;;>2 BC@309A:>3> AB5;;5@8B0, ?>72>;ONI59 >B;8G0BL 53> >B ?>E>653> AB8;L18B0, O2;O5BAO ?;>A:0O 3>;>2:0, >1@07>20==0O 3@0=LN {001}. 1KG=> :@8AB0;;K AB5;;5@8B0 @0AI5?;5=K 2 ?;>A:>AB8 (010) 2?;>BL 4> >1@07>20=8O 48A:>AD5@>;8B>2 A >ALN [100]; G0AB> ?CG:8 :@8AB0;;>2 A>1@0=K 2 AD5@>;8BK 4> 2,5 A<. !B5=:8 =5:>B>@KE ?>;>AB59 ?>:@KBK I5B:0<8 A=56=>-15;KE ?@87< (4> 40(2(2 <<) ;><>=B8B0 (Ca3,88K,12Na,08Mn,01)(4,09 (Al7,67Si16,26)(23,93O48(nH2O, 4@C385 :025@=K =0F5;> 70?>;=5=K @0480;L=>-H5AB>20BK<8 03@530B0<8 3@O7=>-15;>3> A:>;5F8B0 (Ca,97Na,01)(,98 (Al1,99Si3,02)(5,01O10(nH2O, 4;8=0 8=48284>2 :>B>@>3> 4>AB8305B 6 7 A<.  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A>15==> MDD5:B82=K<8 A5?0@0B>@0<8 :0B8>=>2 2KABC?0NB F5>;8BK, 2 AB@C:BC@0E :>B>@KE ?@8ACBAB2CNB ?>;>AB8 =5A:>;L:8E B8?>2, A8;L=> @07;8G0NI85AO ?> <5B@8:5. ;O Sr B0:8< A5;5:B82=K< :>=F5=B@0B>@>< AB0; B><A>=8B: 2 <8=5@0;5 87 %818= 70D8:A8@>20=> A0<>5 2KA>:>5 A>45@60=85 MB>3> M;5<5=B0 4;O ?@8@>4=KE F5>;8B>2 2>>1I5: 19,4 <0A.% SrO. =5:0@:0A=K5 :0B8>=K 2 B><A>=8B5 =0E>4OBAO 2 ?>;>ABOE 42CE B8?>2  2 :0=0;0E 8 2 87>;8@>20==KE  D>=0@OE . >78F8O 2=CB@8 ?>A;54=8E @0AI5?;5=0 2 15AAB@>=F852>< B><A>=8B5 =0 425 ?>4?>78F88, 70A5;5==KE !0 AB0B8AB8G5A:8. -B> A2O70=> A >1J5<><  D>=0@O , :>B>@K9 A;8H:>< 25;8: 4;O B>3>, GB>1K 8>= Ca =0E>48;AO 2 53> F5=B@5. @C?=K9 8>= Sr 2 B><A>=8B5 ;>:0;87C5BAO 2 ?>78F88 2=CB@8  D>=0@O , => 2 >B;8G85 >B !0 @07<5I05BAO =5?>A@54AB25==> 2 F5=B@5 ?>;>AB8 [7], ?>;CG0O O2=>5 M=5@35B8G5A:>5 ?@58<CI5AB2> ?5@54 !0, GB> 8 >1JOA=O5B 2KA>:CN AB5?5=L A5;5:B82=>AB8 B><A>=8B0 2 >B=>H5=88 Sr. 0 >A=>20=88 @57C;LB0B>2 87CG5=8O F5>;8B>2 87 I5;>G=KE 384@>B5@<0;8B>2 (>A>1>5 2=8<0=85 1K;> >1@0I5=> =0 A>AB02K A>ACI5AB2CNI8E <8=5@0;>2) =0<8 CAB0=>2;5= M<?8@8G5A:89 @O4, E0@0:B5@87CNI89 C<5=LH5=85 A@>4AB20 : Ca 8 >A>15==> : Sr: B><A>=8B ( 359;0=48B ( H01078B ( 3<5;8=8B ( D8;;8?A8B. !@>4AB2> <8=5@0;>2 (B.5. AB@C:BC@=KE B8?>2) : K 2 MB>< @O4C, =0>1>@>B, @0AB5B. "0:8< >1@07><, Sr 2KABC?05B 2 1>;LH8=AB25 F5>;8B>2 A2>5>1@07=K<  0=B03>=8AB>< K 8 Ba.  H01078B5 8 359;0=48B5 2KA>:>:0;LF852K5 :@8AB0;;K 8 4065 7>=K 2 :@8AB0;;0E @57:> >1>30I5=K Sr ?> A@02=5=8N A 2KA>:>:0;852K<8. A:;NG5=85 A>AB02;O5B A5@8O 1@NAB5@8B0, 345 87><>@D87< >ACI5AB2;O5BAO <564C Sr 8 Ba. 0H8 =01;N45=8O ?>:07K20NB, GB> 2KA>:0O 0:B82=>ABL C3;5:8A;>BK ?@5?OBAB2C5B >1@07>20=8N AB@>=F852KE F5>;8B>2, 2 >B;8G85 >B 10@852KE. G5=L CAB>9G820 0AA>F80F8O AB@>=F852KE :0@1>=0B>2 ?>GB8 157 Ba (AB@>=F80=8B, 0=:8;8B) A 10@852K<8 F5>;8B0<8 ?>GB8 157 Sr  M48=3B>=8B>< 8 30@<>B><><. "0:85 ?0@035=578AK 2AB@5G5=K 2> <=>38E B>G:0E :>;LA:8E <0AA82>2, 2 B>< G8A;5 8 2 :0@1>=0B8B0E. B<5B8<, GB> ?><8<>  8AB8==KE , B.5. 0;N<>A8;8:0B=KE F5>;8B>2 >G5=L MDD5:B82=K<8 8718@0B5;L=K<8 :>=F5=B@0B>@0<8 Sr 2KABC?0NB 8 4@C385 <8=5@0;K A F5>;8B>?>4>1=K<8 AB@C:BC@0<8  A8;8:0BK, >:A84K, 1>@0BK, 2 :0@:0A0E :>B>@KE 8<5NBAO ?>;>AB8,  ?@8A?>A>1;5==K5 4;O 2E>645=8O 8>=0 Sr. "0:>2K ?>78F8O !0(2) 2 1>@0B0E A5<59AB20 E8;L30@48B0 [8], ?>78F8O Na(4) 2 <8=5@0;0E 3@C??K M2480;8B0 [9], ?>78F8O (3) C ?@54AB028B5;59 AB@C:BC@=>3> B8?0 3CB:>208B0 2 3@C??5 ;01C=F>28B0. 725AB=K 8 1>30BK5 Sr  >:A84=K5 F5>;8BK  G;5=K 3@C??K ?8@>E;>@0. G5284=>, 2KA>:85 A>45@60=8O Sr 2 <8=5@0;0E A F5>;8B=K<8 AB@C:BC@0<8 <>3CB 8<5BL =5 B>;L:> ?5@28G=>5 ?@>8AE>645=85, => 8 4>AB830BLAO ?CB5< ?@8@>4=>3> 8>==>3> >1<5=0. 8B5@0BC@0: 1. Gottardi G., Galli E. Natural Zeolites. Berlin, 1985. 409 p. 2. %><O:>2 .. 8 4@. @NAB5@8B  ?5@20O =0E>4:0 2 !!!  // >:;.  !!! , 1970. ".190. !5. !.1192 1195. 3. Rudinger B. et al. Bellbergite  a new mineral with the zeolite structure type EAB // Min. and Petr., 1993. V.48. P.147 152. 4. 5:>2 . 8 4@. (01078B-Sr (Sr,Ca)[Al2Si4O12](6H2O  =>2K9 F5>;8B 87 >2>75@A:>3> <0AA820, >;LA:89 ?>;C>AB@>2 // , 2000. !4. !.54 58. 5. 5:>2 .. 8 4@. "><A>=8B-Sr (Sr,Ca)2Na[Al5Si5O20](6 7H2O  =>2K9 F5>;8B 87 %818=A:>3> <0AA820 (>;LA:89 ?>;C>AB@>2) 8 87><>@D=0O A5@8O B><A>=8B-Ca  B><A>=8B-Sr // , 2001. !4. !.46 55. 6. 5:>2 .. >2>75@A:89 <0AA82: 8AB>@8O 8AA;54>20=8O, ?53<0B8BK, <8=5@0;K. ., 2001. 432A. 7. C@10=>20 .. 8 4@. @8AB0;;8G5A:0O AB@C:BC@0 2KA>:>AB@>=F852>3> B><A>=8B0 // >:;. , 2001. ".376. !3. !.387 390. 8. $5@@> . 4@. @8AB0;;8G5A:0O AB@C:BC@0 AB@>=F852>3> E8;L30@48B0 // @8AB0;;>3@0D8O, 2000. ".45. !3. !.452 457. 9. Johnsen O., Grice J.D. The crystal chemistry of the eudialyte group // Can. Min., 1999. V.37. P.865 891.  +-!#" !  !    !!+ #',/  # (!   %",) 5B@>2 !.$. XE "5B@>2 !.$."  !  , 3. 03040=, >AA8O, museum@neisri.magadan.ru Petrov S.F. The associated minerals of native silver from the Drug Creek placer, the Northern Priokhotie area (NEISRI FEB RAS, Magadan, Russia). This paper describes chemical compositions and genesis of garnet and chrome spinellid minerals from the native silver placer occurrence in the Nothern Priokhotie area. The author makes the conclusion that garnet and crome spinellid minerals from the Drug creek area have the same original source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he chemical compositions of garnets and alumochromites from the Drug Areek placer :A84,@0=0B / Garnet;N<>E@><8B / Alumochromite<0A.%@>10 1@>10 2@>10 3@>10 4@>10 1@>10 2@>10 3SiO237,3436,5937,6537,380,120,060,11TiO20,060,060,150,060,380,370,37Al2O321,5921,2820,7320,899,4910,129,57Cr2O30,060,000,050,1253,2252,4854,29FeO34,3334,2433,8236,2724,8523,8121,37MnO1,071,091,251,710,320,260,37MgO4,975,025,173,2110,6711,5813,16CaO1,231,191,500,930,040,000,00Na2O0,210,480,000,330,290,000,00K2O0,000,000,000,000,000,000,00NiO0,030,000,000,000,050,110,00!C<<0100,8999,95100,32100,9099,4398,7999,25@8<5G0=85: A5 65;57> >?@545;5=> 2 2845 FeO; 0=0;87 2K?>;=5= =0 <8:@>7>=45  Camebax 2 !  , 0=0;8B8: .. 8E09;>2. 8=5@0;K 3@C??K H?8=5;8 (0,5(1 <<) D>@<8@CNB 2=CB@5==5 3><>35==K5 >:B0M4@8G5A:85 :@8AB0;;K G5@=>3> F25B0 A @57>@18@>20==K<8 3@0=O<8. > E8<8G5A:><C A>AB02C (A<. B01;8FC) A>>B25BAB2CNB 0:F5AA>@=K< 0;N<>E@><8B0< ?>@>4, 8A?KB02H8E ?@>3@5AA82=K9 <5B0<>@D87< 75;5=>A;0=F52>9 ( 0<D81>;8B>2>9 D0F89 [4]. #G8BK20O 35>;>38G5A:CN A8BC0F8N, <K ?@54?>;0305<, GB> E@><H?8=5;84K 1K;8 70E20G5=K 8 ?>4=OBK : ?>25@E=>AB8 2 E>45 M:A?;>782=KE 8725@65=89, AD>@<8@>202H8E ?>:@>2K :A5=>BCD>2 8 :A5=>83=8<1@8B>2 @8>;8B>2 =86=59 G0AB8 2C;:0=>35==>3> @07@570 [2]. 5@2>8AB>G=8:0<8 8E <>3CB 1KBL :0: <5B0<>@D87>20==K5 >A04>G=K5 ?>@>4K 25@E>O=A:>3> :><?;5:A0, B0: 8 70;530NI85 =0 3;C18=5 B5;0 C;LB@0>A=>2=>3> A>AB020 (40==K5 .. :@C38=0 A A>02B>@0<8 [3] C:07K20NB =0 AE>4AB2> =5:>B>@KE 0=0;87>2 E@><H?8=5;84>2 8=B@C782>2 "0;=0EA:>3> 8 >@8;LA: I A 8AA;54>20==K<8). > =0H5<C <=5=8N, 70:0@B8@>20==K5 2 @09>=5 548=8G=K5 409:8 AC1I5;>G=KE 1070;LB>2 =5 <>3;8 ?>AB02;OBL 0;N<>E@><8B 2 @>AAK?L. -B> >1CA;>2;5=> ?>=865==K<8 :>=F5=B@0F8O<8 2 <8=5@0;5 >:A840 B8B0=0 (TiO2), E0@0:B5@=>3> 4;O H?8=5;59 87 B@0??>2 8 1070;LB>2 [4]. @>2545==>5 87CG5=85 3@0=0B>2 8 E@><H?8=5;84>2 ?>72>;O5B A45;0BL 2K2>4, GB> >=8 ?>ABC?0NB 2 0;;N289 2A;54AB285 @07@CH5=8O :A5=>BCD>2 8 :A5=>83=8<1@8B>2 @8>;8B>2, =0AKI5==KE >1;><:0<8 ?>@>4 DC=40<5=B0 E>BA:>-'C:>BA:>3> 2C;:0=>35==>3> ?>OA0. @8 MB>< ?@>872>4=K5 :8A;KE <03<0B8G5A:8E @0A?;02>2 4;O 3@0=0B>2 2KABC?0NB 2 :0G5AB25  <0B5@8=A:8E ?>@>4, 0 4;O 0;N<>E@><8B0 >=8 O2;ONBAO A2>5>1@07=K< ?@><56CB>G=K< :>;;5:B>@><. "0:8< >1@07><, 87CG5==K5 <8=5@0;K-A?CB=8:8 A0<>@>4=>3> A5@51@0 @>AAK?8 @CG. @C3 8<5NB @07=CN 35=5B8G5A:CN ?@8@>4C, => :>@5==>9 8AB>G=8: C =8E >48=. 8B5@0BC@0: 1. 5;L<0= .. @0=0B 2 8725@65==KE ?>@>40E (=0 ?@8<5@5 !525@>(>AB>:0 !!! ) // 72.  !!! . !5@. 35>;. 1980. ! 8. !. 35(49. 2. >;OA=8:>2 ..., 5B@>2 !.$, 5B@>20 .. #A;>28O ;>:0;870F88 8 <8=5@0;>38G5A:85 >A>15==>AB8 A5@51@O=>3> >@C45=5=8O CG0AB:0 @C3 (5@E=5(!59<:0=A:89 @C4=K9 C75;) // 8=5@0;>38O 8 35=5B8G5A:85 >A>15==>AB8 <5AB>@>645=89 7>;>B0 8 A5@51@0. 03040=: !  , 1996. !. 93(104. 3. :@C38= .., 0=:>2 ..., 0E>B:> .$. :F5AA>@=K5 H?8=5;84K 2 B@0??0E !818@A:>9 ?;0BD>@<K // "8?><>@D=K5 >A>15==>AB8 @C4=KE <8=5@0;>2 M=4>35==KE >1@07>20=89 /:CB88. /:CBA:: /$ !  !!! , 1983. !. 54(68. 4. !<8@=>20 ".. @C??0 E@><H?8=5;84>2 // "8?><>@D87< <8=5@0;>2: !?@02>G=8:. .: 54@0, 1989. 560A. 5.!>1>;52.. 0@035=5B8G5A:85 B8?K 3@0=0B>2. .: 0C:0, 1964. 218 A. C4=K5 ?0@035=578AK C@0=>2>3> <5AB>@>645=8O 0@:C (!525@>-2>AB>G=>5 @8;04>6L5) 1>;5E>2A:89 ..!., 1"0@0A>20 .., 1@8B28= !.., 28GC38= .., 2(C@8;>2 .. 1!1#, 3. !.-5B5@1C@3, >AA8O, polekh@ysp.usr.pu.ru; 2  52A:35>;>38O , 3. !.-5B5@1C@3, >AA8O 1Polekhovskiy Yu.S.,1Tarasova I.P.,1Britvin S.N., 2Pithugin V.A., 2Shurilov A.V. Ore paragenesis of Karku uranium deposit, North-Eastern Ladoga region (1SPbSU, S.-Petersburg, Russia, 2SE  Nevskgeologia , S.-Petersburg, Russia). The publication contents new data about the ore paragenesis of Karku uranium deposit in North-Eastern Priladozhie in Karelia region. 5AB>@>645=85 0@:C @0A?>;>65=> 2 ?@545;0E 04>6A:>3> B5:B>=8G5A:>3> 1;>:0 0;B89A:>3> I8B0 (N3>-70?04=0O G0ABL 5A?C1;8:8 0@5;8O), @07<5I05BAO =0 A525@>-2>AB>G=>< 1>@BC @8D59A:>3> 0HA:>-04>6A:>3> ?@>3810, >A=>20=85< :>B>@>3> O2;ONBAO @0==54>:5<1@89A:85 >1@07>20=8O A25:>D5=A:>9 AB@C:BC@=>9 >1;0AB8 8 3@0=8B>84K !0;<8=A:>3> <0AA820 [1]. !B@C:BC@=0O ?>78F8O <5AB>@>645=8O >?@545;O5BAO 53> ?@8C@>G5==>ABLN : ;>:0;L=><C B5:B>=8G5A:><C ?>4=OB8N :@>2;8 DC=40<5=B0. 8D59A:89 AB@C:BC@=>-D>@<0F8>==K9 :><?;5:A ?@54AB02;5= 745AL ?@8>75@A:>9 A28B>9, ?>4@0745;O5<>9 =0 425 ?>4A28BK. >I=>ABL =86=59, @C4>:>=B@>;8@CNI59 B5@@835==>->A04>G=>9, ?>4A28BK, =5 ?@52KH05B 40 <5B@>2; 0 25@E=59  ?@54AB02;5==>9 1078B>2K<8 MDDC7820<8 ?>2KH5==>9 I5;>G=>AB8  A>AB02;O5B >1KG=> 60 90 <. >:5<1@89A:85 >1@07>20=8O ?5@5:@KBK G5E;>< G5B25@B8G=KE >B;>65=89 <>I=>ABLN 4> 30 50 <. 1.5AB>@>645=85 A>AB>8B 87 B@5E @C4=KE 70;5659. 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"01;8F0 8=5@0;L=K5 ?0@035=578AK <5AB>@>645=8O 0@:C* Mineral paragenesis of the Karku deposit !! -B0?KIIIIII?/?!B0488 8=5@0;K123120@F-2+28::8B+3%;>@8B-2 (:;8=>E;>@)+4%;>@8B-3 (H0<>78B)+5%;>@8B-4 ( Na-E;>@8B )+6%;>@8B-5 (:;8=>E;>@)+70@1>=0B-1+80@1>=0B-2+90@1>=0B-3+100@1>=0B-4+110ABC@0=-1+120ABC@0=-2+13>DD8=8B+14 CB8;-3+15 CB8;-4+16?0B8B-2+17$;N>@8B+180;5=8B-1+190;5=8B-2+200;5=8B-3+218@8B-2+228@8B-3+23@02>8B+240@:078B+258@@>B8=-2+268@@>B8=-3+27%0;L:>?8@8B+28>@=8B+290@<0B8B+30;59>D0=+31Cd-AD0;5@8B+32%>C;88B+33@8=>:8B+34Fe Pb Mo D070+358:5;8=+36Co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b/206Pb 2>7@0AB0 1K;> CAB0=>2;5=>, GB> 2@5<O D>@<8@>20=8O =0ABC@0=0-1 A>>B25BAB2C5B 7=0G5=8N 1371(46<;=.;5B [2].  ?0@035=578A5 A =0ABC@0=><-1 =01;N40NBAO 30;5=8B, ?8@@>B8=, Cd-AD0;5@8BK, !>-Ni 0@A5=84K (CA;>2=>, AC;LD84K-3; A<.B01;.), A?>@048G5A:8 D;N>@8B, 0?0B8B, A=>?>284=K9 :0@1>=0B (:0@1>=0B-2) 8 =0B@89A>45@60I89 A;>8ABK9 A8;8:0B, CA;>2=> =0720=K9  Na-E;>@8B (E;>@8B-4). =B5@5A=>9 >A>15==>ABLN C@0=>2KE @C4 <5AB>@>645=8O 0@:C O2;O5BAO =0;8G85 2 =8E Fe Pb MoD07K. %8<8G5A:89 A>AB02 40==>3> <8=5@0;L=>3> >1@07>20=8O ?5@5AG8BK205BAO =0 D>@<C;C, >B25G0NICN AB5E8><5B@88 MX2, 345 M = Mo, Fe, Pb, 0 X = S, As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e, Ti. 6. B@5BL5<C  =081>;55 ?>74=5<C MB0?C M?835=5B8G5A:8E ?@5>1@07>20=89 >B=>AOBAO :0@1>=0B=K5 (:0@1>=0B-4) ?@>68;:8 A E;>@8B>< (E;>@8B-5) 8 E0;F54>=><, A5:CI85 2A5 ?>@>4K 8 CG0AB:8 A C@0=>2>9 <8=5@0;870F859. =8 8 A>?@>2>640NI85 8E ?@>F5AAK ?@82>4OB : @07C1>6820=8N @0=55 AD>@<8@>20==KE C@0=>2>@C4=KE B5;. ! B0:8<8 ?@>68;:0<8, >B<5G0NI8<8AO 4065 2 ?5@5:@K20NI8E 3@025;8B>-?5AG0=8:8 1070;LB>840E, A2O70=0 B>G5G=0O A;01>@048>0:B82=0O <8=5@0;870F8O, ?@54AB02;5==0O 384@>=0ABC@0=>< 8 C@0=A>45@60I8< ;59:>:A5=><. >A;54=85 0AA>F88@CNB A 384@>:A840<8 Fe 8 Mn, A0<>@>4=>9 <54LN. 8=5@0;L=K9 ?0@035=578A ?@>F5AA>2 B@5BL53> MB0?0: :0@1>=0B-4 + E;>@8B-5 + E0;F54>= + 384@>=0ABC@0= + C@0=A>45@60I89 ;59:>:A5= + 384@>:A84K Fe, Mn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b/206 b 2>7@0AB0 ?> 0:F5AA>@=K< <8=5@0;0< =0 <=>3>:0=0;L=>< <0AA-A?5:B@><5B@5 A 8>=870F859 2 8=4C:B82=>-A2O70==>9 ?;07<5 A 8A?>;L7>20=85< ;>:0;L=>3> ;075@=>3> ?@>1>>B1>@0 // XVI A8<?>78C< ?> 35>E8<88 87>B>?>2. ., 2001. !.225 226. >2K5 40==K5 > <8=5@0;>388 <5AB>@>645=8O 7>;>B0 54@>;0<?8 (&5=B@0;L=0O 0@5;8O) 1>;5E>2A:89 ..!., 1"0@0A>20 .., 15B@>2 !.., 1>;>B0@52 .., 2">;:0G52 .. 1!1#, 3. !.-5B5@1C@3, >AA8O, polekh@ysp.usr.pu.ru; 2, 3. !.-5B5@1C@3, >AA8O 1Polekhovskiy Yu.S., 1Tarasova I.P., 1Petrov S.V., 1Zolotarev A.A., 2Tolkathev M.D. New mineralogical data of the Pedrolampi aurum deposit, Central Karelia. (1SPbSU, S.-Petersburg, Russia; 2IGGD, S.-Petersburg, Russia). The publication contents new mineralogical data about of the Precembrian metasomatites and ores Pedrolampi aurum deposit in Central Karelia region. 5AB>@>645=85 54@>;0<?8 @0A?>;>65=> 2 ?@545;0E %0CB0200@0->9:0@A:>9 <561;>:>2>9 7>=K =0 ABK:5 &5=B@0;L=>-0@5;LA:>3> (=0 70?045) 8 =56A:>3> (=0 2>AB>:5) 35>1;>:>2, ;>:0;87>20=> 2 8=B5=A82=> <5B0<>@D87>20==KE, B5:B>=878@>20==KE (4> 1;0AB><8;>=8B>2) 8 <5B0A><0B8G5A:8 87<5=5==KE ?>@>40E A5<G5@5G5=A:>9 (<5B0480107K 8 <5B00=4578BK) 8 15@30C;LA:>9 (@8>;8B>-40F8BK, 3@0D8BA>45@60I85 8 4@. 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In the geological and mineralogical museums side-by-side with traditional exhibiting objects such as rocks and minerals the representation of the unusual exhibits, for example, of technogenic and biogenic minerals which have been not recognized by those officially is possible. The collection of urinary stones of the inhabitants of the Chelyabinsk area is preparing for exhibit in the museum of the Ilmen State Reserve. 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"01;8F0 1KG=K5 <8=5@0;L=K5 D07K 2 A>AB025 C@>;8B>2 0720=85, ?@8=OB>5 2 <548F8=5%8<8G5A:>5 =0720=858=5@0;>38G5A:>5 =0720=85%8<8G5A:0O D>@<C;0:A0;0BK:A0;0B :0;LF8O, <>=>384@0B :A0;0B :0;LF8O, 48384@0B#M25;;8B #M445;;8BCaC2O4H2O CaC2O42H2O$>AD0BK $>AD0B <03=8O 8 0<<>=8O, 35:A0384@0B $>AD0B :0;LF8O >A=>2=>9 !;>6=K9 :0@1>=0B D>AD0B0 :0;LF8O 8A;K9 D>AD0B <03=8O B@5E2>4=K9!B@C28B 84@>:A8;0?0B8B 0@1>=0B0?0B8B LN15@88BNH4MgPO46H2O Ca5(PO4)3(OH) Ca5(PO4,CO3)3(OH) Mg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chneider H.J., Heinzsch E. Welche Bedeutung hat die operative Therapie der Urolithiasis heute? // Z.Urol., 1975. Bd.14. ! 8. s. 547 556. ;075@>;N<8=5AF5=F8/ Sm3+ 2 <8=5@0;0E 3@C??K 15@10=:8B0, :0@1>F5@=08B5 8 AB@>=F80=8B5 1 0AAC;>2 .., 2 !>:>;>2 !.. XE "!>:>;>2 !.."  !, 3. >A:20, >AA8O; 1atcvims@aha.ru, 2vims@df.ru 1Rassulov V.A., 2Sokolov S.V. Laser luminescence of Sm3+ in burbankite group minerals, carbocernaite and strontianite (VIMS, Moscow, Russia). Burbankite group minerals, carbocernaite and strontianite from carbonatites and hydrothermal-metasomatic rocks of alkaline complexes were studied by laser luminescence method. The luminescence spectra of these minerals are characterized by Sm3+ bands of different intensity. The obtained data testify to an unimportant influence of matrix and crystal simmetry on the specific features of Sm3+ spectra in the studied minerals. 5B>4>< ;075@>;N<8=5AF5=F88 () 1K;8 87CG5=K <8=5@0;K 3@C??K 15@10=:8B0 (Na,Ca,%)3(4(Sr,!0,Ba,REE)3(2(!3)5  35:A03>=0;L=K5 15@10=:8B, :0;LF8>15@10=:8B, E0==5H8B 8 <>=>:;8==K5 @5<>=48B-(!5), @5<>=48B-(La), ?5B5@A5=8B-(!5), 8725AB=K5 2> <=>38E I5;>G=KE :><?;5:A0E <8@0 2 A2O78 A :0@1>=0B8B0<8, <5B0A><0B8B0<8 8 384@>B5@<0;L=K<8 >1@07>20=8O<8. "0:65 1K;8 ?@82;5G5=K >1@07FK :0@1>F5@=08B0 (Na,Ca)(Sr,REE,Ba)(!3)2 8 AB@>=F80=8B0 SrCO3 (>10 @><18G5A:85), :>B>@K5 2 :0@1>=0B8B0E ;81> >1@07CNB A0<>AB>OB5;L=K5 2K45;5=8O, ;81> 70<5I0NB 15@10=:8B. ?B8G5A:0O 4803=>AB8:0 <8=5@0;>2 1K;0 ?>4B25@645=0 <8:@>7>=4>2K< 8 @5=B35=>D07>2K< 0=0;870<8 8 ! <5B>4><. A5 <8=5@0;K 3@C??K 15@10=:8B0 8 :0@1>F5@=08B ?>4 2>7459AB285< 87;CG5=8O ;075@0 ((87;=337,1 =<) ?@8 :><=0B=>9 B5<?5@0BC@5 ;N<8=5AF8@CNB 8=B5=A82=K< D8>;5B>2K< F25B>< 8 8<5NB 845=B8G=K5 A?5:B@K  A ?>AB>O==> ?@>O2;5==K<8 G5BK@L<O ?>;>A0<8 A25G5=8O Sm3+ 2 2848<>9 >1;0AB8 A?5:B@0 c <0:A8<C<0<8 I = 560 565, II = 598 602, III = 639 647 8 IV = 700 708 =< (@8A. 0 8 b), 2K720==K<8 >?B8G5A:8<8 ?5@5E>40<8 4G5/2, 4G7/2, 4G9/2 8 4G11/2 A>>B25BAB25==>; =0 <=>38E A?5:B@0E B0:65 ?@8ACBAB2CN ?>;>AK Ce3+, Eu2+ 8 Dy3+ A;01>9 8=B5=A82=>AB8. !B@>=F80=8B >1;0405B 70<5B=> 1>;55 1;54=K< A8@5=52K< 8;8 3>;C1>20BK< A25G5=85<, 0 53> A?5:B@K, 2=5H=5 >G5=L ?>E>685 =0 A?5:B@K  4@C38E 87CG5==KE =0<8 <8=5@0;>2, >B;8G0NBAO A>>B=>H5=85< 25;8G8= II 8 III ?>;>A (@8A. A). (8@>:85 =5M;5<5=B0@=K5 ?>;>AK Sm3+, =5 @07@5H05<K5 4065 ?@8 >E;0645=88 >1@07F>2 4> B5<?5@0BC@K 684:>3> 07>B0 ( 196!), A2845B5;LAB2CNB > <=>3>B8?=>AB8 F5=B@>2 A25G5=8O, ?@8 >1@07>20=88 :>B>@KE 7=0G8B5;L=CN @>;L <>3CB 83@0BL ?@8<5A8 I5;>G=KE <5B0;;>2, 2 ?5@2CN >G5@54L =0B@8O, 2KABC?0NI85 2 :0G5AB25 :><?5=A0B>@0 871KB>G=>3> ?>;>68B5;L=>3> 70@O40, A>740205<>3> -. B<5B8<, GB> 2 AB@>=F80=8B0E CAB0=>2;5=0 ?@8<5AL REE 8 Na (0=0;870B>@ JSM-5300, ..>E>2,  ). ! F5;LN 2KO2;5=8O @07;8G89 2 A?5:B@0;L=KE E0@0:B5@8AB8:0E 40==KE <8=5@0;>2 1K;0 ?@>2545=0 :>;8G5AB25==0O >F5=:0 F5=B@>2 A25G5=8O Sm3+ ?> ?;>I04O< =081>;55 8=B5=A82=KE ?>;>A I, II, III. ;O MB>3> 8A?>;L7>20;AO 0?@>18@>20==K9 2 A?5:B@>A:>?88 <5B>4, >A=>20==K9 =0 87<5@5=88 8=B5=A82=>AB8 ;N<8=5AF5=F88 2 B@5E 7>=0E, 2 >4=C 87 :>B>@KE ?>?0405B >?@545;O5<0O ?>;>A0, 0 2 425 4@C385 ( D>=>2K5 A83=0;K, ;560I85 ;5255 8 ?@0255 55. > @0AAG8B0==K< >B=>H5=8O< :>=F5=B@0F89 F5=B@>2, ?@>?>@F8>=0;L=KE >?@545;5==K< 25;8G8=0< ?;>I0459, ?>AB@>5=0 4803@0<<0 (@8A. d), D83C@0B82=K5 B>G:8 =0 :>B>@>9 >1@07CNB B@5=4 A :>MDD8F85=B>< :>@@5;OF88 0,83 (n=53). 1@07FK AB@>=F80=8B0 A>AB02;ONB >1>A>1;5==CN 3@C??C A <8=8<0;L=K<8 7=0G5=8O<8 >B=>H5=89 II/I 8 II/III. $83C@0B82=K5 B>G:8 :0@1>F5@=08B0 B0:65 ;>:0;87CNBAO 2 :><?0:B=>9 >1;0AB8 (?>:070=0 M;;8?A><), ?@8G5< 2 =55 =5 ?>?040NB 15@10=:8BK 87 B5E 65 :><?;5:A>2. @82545==K5 40==K5 3>2>@OB > =57=0G8B5;L=>< 2;8O=88 <0B@8FK 8 A8<<5B@88 :@8AB0;;>2 =0 >A>15==>AB8 A?5:B@>2 ;N<8=5AF5=F88 Sm3+ 2 87CG5==KE <8=5@0;0E. 8=5@0;>38O ?>;>38E @C4=KE B5; <5AB>@>645=8O >G1C;0: 0E<0=>20 .. 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B;>65=85 <8=5@0;>2 III @C4=>9 AB0488 ?@>8AE>48;> :0: ?CB5< 2K?>;=5=8O F5=B@0;L=KE G0AB59 68; 2 ?>@>40E A @8B<8G=>-?>;>AG0B>9 B5:ABC@>9, B0: 8 ?CB5< 2K?>;=5=8O B@5I8==KE ?>;>AB59, 4@C7>2KE ?CAB>B 8 ?CAB>B 2KI5;0G820=8O.  B5G5=85 MB>9 AB0488 ?@>8AE>48;> D>@<8@>20=85 ?>A;54>20B5;L=> 2K45;82H8EAO <8=5@0;L=KE 0AA>F80F89 A 1;5:;K<8 @C40<8, B5;;C@840<8, AC@L<O=K<8 8 28A<CB>2K<8 AC;LD>A>;O<8, <8=5@0;0<8 >;>20.  ?@545;0E @C4=>9 AB0488 2K45;5=K G5BK@5 <8=5@0;L=K5 0AA>F80F88. "5-B5B@0M4@8B>20O <8=5@0;L=0O 0AA>F80F8O A AC;LD>A>;O<8: Cu Bi, Pb Bi, Cu Pb Bi, Ag Pb(Cu) Bi (Se); A AC;LD>B5;;C@840<8 Bi 8 AC;LD>AB0==0B>< Cu Fe. $>@<8@>20=85 MB>9 0AA>F80F88 =0G8=05BAO A >B;>65=8O A@54=575@=8AB>3> 15;>3> :20@F0 8 ?8@8B0. ;5:;0O @C40 ?@54AB02;5=0 Te-B5B@0M4@8B><, 2AB@5G05BAO 2 2845 @5;8:B>2KE CG0AB:>2 A@548 03@530B>2 1>;55 ?>74=8E 1;5:;KE @C4, A>45@68B M<C;LA8>==CN 2:@0?;5==>ABL E0;L:>?8@8B0, @54:85 <5;:85 2:;NG5=8O M<?;5:B8B0, 09:8=8B0, :>70;8B0 8 70<5I0NI53> 8E B5B@048<8B0.  M<?;5:B8B5 2 =5:>B>@KE 75@=0E 2K@065=K O2;5=8O @07;>65=8O, ?@82>4OI85 : >1@07>20=8N 03@530B0 E0;L:>?8@8B0, 28A<CB8=0 8 28A<CB0. "0: 65 Te-B5B@0M4@8B A>45@68B 2:;NG5=8O :0AA8B5@8B0 8 AB0==8=0, :>B>@K9 <0@:8@C5B 7>=K @>AB0 2 1;5:;>9 @C45. A5 2KH5?5@5G8A;5==>5 E0@0:B5@=> 4;O 70?04=>9 G0AB8 <5AB>@>645=8O, 2 F5=B@0;L=>9 65 G0AB8, 2 >B=>A8B5;L=> ?>4=OB>< @C4>=>A=>< 1;>:5, MB0 0AA>F80F8O 2K@065=0 A;01> 8 >;>2O==K5 <8=5@0;K >BACBAB2CNB, @C4=0O <8=5@0;870F8O ?@54AB02;5=0 B5B@048<8B><, AC;LD>FC<>8B, Se-15=60<8=8B><, M<?;5:B8B><, 0 28A<CB8= >1>30I5= AC@L<>9 8 ?@54AB02;O5B A>1>9 ?@><56CB>G=CN @07=>284=>ABL @O40 28A<CB8= E>@>15BAC8B. "5B@0M4@8B-B5==0=B8B>20O <8=5@0;L=0O 0AA>F80F8O A B5;;C@840<8: Ag, Au Ag, Pb 8 AC;LD>AB0==0B0<8 Cu 8 Cu-Fe. -B0 0AA>F80F8O ?@54AB02;5=0 <5;:>75@=8ABK< :20@F5< 4@C7>2KE ?CAB>B 8 1;5:;>9 @C4>9, 2K?>;=ONI59 MB8 ?CAB>BK. ;5:;0O @C40 ?@8=04;568B : B5B@0M4@8B B5==0=B8B>2><C @O4C. >;55 ?>74=55 2@5<O D>@<8@>20=8O MB>9 <8=5@0;L=>9 0AA>F80F88 CAB0=02;8205BAO ?> AB@C:BC@=K< A>>B=>H5=8O< <8=5@0;>2: =0;8G85 @5;8:B>2 "5-B5B@0M4@8B0 8 ?@>68;:>2 B5B@0M4@8B B5==0=B8B0 2 =5<. 1;878 55 3@0=8F A @0==59 B5;;C@A>45@60I59 1;5:;>9 @C4>9 >B<5G0NBAO A:>?;5=8O :A5=><>@D=KE 2K45;5=89 E0;L:>?8@8B0, 0;B08B0, 35AA8B0, ?5BF8B0. !C;LD>AB0==0BK ?@54AB02;5=K :C@0<8B>< 8 <>CA>=8B><. C@0<8B =01;N405BAO 2 2845 :>;;><>@D=KE >1>A>1;5=89, >1@07CNI8E D5AB>=G0BK5 :05<:8, 2>:@C3 @5;8:B>2KE 2K45;5=89 "5-B5B@0M4@8B0, A>45@60I53> 2:;NG5=8O :0AA8B5@8B0. 5;:85 2K45;5=8O <>CA>=8B0 A>A@54>B>G5=K C 3@0=8FK A "5-B5B@0M4@8B><. "5B@0M4@8B>20O <8=5@0;L=0O 0AA>F80F8O A AC;LD>A>;LN Cu Sb, B5;;C@840<8: Au, Ag, Au Ag, Pb, Bi, Sb 8 AC;LD>AB0==0B>< Cu Zn >1@07C5B ?@>68;:8, ?5@5A5:0NI85 03@530BK @0==8E <8=5@0;L=KE 0AA>F80F89. ;5:;0O @C40 A>45@68B <=>3>G8A;5==K5 <5;:85 2:;NG5=8O E0;L:>AB818B0 8 @54:85  AD0;5@8B0 8 :0AA8B5@8B0, 2>:@C3 2K45;5=89 :>B>@>3> 2 2845 @50:F8>==>9 :05<:8 @0728205BAO :5AB5@8B. "5;;C@84K, B5A=> A@0AB0OAL 4@C3 A 4@C3><, >1@07CNB 2 1;5:;>9 @C45 M<C;LA8>==CN 2:@0?;5==>ABL ;81> 2:;NG5=8O :0?;5284=>9 D>@<K. K45;OOAL =5<=>3> ?>74=55 1;5:;>9 @C4K, B5;;C@84K :>@@>48@CNB 55, @0AA5:0NB ?> A5B8 B>=:8E B@5I8=>: 8 ?@8 7=0G8B5;L=>< @0728B88 ?>;=>ABLN 70<5I0NB, >1@07CO A:>?;5=8O C=0A;54>20==>9 D>@<K, 0 B0:65 A0<>AB>OB5;L=K5 8=B5@AB8F80;L=K5 2K45;5=8O 2 :20@F5. "5;;C@84K ?@54AB02;5=K A@0AB0=8O<8 0;B08B0, ?5BF8B0, 35AA8B0, A8;L20=8B0, B5;;C@>28A<CB8B0, 2>;K=A:8B0, B5;;C@0=B8<>=8B0, HBNBF8B0. %0;L:>?8@8B O2;O5BAO A0<K< ?>74=8< <8=5@0;>< 2 MB>9 0AA>F80F88. K45;5=8O 53> 2AB@5G0NBAO 24>;L 3@0=8F 1;5:;>9 @C4K. "5B@0M4@8B-30;5=8B-AD0;5@8B>20O <8=5@0;L=0O 0AA>F80F8O A AC;LD>A>;O<8 Pb Sb 8 Cu Pb Sb. ;5:;0O @C40 A>45@68B @54:85 <5;:85 2:;NG5=8O 1C@=>=8B0, 30;5=8B0, AD0;5@8B0, OA:C;LA:88B0 8 E0;L:>?8@8B0, 0 B0:65 <5;:85 <5B0:@8AB0;;K ?8@8B0. =0 A?>@048G5A:8 A;0305B ?5@8D5@89=K5 CG0AB:8 @0==8E 1;5:;>@C4=KE 03@530B>2. !0<>@>4=>5 7>;>B> III @C4=>9 AB0488 >1@07C5B, A>2<5AB=> A 0;B08B>< 8 1;5:;>9 @C4>9, ?@>68;:>284=K5 2K45;5=8O 2 ?8@8B5 8 <5;:85 >:@C3;K 2:;NG5=8O<8 2 E0;L:>?8@8B5, 1;5:;>9 @C45, 0;B08B5. 081>;55 ?>;=> AB0488 @C4>>1@07>20=8O (I, II, III) ?@54AB02;5=K =0 25@E=5< 38?A><5B@8G5A:>< C@>2=5 2 @C4=KE B5;0E 7>=K #7C=.  7>=5 0;LB0 (A@54=89 38?A><5B@8G5A:89 C@>25=L) @0==88 AB0488 <8=5@0;>>1@07>20=8O (I, II) A>2<5I5=K A <8=5@0;L=K<8 0AA>F80F8O<8 III AB0488 8 2AB@5G0NBAO 2 =8E 2 2845 @5;8:B>2.  7>=5 '5B38 (=86=89 38?A><5B@8G5A:89 C@>25=L) @0==88 AB0488 (I, II) =5 ?@54AB02;5=K 8 >A=>2=>9 >1J5< @C4=KE B5; 2K?>;=5= 1;5:;>@C4=>-B5;;C@84=>9 AB04859 (III). @8ACBAB285 2 I @C4=>9 AB0488 B>=:>@8B<8G=>3> <5B0:>;;>84=>3> :20@F0 A D5AB>=G0BK<8 873810<8 A;>52 C:07K205B =0 2KA>:>5 ?5@5AKI5=85 @0AB2>@>2, 2>7=8:H55 2 @57C;LB0B5 @57:>3> 87<5=5=8O B5<?5@0BC@K 8 402;5=8O, :>B>@>5, :0: 8725AB=>, <>3;> ?@825AB8 : <0AA>2><C >B;>65=8N @C4=KE <8=5@0;>2, 2 =0H5< A;CG05  7>;>B0. @8 D>@<8@>20=88 II @C4=>9 AB0488 ?@>8AE>48; @>AB 0:B82=>AB8 Te 8 Bi, GB> 25@>OB=> >1CA;>28;> :@8AB0;;870F8N B5;;C@84>2 Au, Pb 8 28A<CB8=0.  E>45 III AB0488 M2>;NF8O A>AB020 @C4=>3> @0AB2>@0 E0@0:B5@87C5BAO =0@0AB0=85< 0:B82=>AB8 Sb, Te, Zn 8 Ag >B @0==8E : ?>74=8< 0AA>F80F8O<. !>AB02 28A<CB>2KE AC;LD>A>;59 2 B5G5=88 2@5<5=8 CA;>6=O5BAO: 28A<CB8=!AC;LD>A>;8: Pb Bi!Cu Bi!Pb Cu Bi!Ag Pb(Cu) Bi (Se), ?@8 MB>< : :>=FC AB0488 AC;LD>A>;8 Bi A<5=ONBAO AC;LD>A>;O<8: Cu Sb!Cu Pb Sb!Pb Sb. !>AB02 B5;;C@84>2 B0: 65 87<5=O5BAO: B5;;C@84K Au!B5;;C@84K Au-Ag!B5;;C@84K Ag-Bi!B5;;C@84K Ag. 8=5@0;K >;>20 ?@54AB02;5=K :0AA8B5@8B>< 8 A<5=ONI8<8AO 2> 2@5<5=8 AC;LD>AB0==0B0<8: Cu Fe!Cu 8 Cu Fe!Cu Zn. !0<>@>4=>5 7>;>B> ?@8ACBAB2C5B 2> 2A5E @C4=KE AB048OE 8 <8=5@0;L=KE 0AA>F80F8OE, =0E>48BAO 2 A@0AB0=8OE A :20@F5<, AC;LD840<8, 1;5:;K<8 @C40<8 8 B5;;C@840<8, >1@07C5B <5;:85 2K45;5=8O @07=>>1@07=>9 D>@<K: ?;0AB8=G0BK5, :><:>284=K5, 45=4@8B>284=K5. 0 @5=B35=>2A:>< <8:@>0=0;870B>@5  Camebax (0=0;8B8: ../:>2;520, !) ?@>2545=> 8AA;54>20=85 2K45;5=89 A0<>@>4=>3> 7>;>B0 87 2A5E <8=5@0;L=KE 0AA>F80F89 ?>;>38E @C4=KE B5;. #AB0=>2;5=>, GB> 2A5 7>;>B> O2;O5BAO 2KA>:>?@>1=K< (818 982). !>45@60=85 A5@51@0 2 A0<>@>4=>< 7>;>B5 2>7@0AB05B (1,71 16,44 25A.%) >B @0==8E <8=5@0;L=KE 0AA>F80F89 A ?8@8B>< (I @C4=0O AB048O); :0;025@8B><, 28A<CB8=><, 0;B08B>< (II @C4=0O AB048O) : ?>74=8<  A AC;LD>A>;O<8, ?5BF8B><, 35AA8B>< (III @C4=0O AB048O).  MB>< 65 =0?@02;5=88 C25;8G8205BAO @>;L <8=5@0;>2 A5@51@0. B AB0488 : AB0488 ?@>8AE>48B CA;>6=5=85 D>@<8@CNI8EAO <8=5@0;L=KE 0AA>F80F89 8 ?>2KH5=85 @>;8 <8=5@0;>2 Ag, Te, Sb 8 Zn. 8B5@0BC@0: 1. >20;5=:5@ ..,!0D>=>2 ...,0C<>2 .., CA8=>2 .. -?8B5@<0;L=>5 7>;>B>-B5;;C@84=>5 <5AB>@>645=85 >G1C;0: (#715:8AB0=) // 5>;>38O @C4=KE <5AB>@>645=89. 1997. ". 39. ! 2. !. 127 153. 2. 0E<0=>20 ., (C<A:0O .., /:>2;520 .. Se-15=60<8=8B  =>20O @07=>284=>ABL AC;LD>A>;59 // . 1990. ! 5. !. 22 26. 3. ;L8=0 .., 0E<0=>20 .., (C<A:0O ..  =5:>B>@KE @54:8E <8=5@0;0E >G1C;0:A:>3> <5AB>@>645=8O // . 1990. ! 6. !. 87 92. AA>F80F8O A0<>@>4=KE <8=5@0;>2 A8AB5<K Pb Sn Sb 87 ?>@>4 @C4=>3> :><?;5:A0 >24>@A:>3> <0AA820 1 C40H52A:89 .!., 2@BNE>20 .. 1 5E0=>1@-=0;8B, 3.!0=:B-5B5@1C@3, >AA8O, rudash@online.ru; 2!1# 3. !0=:B-5B5@1C@3, >AA8O, vuore@rambler.ru 1Rudashevsky N.S., 2Artuhova A.A. Association native minerals of system PbSnSb in ores and carbonatites of Kovdor massiv (1Mehanobr-Analyt, Saint-Petersburg, Russia; 2SPbU Saint-Petersburg, Russia). Scanning microprobe analyses and optical studies of sulphide product of Kovdrsky processing plant gave an opportunity to find association of native metals SnPbSb. This elements are dominantly presented by stistaite, native Pb and sorosite. Also, often one can meet braitgauptite, native tin, unnamed compound Cu3(Sn,Sb). Almost all grains of these minerals are containing inclusions calcite, dolomite, forsterite, apatite, magnetite, rare potassium feldspar and schorlomite. Studying association of native minerals we can make conclusion that, a great amount of reduction fluids presented during forming of a carbonatites complex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amscan-4DV, Link AN-10000). >;LH8=AB2> @0AA<0B@8205<KE 75@5= A;>65=K A0<>@>4=K< A28=F>< 8 AB8AB08B>< Sb(Sn,Pb).  =8E =5@54:> ?@8ACBAB2C5B B0:65 A>@>A8B Cu(Sn,Sb,Pb), 8=>340 =5=0720==K9 <8=5@0; A>AB020 !u3(Sn,Sb), 87@54:0 >;>2> A0<>@>4=>5.  548=8G=KE 75@=0E, A;>65==KE MB>9 0AA>F80F859 <8=5@0;>2, >1=0@C65=K =8:5;L A0<>@>4=K9 8 1@59B30C?B8B Ni(Sb,Sn). AB@5G5=K B0:65 548=8G=K5 <>=><8=5@0;L=K5 75@=0 A28=F0 A0<>@>4=>3>, 0 B0:65 42C<8=5@0;L=K5  A28=5F A0<>@>4=K9 + AC@L<0 A0<>@>4=0O, A28=5F A0<>@>4=K9 + >;>2> A0<>@>4=>5. >4G5@:=5<, GB> >1=0@C65=0 C=8:0;L=0O 0AA>F80F8O <8=5@0;>2, :>340 03@530B A28=F0 A0<>@>4=>3> 8 AB8AB08B0 >BG5B;82> 70<5I05B ?5@28G=K9 30;5=8B.  A>AB025 87CG5==KE 75@5= ?>AB>O==> ?@8ACBAB2CNB 2:;NG5=8O E0@0:B5@=KE <8=5@0;>2 @C4 8 :0@1>=0B8B>2: :0;LF8B, 4>;><8B, 48>?A84, D>@AB5@8B, <03=5B8B, 0?0B8B, 87@54:0 H>@;><8B 8 :0;852K9 ?>;52>9 H?0B. :;NG5=8O ?>@>4>>1@07CNI8E <8=5@0;>2 @07<5@0<8 >B ?5@2KE <8:@><5B@>2 4> 50 <:< 8<5NB =5?@028;L=CN D>@<C 8 >BG5B;82> F5<5=B8@CNBAO A0<>@>4=K<8 <8=5@0;0<8. ! CG5B>< 1;87?>25@E=>AB=>3> D>@<8@>20=8O ?>@>4 @C4=>3> :><?;5:A0, =86=OO B5<?5@0BC@=0O 3@0=8F0 :@8AB0;;870F88 @0AA<0B@8205<KE <8=5@0;L=KE 0AA>F80F89 2 ?5@2>< ?@81;865=88 0?@>:A8<8@C5BAO 8=B5@20;>< B5<?5@0BC@ 630 220oC: B5<?5@0BC@0 ?;02;5=8O AC@L<K (~630oC), A28=F0 (325>!) 8 >;>20 (~220oC). #AB0=>2;5==K9 D0:B 70<5I5=8O 30;5=8B0 A0<>@>4=K<8 <5B0;;0<8 A2845B5;LAB2C5B > =87:>9 DC38B82=>AB8 A5@K 2 @0AA<0B@8205<>< ?@>F5AA5 <8=5@0;>>1@07>20=8O. $>@<8@>20=85 :><?;5:A0 A0<>@>4=KE <5B0;;>2 A28=5F-AC@L<0-=8:5;L->;>2> ?>72>;O5B >F5=8BL B0:65 >:8A;8B5;L=>-2>AAB0=>28B5;L=K5 CA;>28O MB>3> ?@>F5AA0. > 2A5< 8=B5@20;5 B5<?5@0BC@ :@8AB0;;870F88 A0<>@>4=KE <5B0;;>2 DC38B82=>ABL :8A;>@>40 :>=B@>;8@>20;0AL 1CD5@>< Sn/SnO2, 1;87:8< ?> 7=0G5=8O< f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ig@anrb.ru Saveliev D.E., Sutyagina E.N. On the mineralogy of serpentinite alterations in ultramafic rocks of the Western slope of the Southern Urals (IG USC RAS, Ufa, Russia). By temperature analitical method was studed Serpentinous ultramafic rocks of the western slope of the Southern Urals. For the Zilair zone (Kraka), Uraltau zone (Byrsinsky, Abdulcasimovsky) and Main Uralian Fault zone (Nuralinsky, Abzacovsky, Burangulovsky) the intensity of serpentinization for the rocks was studied. Metamorphic facies of ultramafic rock alterations were determined. 081>;55 @0A?@>AB@0=5==K< 87 ?@>F5AA>2 <5B0<>@D87<0, ?@>O2;ONI8<AO 2 C;LB@0>A=>2=KE ?>@>40E, O2;O5BAO A5@?5=B8=870F8O.  ?>A;54=85 3>4K 4;O :>;8G5AB25==>9 >F5=:8 AB5?5=8 A5@?5=B8=870F88 ?>@>4, 0 B0:65 >?@545;5=8O D0F89 <5B0<>@D8G5A:8E ?@5>1@07>20=89 2A5 G0I5 AB0; ?@8<5=OBLAO B5@<8G5A:89 <5B>4 0=0;870 [2,3]. = O2;O5BAO 1>;55 >1J5:B82=K< 8 B>G=K< ?> A@02=5=8N A B@048F8>==K<8 ?5B@>3@0D8G5A:8<8 <5B>40<8 8AA;54>20=8O 8 ?5@5AG5B0<8 E8<8G5A:8E 0=0;87>2 87<5=5==KE C;LB@01078B>2. ;O 2KOA=5=8O CA;>289 <5B0<>@D8G5A:8E ?@5>1@07>20=89 38?5@1078B>2 =0<8 1K;> ?@>2545=> 87CG5=85 @O40 >1@07F>2 ?>@>4 87 <0AA82>2, @0A?>;>65==KE 2 ?@545;0E @07;8G=KE AB@C:BC@=>-D>@<0F8>==KE 7>= .6=>3> #@0;0: 8;08@A:>3> <530A8=:;8=>@8O (@0:0), 7>=K #@0;B0C (8@O18=A:89, 8@A8=A:89, 14C;:0A8<>2A:89) 8 ;02=>3> #@0;LA:>3> @07;><0 (C@0;8=A:89, C@0=3C;>2A:89, 170:>2A:89). AA;54>20=8O ?@>2>48;8AL 2 =AB8BCB5 35>;>388 #&  =0 45@820B>3@0D5 Q-1500D D8@<K $.0C;8:, /.0C;8:, .-@459 (5=3@8O) (0=0;8B8: "..'5@=8:>20). 0AA82K @0:0 E0@0:B5@87CNBAO 2 F5;>< =52KA>:>9 AB5?5=LN A5@?5=B8=870F88: 2> 2=CB@5==8E 7>=0E <0AA82>2 >=0 A>AB02;O5B >B 35 4> 80%. 8=5@0;K 3@C??K A5@?5=B8=0 ?@54AB02;5=K 3;02=K< >1@07>< (-;870@48B>< (10 70%), @565  :;8=>E@87>B8;>< (8 12%). >A:>;L:C (-;870@48B O2;O5BAO 8=48:0B>@=K< <8=5@0;>< =081>;55 =87:>B5<?5@0BC@=>9 ABC?5=8 @53@5AA82=>3> (@538>=0;L=>3>) <5B0<>@D87<0 [3], B> 87 ?@82545==KE 40==KE <>6=> A45;0BL 2K2>4 > ?@5>1;040NI5< @5B@>3@04=>< E0@0:B5@5 A5@?5=B8=870F88 38?5@1078B>2 @0:0. <5AB5 A B5<, :@052K5 G0AB8 <0AA82>2 A5@?5=B8=878@>20=K 1>;55 8=B5=A82=>, 745AL ?@58<CI5AB25==>5 @0A?@>AB@0=5=85 8<55B E@87>B8; (4> 100%), O2;ONI89AO 8=48:0B>@>< ?@>3@5AA82=>3> (:>=B0:B>2>3>) <5B0<>@D87<0. =B83>@8B 2 38?5@1078B0E <0AA82>2 @0:0 =5 >B<5G5=. 8?5@1078BK 7>=K #@0;B0C >B;8G0NBAO AB018;L=> 2KA>:>9 AB5?5=LN A5@?5=B8=870F88 (90 100%), @5;8:BK ?5@28G=KE <8=5@0;>2 2 =8E >B<5G0NBAO >G5=L @54:>. ;02=K<8 ?>@>4>>1@07CNI8<8 <8=5@0;0<8 A5@?5=B8=8B>2 8@A8=A:>3>, 8@O18=A:>3> 8 14C;:0A8<>2A:>3> <0AA82>2 O2;ONBAO 0=B83>@8B 8 E@87>B8;, A;030NI85 2<5AB5 A <03=5B8B>< >B 60 4> 100% ?>@>4K. @><5 B>3>, 8=>340 2 70<5B=KE :>;8G5AB20E ?@8ACBAB2CNB <03=578B, 1@CA8B, <03=5780;L=K9 E;>@8B. "0:8< >1@07><, <0:A8<0;L=0O ABC?5=L <5B0<>@D87<0 38?5@1078B>2 7>=K #@0;B0C >B25G05B 0=B83>@8B>2>9 D0F88, :>B>@0O 2 A2>N >G5@54L A>>B25BAB2C5B M?84>B-0<D81>;8B>2>9 D0F88 @538>=0;L=>3> <5B0<>@D87<0 ?> [3]. >@>4K @0A?>;>65==>3> 2 MB>9 65 7>=5 8@O18=A:>3> 3011@>-?8@>:A5=8B>2>3> <0AA820 <5B0<>@D87>20=K 2 B>9 65 D0F88 [1]. @8C@>G5==>ABL <0AA82>2 3011@>84>2 8 38?5@1078B>2 : 548=>9 AB@C:BC@5, AE>4=K5 CA;>28O ?@5>1@07>20=8O 8 1;87>ABL ?5B@>35>E8<8G5A:8E E0@0:B5@8AB8: [4] ?>72>;ONB ?@54?>;>68BL ?@8=04;56=>ABL 8E : 548=><C >D8>;8B>2><C :><?;5:AC.  ?@545;0E ;02=>3> #@0;LA:>3> @07;><0 AB5?5=L A5@?5=B8=870F88 38?5@1078B>2 ACI5AB25==> 20@L8@C5B >B <0AA820 : <0AA82C. 08<5=55 87<5=5==K<8 ?>@>40<8 A;>65= C@0;8=A:89 <0AA82: C;LB@01078BK A5@?5=B8=878@>20=K 2 ;870@48B>2>9 D0F88 =0 35 55%. >;55 7=0G8B5;L=> ?@>O2;5= <5B0<>@D87< 2 38?5@1078B0E 170:>2A:>3> <0AA820. 0@F1C@38BK A5@?5=B8=878@>20=K :0: ?@028;> =0 80 100%, 25@;8BK 8 ?8@>:A5=8BK  =0 40 55%. 45AL =081>;LH55 @0A?@>AB@0=5=85 8<5NB ;870@48B-E@87>B8;>2K5 A5@?5=B8=8BK A A>>B=>H5=85< 1:2. =B83>@8B>2K5 A5@?5=B8=8BK 2 7>=5 # 0 2AB@5G5=K =0<8 B>;L:> =0 C@0=3C;>2A:>< <0AA825. =0G8B5;L=K5 @07;8G8O 2 AB5?5=8 A5@?5=B8=870F88 8 D0F8OE <5B0<>@D87<0, ?@>O282H53>AO 2 38?5@1078B0E 70?04=>3> A:;>=0 .6=>3> #@0;0, =0 =0H 273;O4, >1CA;>2;5=K A;>6=>9 35>;>38G5A:>9 8AB>@859 40==>9 ?;>I048. 45AL ?@54AB02;5=K <0AA82K A @07;8G=>9 AB5?5=LN 45?;5B8@>20==>AB8, AD>@<8@>20==K5 2 @07;8G=KE 35>48=0<8G5A:8E >1AB0=>2:0E. 0: A;54AB285, 4;O =8E E0@0:B5@=K 1K;8 8 @07;8G=K5 CA;>28O ?@5>1@07>20=8O :0: 2 <0=B89=KE, B0: 8 2 :>@>2KE CA;>28OE. 8B5@0BC@0: 1. ;5:A552 .. 03<0B8G5A:85 :><?;5:AK 7>=K E@51B0 #@0;B0C. .: 0C:0. 1976. 170A. 2.5@820B>3@0<<K, 8=D@0:@0A=K5 8 <5AA10CM@>2A:85 A?5:B@K AB0=40@B=KE >1@07F>2 D07>2>3> A>AB020 (4>?>;=5=85 : :0B0;>3C). !1., 1992. 3.0:552 .., @O=G0=8=>20 .. ">?><8=5@0;>38O C;LB@01078B>2 >;O@=>3> #@0;0. !1.: 0C:0. 1999. 252A. 4. K:CA .. 8 4@. A04:>=0:>?;5=85, <03<0B87< 8 @C4>>1@07>20=85 A525@=>9 G0AB8 7>=K #@0;B0C. #D0: #. 2002. 266 A.  &+ - -" ! !" / (.+ # , !!/) !5<:>20 ".. XE "!5<:>20 ".."  !1#, 3. !0=:B-5B5@1C@3, >AA8O, semkova@yandex.ru Semkova T.A. Manganoan aegirine-augite from kozhaevskoye deposit, the South Ural, Russia (St.-Petersburg State University, St.-Petersburg, Russia). The paper contains a mineralogical description of manganoan aegirine-augite. The mineral was found in Kozhaevskoye deposit, South Ural, Russia. The Kozhaevskoye deposit is an example of low-grade metamorphosed volcano-sedimentary oxide-carbonate-silicate manganese ores. Manganese ores consist of rhodonite, tephroite, manganese grossularite, albite, hematite, hausmannite, rhodochrosite, spessartine, andradite, manganaxinite, piemontite, caryopilite, coombsite, parsettensite, baric bannisterite, neotocite, titanite, actinolite, quartz, pyrofanite, pyrite, chalcopyrite, barite and apatite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p  :>@8G=52K9, Ng  B5<=K9 75;5=>-:>@8G=52K9, Nm  A25;K9 75;5=>-:>@8G=52K9. 8A?5@A8O r<v, OA=0O; cNp SYMBOL 187 \f "Symbol" \s 12  10 12SYMBOL 176 \f "Symbol" \s 12; 2V87<5@.=70(5); npSYMBOL 187 \f "Symbol" \s 12 1,705, ng>1,734. %8<8G5A:89 A>AB02 ?8@>:A5=0 ?> 40==K< <8:@>7>=4>2>3> 0=0;870 A;54CNI89 (<0A. %): M38@8=-0238B I  SiO2 52,04, Al2O3 0,87, Fe2O3>1ISYMBOL 45 \f "Symbol" \s 12-19,40, MnO>1ISYMBOL 45 \f "Symbol" \s 12-8,30, MgOSYMBOL 45 \f "Symbol" \s 12-3,75, CaOSYMBOL 45 \f "Symbol" \s 12-8,11, Na2OSYMBOL 45 \f "Symbol" \s 12-7,40, AC<<0  99,87. 0AAG8B0==0O =0 4 :0B8>=0 :@8AB0;;>E8<8G5A:0O D>@<C;0 8<55B 284: (Na0,55Ca0,34Mn0,09)0,98(Fe0,513+Mg0,22Mn0,18Fe2+0,04Al0,04)1,00(Si2,02O6,01). -38@8=-0238B-III: SiO2SYMBOL 45 \f "Symbol" \s 12-51,92, Al2O3SYMBOL 45 \f "Symbol" \s 12-0,84, Fe2O3>1I SYMBOL 45 \f "Symbol" \s 12-23,12, MnO>1ISYMBOL 45 \f "Symbol" \s 12-4,82, MgOSYMBOL 45 \f "Symbol" \s 12-3,44, CaOSYMBOL 45 \f "Symbol" \s 12-7,20, Na2OSYMBOL 45 \f "Symbol" \s 12-8,71, AC<<0  100,04. @8AB0;;>E8<8G5A:0O D>@<C;0 8<55B 284: (Na0,65Ca0,29Mn0,07)1,01(Fe0,633+Mg0,20Mn0,09Fe2+0,04Al0,04)1,00(Si1,99O6,00). 84=>, GB> 2 >1>8E A;CG0OE 2 ?>78F88 1 ?@5>1;0405B =0B@89, 0 2 ?>78F88 2 SYMBOL 45 \f "Symbol" \s 12- B@5E20;5=B=>5 65;57>. !>3;0A=> ?@8=OB><C   ?@028;C 50 % B0:>9 ?8@>:A5= 4>;65= =07K20BLAO M38@8=><, 0 A CG5B>< 2KA>:>3> A>45@60=8O <0@30=F0 (Mn = 0,16 D.5.)  <0@30=F52K< M38@8=><. 4=0:>, 2 A>>B25BAB288 A ?@8=OB>9 B>9 65 :><8AA859 =><5=:;0BC@>9 ?8@>:A5=>2 [3], A>AB02 87CG5==>3> =0<8 ?8@>:A5=0 >B25G05B <0@30=F52><C M38@8=-0238BC. ;02=K5 ;8=88 48D@0:B>3@0<<K 4;O M38@8=-0238B0-III d()/I: 6,39/40, 4,43/40, 2,93/15, 2,99/100, 2,91/60, 2,53/35, 2,49/35, 2,20/15, 2,02/15, 1,98/10, 1,61/10, 1,51/10. 0@0<5B@K M;5<5=B0@=>9 OG59:8 ?8@>:A5=0 B@5BL59 35=5@0F88 (): a0=9,5830,006; b0=8,8410,004; c0=5,2810,003; SYMBOL 98 \f "Symbol" \s 12b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asgupta S. P T X relationships during metamorphism of manganese-rich sediments: Current status and future studies // Geol. Soc., Spec. Publ. ! 119. London, 1997. P. 5(27. 3. Morimoto et al. Nomenclature of pyroxenes. // Am. in., 1988. v.73. .1123 1133.  <8=5@0;L=>< A>AB025  A8=8E 3;8= =86=53> :5<1@8O A525@>-70?040 CAA:>9 ?;0BD>@<K 1C5@3552 . !., 1>9;> -. . 1 !0=:B-5B5@1C@3A:89 3>AC40@AB25==K9 C=825@A8B5B, :0D54@0 <8=5@0;>388; Sergeev D.S., Goilo E.A. About the mineral composition of the low Cambrian  blue clays from the north east region of Russian platform. (1Saint Petersburg State University, Department of Mineralogy, St-Petersburg, Russia) Three fractions of low Cambrian clays of Leningrads region (pelite, sandpelite and heavy fractions) were studied by the Xray powder diffraction method, visual and optical observation. The following mineral species were determined. Among them the mainly allotigent minerals are quartz, almandine and zircon, the autigent minerals are pyrite, hematite, ilmenite and carbonates. The light fraction consists of interlayerdeficient mica of glauconite row with kaolinite, chlorite, quartz and feldspar. It is shown that diagenetic transformations in Cambrian clays proceeded very slowly. ;8=K A825@A:>9 A28BK =86=53> :5<1@8O, =01;N405<K5 2 <=>3>G8A;5==KE ?@8@>4=KE 8 B5E=>35==KE M:A?>78F8OE 2 ?@83;8=B>2>9 G0AB8 B5@@8B>@88 5=8=3@04A:>9 >1;0AB8 2> <=>38E >B=>H5=8OE O2;ONBAO C=8:0;L=K< 35>;>38G5A:8< >1J5:B><. 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"0:, 2 >1@07F5 A402;5==>9 3;8=K A>:@0I5=85 d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ieder  Nomenclature of micas . Mineralogical Magazine, April 1999, Vol. 63(2), pp. 267 279. 2. . . $@0=:  0<5=5F:89, . . >B>2, -. . >9;>  5=B35=>3@0D8O <8=5@0;L=>3> AK@LO !1>@=8: 7 874. 54@0 ., 19703. $"-  ".!&&/ !" !# ! !" /   #,! !"&   !"&  % #/ !<>;O=A:89 .. XE "!<>;O=A:89 .."  !, 3. !0=:B-5B5@1C@3, >AA8O, psm@mail.axon.ru Smolyansky P.L. Photo- and X-ray exited optical luminescence (XEOL) of sellaite from Suran deposit by atationary, quasistationary and nanosecond pulsed excitation (VSEGEI, St. Petersburg, Russia). Spectrum and kinetic parameters of UV- and X-ray excited luminescence of 35 sellaite samples from Suran deposit (South Urals) unique in genesis and ore properties have been studied. Comparisons of the luminescence spectra, excitation spectra and luminescence lifetimes of natural and artificially irradiated sellaite samples enabled to figure out a number of point defects of the mineral, with which four main wide and intensive fluorescence bands are connected: blue ((max = 420 nm), bluish-green (460 =<), yellow (560 nm) and red (590 nm). It s shown that intrinsic imperfections of sellaite are mobile and sensitive to external influence (X- and (-irradiation; 300C annealing). Possible nature of luminescence centres of Suran s sellaite is discussed. !5;;08B (Mg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gF2, ?>72>;8;8 2KO28BL @O4 B>G5G=KE 45D5:B>2 <8=5@0;0, A :>B>@K<8 A2O70=K >A=>2=K5 H8@>:85 8 8=B5=A82=K5 ?>;>AK A25G5=8O: A8=OO ((max = 420 =<), A8=5-75;5=0O (460 =<), 65;B0O (560 =<) 8 :@0A=0O (590 =<). 5@2K5 B@8 87 =8E ?@54AB02;O5BAO 2>7<>6=K< ?@8?8A0BL D878G5A:8 =5M:2820;5=B=K< 4820:0=A8>==K< M-F5=B@0< M;5:B@>==>9 >:@0A:8, E0@0:B5@87CNI8<AO A>>B25BAB25==> A8<<5B@859 B>G5G=KE 3@C?? C2h , D2h 8 !1. 1AC640NBAO B0:65 4@C385 2>7<>6=K5 <>45;8  65;BKE 8  :@0A=KE F5=B@>2 A25G5=8O A5;;08B0, 0 B0:65 ?@>8AE>645=85 53>  8=5@F8>==>3> 75;5=>3> A25G5=8O. A>1>5 2=8<0=85 C45;O5BAO ;N<8=5AF5=B=K< A2>9AB20< A8=59 ?>;>AK A (max = 420 =< (@8A.1 1), ?> A2>8< A?5:B@0;L=K< E0@0:B5@8AB8:0< ?@0:B8G5A:8 A>2?040NI59 A 87;CG5=85< Eu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g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molyansky P.L. Spectra and kinetics of luminescence of sellaite and fluorite from Suran deposit (S. Urals) // IGC. Brazil. 2000. (sec. of phys. and chem. minerals), publishing in CD. 4.C<>;O=A:89 .. KO2;5=85 =5B@048F8>==>3> DB>@8AB>3> AK@LO <5B>40<8 ;N<8=5AF5=B=>9 A?5:B@>A:>?88 // 1>30I5=85 @C4, 2002. ! 2. !.25 30. 5.30D>=>2 .., >;>28= .., >4=K9 .. N<8=5AF5=F8O F5=B@>2 >:@0A:8 2> DB>@845 <03=8O // ?B8:0 8 A?5:B@>A:>?8O, 1986. ".60. !2. !.297 300. &!"   + +" / ! "" ! !" / % "-!!". !>:>;-CBK;>2A:89 .. 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BACBAB285 2 >3@0=:5 :@8AB0;;>2 >1KG=>3> 4;O F5;5AB8=0 107>?8=0:>840 A{001} ?@8405B 8< >AB@>:>=5G=CN D>@<C. 5=B35=>3@0<<0 <8=5@0;0, A=OB0O 2 @5=B35=>AB@C:BC@=>9 ;01>@0B>@88 # (48D@0:B><5B@  -2,0, 0=0;8B8: ..!0?>6=8:>20), A>>B25BAB2C5B MB0;>==>9 4;O F5;5AB8=0 87 :0@B>B5:8 ASTM (:0@B0 5 0593) 8 E0@0:B5@87C5BAO A;54CNI8<8 >B@065=8O<8 (d, ; (I)): 3,76 (30), 3,42 (50), 3,29 (100), 3,18 (50), 2,96 (90), 2,73 (50), 2,67 (40). 8=5@0; >:@0H8205B ?;0<O A?8@B>2:8 2 :@0A=K9 F25B A <0;8=>2K< 8 ?C@?C@=>-:@0A=K< >BB5=:><, GB> ?>4B25@6405B =0;8G85 AB@>=F8O 2 53> A>AB025. >;C:>;8G5AB25==K< 0=0;87>< :@><5 F5;5AB8=0 1K;8 CAB0=>2;5=K A;54CNI85 E8<8G5A:85 M;5<5=BK: 10@89 (4> 2%), :0;LF89 (>:>;> 1%), =8:5;L 8 E@>< (>:>;> 0,01%). 0E>4:C F5;5AB8=0 2 =5>1KG=>9 4;O =53> >1AB0=>2:5  :>@5 2K25B@820=8O A5@?5=B8=8B>2  <>6=> >1JOA=8BL ?@>A0G820=85< 0B<>AD5@=KE 2>4, =5ACI8E A A>1>9 AB@>=F89 8 ?>ABC?0NI8E 87 2KH5;560I8E <>@A:8E B>;I, ?5@5:@K20NI8E :>@C 2K25B@820=8O. @54?>;>65=85, GB> F5;5AB8= =5 O2;O5BAO ?@>4C:B>< @07@CH5=8O A5@?5=B8=8B>2, ?>4B25@6405BAO >BACBAB285< AB@>=F8O, :0: 2 A0<8E A5@?5=B8=8B0E, B0: 8 2 >?0;0E. % " + !!"   !" )!"  . !% "  +% "/% .-!"  !  1!>;>BG8= .., 2(C;L65=:> !.. 1 ! , >2>A818@A:, >AA8O, paul@uiggm.nsc.ru, 2 ! , >2>A818@A:, >AA8O, serzh@uiggm.nsc.ru 1Solotchin P.A., 2Shulzhenko S.G. Characteristic features of clay matter mineralogy in Lower Jurassic terrigenous deposits of South-East of West Siberia (1IG SB RAS, Novosibirsk, Russia; 2UIGGM SB RAS, Novosibirsk, Russia). Clay minerals from Lower Jurassic sediments of the south-east part of the West Siberian plate are investigated. With the help of some methods the peculiar properties of their composition, structures, crystal chemistry and morphology are investigated. It is shown, that prevailing minerals are minerals of kaolinite group, illite and chlorite, moreover mixed-layer illite/smectite, sometimes bertherine occur. Associations of clay minerals in various types of rocks are established. Regularity in predominance of one or another mineral depending on grain-size of sedimrnts is revealed. In detail bertherine and minerals of kaolinite group are investigated from the point of view of their genesis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lena@AA5709.spb.edu.,  HYPERLINK mailto:vuore@rambler.ru vuore@rambler.ru Soukharjevskaya E.S., Artuhova A.A. Sulfide mineralisation of carbonatites and ores of the Kovdor massif (SPbSU, St-Petersburg, Russia). During this work sulfide mineralisation of Kovdor massif was investigated by optical and microprobe methods. The following minerals have been obtained: pyrrhotite, pentlandite, cobalt pentlandite, pyrite, valleriite, chalcopyrite, sphalerite, cubanite, bornite, galena, marcasite. On the basis of the study of sulfide minerals relationships, the sequence of the minerals were determined. !C;LD84=0O <8=5@0;870F8O =5 O2;O5BAO H8@>:> @0A?@>AB@0=5==>9 2 ?>@>40E @C4=>3> :><?;5:A0 >24>@A:>3> <5AB>@>645=8O. 1KG=> A>45@60=85 AC;LD84>2 2 ?>@>40E :0@1>=0B8B>2>9 A5@88 =5 ?@52KH05B 1 5%. 081>;LH8< @0A?@>AB@0=5=85< ?>;L7CNBAO AC;LD84K 2 @C40E 8 :0@1>=0B8B0E A B5B@0D5@@8D;>3>?8B><. !0<K< @0A?@>AB@0=5==K< AC;LD84>< O2;O5BAO ?8@@>B8=.  D>@AB5@8B>2KE 8 0?0B8B>-D>@AB5@8B>2KE ?>@>40E =081>;55 :@C?=K5 2K45;5=8O ?8@@>B8=>2 ?@8C@>G5=K : 7>=0< :0@1>=0B870F88.  MB8E ?>@>40E B0:65 2AB@5G0NBAO E0;L:>?8@8B 8 ?8@8B 2 ?>4G8=5==>< :>;8G5AB25.  0?0B8B>-D>@AB5@8B>-<03=5B8B>2KE ?>@>40E ?8@@>B8= >1@07C5B B>=:85 ?@>68;:8 8 2:@0?;5=8O =5?@028;L=>9 D>@<K @07<5@>< 1 5 <<. B<5G0NBAO A@0AB0=8O 53> 75@5= A <03=5B8B><, 0 B0:65 2:;NG5=8O <03=5B8B0 2 A0<>< ?8@@>B8=5. > B>=:8< B@5I8=:0< 2 ?8@@>B8=5 =5@54:> @0728205BAO <5;:>:@8AB0;;8G5A:89 ?8@8B. %0;L:>?8@8B 2 MB8E @C40E =0E>48BAO 2 ?>4G8=5==>< :>;8G5AB25. ;O :0;LF8B>-D>@AB5@8B>-<03=5B8B>2KE 8 @54:><5B0;L=KE @C4 E0@0:B5@=K ?8@@>B8= 8 E0;L:>?8@8B, :>B>@K5 =01;N40NBAO 2 2845 <5;:8E 2:@0?;5=89, ?@8C@>G5==KE : 3=5740< :0;LF8B0. 8@8B 2 MB>< B8?5 @C4 >B<5G05BAO 2 2845 :>@>G5:, @072820NI8EAO ?> 7>=0< B@5I8=>20B>AB8 ?8@@>B8=0 8 <03=5B8B0.  @54:><5B0;L=KE @C40E, 2 0AA>F80F88 A 2KH5?5@5G8A;5==K<8 AC;LD840<8 2AB@5G0NBAO :C10=8B, 1>@=8B, 465@D8H5@8B 8 AD0;5@8B, @0A?@545;5=85 :>B>@KE >G5=L =5@02=><5@=>. !D0;5@8B 2AB@5G05BAO ;8HL ?@8 <8:@>A:>?8G5A:8E 8AA;54>20=8OE 2 2845 AB@C:BC@ @0A?040 2 E0;L:>?8@8B5.  :0@1>=0B8B0E AC;LD84K ;>:0;87CNBAO 2 2845 @02=><5@=>@0AA5O==>9 2:@0?;5==>AB8, =5@54:> ?>4G5@:820O ?>;>AG0B>ABL ?>@>4, 8;8 2 2845 ?@>68;:>2 8 3=574 =5?@028;L=>9 D>@<K.  ?>@>40E :0@1>=0B8B>2>9 A5@88 =0<8 CAB0=>2;5=K A;54CNI85 AC;LD84=K5 <8=5@0;K: ?8@@>B8= (35:A03>=0;L=K9 8 <>=>:;8==K9), ?5=B;0=48B, :>10;LB?5=B;0=48B, 20;;5@88B, ?8@8B, E0;L:>?8@8B, AD0;5@8B, :C10=8B, 465@D8H5@8B, <0@:078B, 1>@=8B 8 30;5=8B. 081>;55 @0A?@>AB@0=5==K<8 O2;ONBAO ?8@@>B8= 8 E0;L:>?8@8B. 8@@>B8= =01;N405BAO 2 2845 87><5B@8G=KE 75@5= 8;8 :@8AB0;;>2 ?;0AB8=G0B>9 D>@<K @07<5@>< 4> 1,5 A< 2 ?>?5@5G=8:5, 8=>340 >1@07CO F5?>G:>>1@07=K5 8 68;>?>4>1=K5 A:>?;5=8O :0: 2 @C40E, B0: 8 2 :0@1>=0B8B0E. > 40==K< <8:@>7>=4>2>3> 8AA;54>20=8O ?8@@>B8=>2 87 @07;8G=KE B8?>2 @C4 8 :0@1>=0B8B>2, >B<5G05BAO =5@02=><5@=> @0A?@545;5==0O ?@8<5AL Co 8 Cu, ?@8G5< CAB0=>2;5=0 B5=45=F8O =0@0AB0=8O >B=>A8B5;L=>3> A>45@60=8O Co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mailto:s.p.roev@diamond.ysn.ru s.p.roev@diamond.ysn.ru Trunilina V.A., Roev S.P. Si-bearing ilmenite from magmatic rocks of Verchoyansk-Kolyma mesozoides (IGDNM SBRAS, Yakutsk, Russia). Mineral is for the first time described E.A.Shamshina and N.V. Zayakina [1] in potassic alkaline tuffs of Olenyok uplift of a Siberian platform. It has ilmenite structural type and widely variated composition. Usually at study of heavy fractions of patterns is accepted for ilmenite. By us this mineral is found out in the high-temperature volcanic and subvolcanic rocks of various composition (andesibasalt, andesite, rhyolite) and, less often, in zones tempering hypabyssal massifs of granitoids with increased basic. The physical parameters and variation of composition are very similar to resulted above by authors (wt.%): TiO2=26.652.2; SiO2=8.827.8; Al2O3=1.57.7; FeO=418.8; MnO=3.817.9; MgO=24; CaO=2.120.4; Na2O=02.4; K2O=04.7; Cr2O3=00.23. The return dependence Ti and Si confirms isomorphic replacement of these components in structure mineral. Direct dependence of the contents Si and Al from temperature liquidus of melts is increased also. To reduction of temperature there is the disintegration mineral on two phases of varying compositions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iO2=30 53; SiO2=8 30; Al2O3=1,6 6,3; FeO=5,1 13; MnO=6,4 15,5; MgO=2,1 4,4; CaO=3,8 15,7; Na2O=0 1,4; K2O=0 4; Cr2O3=0,1 0,3. #AB0=>2;5=0 >1@0B=0O 7028A8<>ABL <564C A>45@60=8O<8 TiO2 8 SiO2, =0 >A=>20=88 G53> A45;0= 2K2>4 >1 87><>@D87<5 Ti 8 Si 2 AB@C:BC@5 <8=5@0;0, 8 ?@O<0O  <564C A>45@60=8O<8 SiO2 8 Al2O3. 7CG5=85 M;5:B@><03=8B=KE BO65;KE D@0:F89 ?@>B>;>G5: ?@>1 MDDC782=KE 8 AC12C;:0=8G5A:8E ?>@>4 @07;8G=>3> A>AB020 (0=45781070;LB>2, 0=4578B>2, @8>;8B>2, B@0E8B>2, I5;>G=KE ;0<?@>D8@>2) ?>:070;>, GB> MB>B <8=5@0; ?>;L7C5BAO H8@>:8< @0A?@>AB@0=5=85< 8 2 <03<0B8G5A:8E ?>@>40E 5@E>O=> >;K<A:8E <57>7>84, 345 ?@8=8<05BAO 70 >1KG=K9 8;L<5=8B. 1I8< 4;O 2A5E MB8E ?>@>4 O2;O5BAO 1KAB@0O A:>@>ABL 8 2KA>:0O B5<?5@0BC@0 :@8AB0;;870F88 @0==5<03<0B8G5A:8E ?0@035=578A>2 <8=5@0;>2. 8=5@0; 2AB@5G05BAO B0:65 2 3@0=8B>84=KE <0AA820E ?>2KH5==>9 >A=>2=>AB8, 345 CAB0=>2;5= 2 ?>@>40E M=4>:>=B0:B>2KE 7>=.  ?>@>40E 3;02=>9 D0F88 =01;N40;8AL 75@=0 1;87:>3> AC<<0@=>3> A>AB020, => A B>=:8<8 AB@C:BC@0<8 @0A?040, B.5. 2 CA;>28OE A=865=8O B5<?5@0BC@ 8 ?>2KH5=8O 2>4=>3> 402;5=8O <8=5@0; =5CAB>9G82. $878G5A:85 :>=AB0=BK 8 A>AB02 <8=5@0;0 1;87:8 >?8A0==K< -.. (0<H8=>9 8 .. 0O:8=>9 [1]. %8<8G5A:89 A>AB02 >4=>@>4=KE 75@5= (<0A.%): TiO2=26,6 52,2; SiO2=8,8 27,8; Al2O3=1,5 7,7; FeO=4 18,8; MnO=3,8 17,9; MgO=2 4; CaO=2,1 20,4; Na2O=0 2,4; K2O=0 4,7; Cr2O3=0 0,23. @8 MB>< Si 8 Ti A2O70=K >1@0B=>9 7028A8<>ABLN (@8A.1), GB> ?>4B25@6405B <=5=85 C:070==KE 02B>@>2 >1 87><>@D87<5 MB8E M;5<5=B>2 2 AB@C:BC@5 <8=5@0;0. >AB0B>G=> >BG5B;82> 2K@065=0 B0:65 ?@O<0O 7028A8<>ABL <564C Si 8 Al (@8A.2), A>45@60=8O :>B>@KE 7028AOB, 2848<>, :0: >B B5<?5@0BC@K ;8:284CA0, B0: 8 >B A>AB020 <0B5@8=A:>3> @0A?;020. %>BO ?@54AB>8B 5I5 1>;LH0O @01>B0 ?> 87CG5=8N AB@C:BC@K <8=5@0;0, 40==>9 ?C1;8:0F859 <K E>B5;8 >1@0B8BL 2=8<0=85 4@C38E 8AA;54>20B5;59 =0 2>7<>6=>ABL >1=0@C65=8O 0=0;>38G=>3> <8=5@0;0 (3@C??K <8=5@0;>2) 8 2 4@C38E ?>@>40E 8 @538>=0E, GB> ?>72>;8B ?@>OA=8BL 53> 35=5B8G5A:CN ?@8@>4C. 8A. 2. !>>B=>H5=85 SiO2 8 Al2O3 2 :@5<=89A>45@60I5< 8;L<5=8B5 87 <03<0B8G5A:8E ?>@>4 5@E>O=>->;K<A:8E <57>7>84 (1 3  A<. @8A. 1). Fig.2. Diagram of SiO2 and Al2O3 contents in Si-bearing ilmenite from magmatic rocks of Verkhoyansk-Kolyma mesozoides (1 3  see. Fig.1). 8B5@0BC@0: 1. Shamshima E..., Zayakina N.V. Si-bearing ilmenite from tuff pipes of Olenyok uplift, N. E. of Siberian //17-th General Meeting IM, Toronto, 1998. . 113. + #+ ",- "+% "!""  " $ & ( ! !" / (!  # ) $8;8<>=>2 !.. XE "$8;8<>=>2 !.."  >A:>2A:89 3>AC40@AB25==K9 C=825@A8B5B, >A:20, >AA8O, mineral@geol.msu.ru The first finding of fahlores occured within the talc-carbonate propylite-type alteration in the Shabrovskoe deposit, Central Urals, is described. Chemical composition of the fahlores ranges from Cu-rich and low Sb tennantite to Cu- and As-rich tetrahedrite. Tennantite associated with bornite and enriched in Fe and Cu dominates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E E8<8G5A:89 A>AB02 ?@82545= 2 B01;8F5. ;5:;K5 @C4K 87 4>;><8B>2KE <@0<>@>2 ?@54AB02;5=K B5==0=B8B>< 8 Sb-B5==0=B8B><, 0 87 4>;><8B>2KE ?@>68;:>2  As-B5B@0M4@8B><. > 2A5E A;CG0OE <8=5@0; O2;O5BAO 2KA>:><548ABK< 8 65;578ABK<. %0@0:B5@=K =51>;LH85 ?@8<5A8 Se (4> 0,16 <0A.%) 8 Ag (4> 0,14 <0A.%). 1@0I05B 2=8<0=85 >BACBAB285 2 A>AB025 1;5:;KE @C4 F8=:0. 5@>OB=>, MB> A2O70=> A 8E D>@<8@>20=85< A@548 87<5=5==KE 38?5@1078B>2. >@=8B A;0305B =5?@028;L=>9 D>@<K 2K45;5=8O 2 4>;><8B5, 0 B0:65 A@0AB0=8O A 1;5:;K<8 @C40<8. =>340 <8=5@0; A>45@68B ;0<5;;8 E0;L:>?8@8B0.  >B@065==>< A25B5 <8=5@0; 87>B@>?=K9. ?B8G5A:85 A2>9AB20 AB0=40@B=K5. !>AB02 1>@=8B0 (<0A.%): Cu 63,22, Ag 0,11, Fe 9,94, Cd 0,06, Bi 0,16, Te 0,06, S 24,94, Se 0,02, Zn, Hg, As, Sb =5 >1=., AC<<0 98,51.$>@<C;0: (Cu5,092Ag0,005)5,097(Fe0,912Cd0,003)0,915(S3,981Bi0,004Te0,002Se0,001)3,988. %0;L:>78= >1@07C5B :05<:8 70<5I5=8O 2>:@C3 1;5:;KE @C4 8 1>@=8B0.  >B@065==>< A25B5 <8=5@0; A5@K9 A> A;01K< 3>;C1>20BK< >BB5=:><, A;01> 0=87>B@>?5=.  =5:>B>@KE 2K45;5=8OE >BG5B;82> =01;N405BAO A>25@H5==0O A?09=>ABL. !>AB02 (<0A.%) Cu 78,62, Ag 0,03, Zn 0,04, Fe 0,24, Hg 0,24, Cd 0,02, Bi 0,07, S 19,69, As, Sb, Te, Se =5 >1=., AC<<0 98,95. $>@<C;0 (Cu1,997Fe0,007Hg0,002Zn0,001)2,007 (S0,992Bi0,001)0,993. !>AB02 E0;L:>78=0 AB5E8><5B@8G5=. 60@;58B 8 :>25;;8= A;030NB <5;:>75@=8ABK5 03@530BK ?> 3@0=8F0< 75@5= E0;L:>78=0, 1>@=8B0, >1@07CNB G0AB8G=K5 8;8 ?>;=K5 ?A524><>@D>7K ?> E0;L:>78=C.  >B@065==>< A25B5 460@;58B >BG5B;82> 3>;C1>9, 42C>B@065=85 A;01>5, 0=87>B@>?8O 70<5B=0O. >25;;8=  O@:>-3>;C1>9 A A8;L=K< 42C>B@065=85< (>:@0A:0 <5=O5BAO >B B5<=>-A8=59 4> A25B;>-3>;C1>9). -DD5:BK 0=87>B@>?88 O@:> @>7>2K5. !>AB02 :>25;;8=0 (<0A.%): Cu 66,19, Ag 0,32, Zn 0,05, Fe 0,04, Hg 0,23, Bi 0,03, Te 0,09, S 31,15, Se 0,03, Pb, Sn, Cd, As, Sb =5 >1=., AC<<0 98,13. $>@<C;0 (Cu1,031Ag0,003Zn0,001Fe0,001Hg0,001)1,037(S0,962Te0,001)0,963. 7-70 <0;>3> @07<5@0 2K45;5=89 @5=B35=><5B@8G5A:85 E0@0:B5@8AB8:8 >?8A0==KE 2KH5 <8=5@0;>2 ?>;CG8BL =5 C40;>AL. "01;8F0 %8<8G5A:89 A>AB02 (<0A.%) 1;5:;KE @C4 87 B0;L:-:0@1>=0B=KE <5B0A><0B8B>2 ?@>?8;8B>2>9 D>@<0F88 (01@>2A:>3> <5AB>@>645=8O Compositions (wt.%) of fahlores from talc-carbonate propylite-type alteration !CuAgZnFeHgAsSbBiSSe!C<<0145,990,040,053,120,2819,102,86=.>.27,010,1698,61245,280,140,183,27=.>.16,915,180,0426,650,1297,77344,19=.>.0,042,62=.>.12,8212,160,2726,220,0298,34443,540,050,042,670,606,8420,000,0526,130,11100,03@8<5G0=8O. -;5:B@>==K9 <8:@>7>=4  Cameca SX-50 (:0D54@0 <8=5@0;>388 #), 0=0;8B8:8 ..>=>=:>20 8 ..>@>B0520. =.>.  M;5<5=B =5 >1=0@C65=. Cd, Pb, Te, Sn  =5 >1=0@C65=K. =. 1 3  B5==0=B8B-(Cu,Fe) 87 4>;><8B>2KE <@0<>@>2, 0=. 4  B5B@0M4@8B-(Cu,Fe) 87 B0;L:-4>;><8B>2KE ?@>68;:>2. 1  (Cu9,994Ag0,006)10,000(Cu2+1,024Fe0,850Hg0,022Zn0,011)1,907(As3,881Sb0,358)4,239(S12,822Se0,032)12,854; 2 (Cu9,980Ag0,020)10,000(Cu2+1,034Fe0,906Zn0,043)1,983(As3,487Sb0,658Bi0,003)4,148(S12,845Se0,024)12,869; 3 Cu10,000(Cu2+1,003Fe0,742Zn0,010)1,755(As2,707Sb1,580Bi0,020)4,307(S12,935Se0,003)12,938; 4 (Cu9,992Ag0,008)10,000(Cu2+0,992Fe0,766Hg0,048Zn0,009)1,815(Sb2,634As1,462Bi0,004)4,100(S13,063Se0,022)13,085. $>@<8@>20=85 0?>38?5@1078B>2KE <5B0A><0B8B>2 ?@>?8;8B>2>9 D>@<0F88 ?@>E>48;> 2 CA;>28OE 25AL<0 =87:>9 0:B82=>AB8 A5@K 8 ?>2KH5==>9 0:B82=>AB8 :8A;>@>40, > G5< A2845B5;LAB2C5B ?@8ACBAB285 2 ?>@>40E Ni-B0;L:0 8 35<0B8B0. ;5:;K5 @C4K 2>7=8:;8 =0 7025@H0NI5< MB0?5 D>@<8@>20=8O B0;L:-<03=578B>2KE <5B0A><0B8B>2, ?>A;5 >1@07>20=8O Ni-B0;L:0 8 35<0B8B0. 5@>OB=>, : :>=FC ?@>F5AA0 0:B82=>ABL :8A;>@>40 =5A:>;L:> ?>=878;0AL, 0 0:B82=>ABL A5@K ?>2KA8;0AL, GB> ?@825;> : >1@07>20=8N 1>@=8B0 8 1>30BKE Cu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antonov@AA5709.spb.edu Chlestunova A.G., Antonov A.A. Features of methasomatism in the evolution of rodingites (on example of Bazhenov deposit, Middle Urals). (SPbGU, St.-Petersburg, Russia). Contact relationships of the contrast in composition rocks (grossular-rodingites and serpentinites) have been investigated. General scheme of metasomatic contact zone is as following: 1) grossular (( vesuvianite), 2) vesuvianite (( grossular) 3) diopside + chlorite (60 8 40 vol. % accordingly, ( andradite) gradually transfomed to chlorite+diopside (70 8 30 vol. %, ( serpentine), 4) serpentine (( chlorite, garnet). Atomic amounts of the main elements for volume unit in given zones were calculated. As a result, metasomatic processes dominated on late steps of rockforming were determined. 065=>2A:>5 <5AB>@>645=85 O2;O5BAO O@:8< ?@54AB028B5;5< B>3> :;0AA0 <5AB>@>645=89, 2 D>@<8@>20=88 :>B>@KE 206=59HCN @>;L AK3@0;8 @07;8G=K5 384@>B5@<0;L=>-<5B>A><0B8G5A:85 ?@>F5AAK. 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A25@E?5@8>48G5A:>9 OG59:8>MDD8F85=B =5G5B=>AB8 '/'12345677>:5@8BK/@530, ><87 2<5I0NI59 ?>@>4K15 348<>40;L=K92"@5EA;>9=0O1,038;L=K916 34>;8<>40;L=K92(0,92030468:, "C@:<5=8O8;L=K918 388<>40;L=K93'5BK@5EA;>9=0O1,027 @>AAK?5919 41>;8<>40;L=K93'5BK@5EA;>9=0O1,60548F8=A:85, 0@?0BKI15(34A8<<5B@8G=K92(1,02II15(33A8<<5B@8G=K92(1,01&5@578=K75:AC-0BA:0O =5DBL, !B02@>?>;LA:89 :@095>G8I5=K9 (&-67)23 38A8<<5B@8G=K91"@5EA;>9=0O1,00G8I5==K9 (&-80)21 37A8<<5B@8G=K91"@5EA;>9=0O1,05!8=B5B8G5A:89 (&-!)20 38A8<<5B@8G=K92"@5EA;>9=0O0,94@8 =03@520=88 F5@578= (>1@. &-67) 8A?KBK205B <=>3>ABC?5=G0BK9 @0A?04 ?>;8:><?>=5=B=>3> B25@4>3> @0AB2>@0 ?@8 ?5@5E>45 87 :@8AB0;;8G5A:>3> A>AB>O=8O 2 @>B0F8>==>-:@8AB0;;8G5A:>5 A>AB>O=85, ?>4>1=> B><C, :0: MB> =01;N40;>AL 2 A;CG05 >7>:5@8B>2, ?G5;8=KE 2>A:>2 8 =5:>B>@KE 4@C38E ?@8@>4=KE 8 A8=B5B8G5A:8E ?0@0D8=>2KE :><?>78F89 A 0A8<<5B@8G=K< E0@0:B5@>< @0A?@545;5=8O 3><>;>3>2 ?> G8A;C n (>B5;L=8:>20, 1999). 01>B0 2K?>;=5=0 ?@8 D8=0=A>2>9 ?>445@6:5 $$ (?@>5:BK: 00 05 65161 8 02 05 06115) 8 8=8AB5@AB20 >1@07>20=8O $ (?@>5:B  9 43; ?@>5:B 992738 ?> ?@>3@0<<5  #=825@A8B5BK >AA88 ). .! ) !"   "+% "!"" . !! '5@=8FK=0 .. XE "'5@=8FK=0 .."   #:@  , 3.!8<D5@>?>;L,#:@08=0, imr @ utel. net. ua. Chernitzyna O.M. Aluminium-bearing seladonite from the apocarbonaceous metasomatites of the South Donbas (CB UkrSGRI, Simferopol,Ukraine). The peculiarities of the chemical composition the structure make it possible to classify the mineral as alumoceladonite and to suppose its formation from low-temperature hydrothermal solutions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l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iO2 43,59 49,82, Al2O3 21,86 24,84, Fe2O3 1,39 2,39, FeO 0,22 0,79, CaO 0,18 0,89, MgO 2,57 3,87, TiO2 0,38 1,04, MnO 0,01 0,07, K2O 7,48 8,74, Na2O 0,04 0,05, P2O5 0,12 0,18, Cl2O 0,30 0,56, H2O 14,66 19,24. 5;8G8=0 65;578AB>AB8 A>AB02;O5B 0,06 0,07. B;8G0NI85AO >B B5>@5B8G5A:8E AC<<K <56A;>52KE (0,8 0,82 D.5.) 8 >:B0M4@8G5A:8E (1,88 1,96D.5.) :0B8>=>2 A2845B5;LAB2CNB > B><, GB> <8=5@0; =5 O2;O5BAO AB@>3> 48>:B0M4@8G5A:>9 A;N4>9 8 5<C A2>9AB25==K 45D5:BK AB@C:BC@K. > :>;8G5AB2C :@5<=8O (Si  3,41 3,56 D.5.) 2 B5B@0M4@0E, >B:;>=ONI5<CAO >B <0:A8<0;L=>3> =0AKI5=8O, <8=5@0; <>6=> >B=5AB8 : 2KA>:>:@5<=8ABK< A;N40< [3], => >B<5G0;8AL B0:65 >1@07FK, E0@0:B5@87CNI85 >1;0ABL =54>AB>25@=>3> @0728B8O 2KA>:>- 8 =87:>:@5<=8ABKE A;N4. 0==K5 @5=B35=>AB@C:BC@=>3> 0=0;870 ?>4B25@640NB 4803=>AB8:C <8=5@0;0. ;02=K5 ;8=88 =0 @5=B35=>3@0<<0E(d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i O, Si O AlIV A <0:A8<C<0<8 470 480A< 1 8 530 540A< 1. A=>2=0O ?>;>A0 20;5=B=KE :>;510=89 Si O ?@>O2;O5BAO ?@8 1035A< 1 A CA;>6=5=85< 2 2845  ABC?5=8 2 =87:>G0AB>B=>9 (920 A< 1), 8 2 2845 ?;5G0 2 2KA>:>G0AB>B=>9 >1;0AB8 (1080 1085A< 1). 8=88 A <0:A8<C<0<8 ?@8 3600A< 1, 3615A< 1 E0@0:B5@87CNB >1;0ABL 20;5=B=KE :>;510=89 -3@C??. -A?5:B@>A:>?8O A2845B5;LAB2C5B > E>@>H5< A>25@H5=AB25 AB@C:BC@K <8=5@0;0, GB> <>65B 1KBL >4=8< 87 ?@87=0:>2 53> >1@07>20=8O 87 B5@<0;L=KE @0AB2>@>2. 5>E8<8G5A:>9 >A>15==>ABLN 0;N<>A5;04>=8B0 O2;O5BAO H8@>:89 A?5:B@ @C4>35==KE M;5<5=B>2-?@8<5A59, 2 B>< G8A;5 B8?><>@D=KE 4;O 7>;>B>-@BCB=>9 D>@<0F88 :0@;8=A:>3> B8?0.  =5< 2KO2;5=K Cu, Pb, Zn, Ni, Mo, Cr, V, Ti, Sn, Ba, Mn, Be, Nb, Zr, Ga, La, Y, Yb, Ag, Bi, Ge, Sc, Li, P, Tl, Hg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polekh@ysp.usr.pu.ru. Shulgin E.A., Polekhovskiy Yu.S. Properties and compositions of nugget gold of the Ural South-Kochkarskoy field (SPbSU, S.-Petersburg, Russia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i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nm 4;O B@5E @07=>284=>AB59 7>;>B0. (nm Au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akovleva V.A., Belogub E.V., Novoselov K.A. Native copper from Letnee massive sulfide deposit, South Urals. (1Saint-Petersburg State University, Saint-Petersburg, Russia; 2Institute of Mineralogy, UB RAS, Miass, Russia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anson S.Yu. Balance of chemical components on the contact of chemically nonequilibrium marble and granite (Saint-Petersburg State University, Saint-Petersburg, Russia). Distribution of chemical components at formation of lazurite rocks are calculated. All necessary components for lazurite forming are presented in host rocks. Lazurite rocks are formed without addition of matter. The process is based on redistribution of components on the contact of chemically nonequilibrium marble and granite. 5A<>B@O =0 4;8B5;L=CN 8AB>@8N 87CG5=8O ;07C@8B>2KE <5AB>@>645=89, 2>?@>A >1 8AB>G=8:5 25I5AB20 ?@8 ?@>F5AA0E ;07C@8B>>1@07>20=8O 4> A8E ?>@ >AB05BAO =5@5H5==K<. @8 MB><, <>18;870F8O 87 2<5I0NI59 B>;I8 8 ?5@5@0A?@545;5=85 <564C :>=B0:B8@CNI8<8 ?>@>40<8 B0:8E M;5<5=B>2 :0: Mg, Si, Al, Ca, Fe, =5 2K7K205B A><=5=8O C 1>;LH8=AB20 8AA;54>20B5;59.  >B=>H5=88 8AB>G=8:0 I5;>G59 8 A5@K ACI5AB2CNB @07;8G=K5 B>G:8 7@5=8O. > <=5=8N >4=8E 02B>@>2, >=8 ?>;=>ABLN ;81> G0AB8G=> ?@82=>AOBAO 872=5 8 8<5NB BC 65 35=5B8G5A:CN ?@8@>4C, GB> 8 8AB>G=8: 3@0=8B878@CNI8E D;N84>2 [1,2]. > <=5=8N 4@C38E 8AA;54>20B5;59 [3,4], 8AB>G=8:>< I5;>G=KE M;5<5=B>2 8 A5@K O2;O;8AL 38?>B5B8G5A:85 M20?>@8BK, =0 ACI5AB2>20=85 :>B>@KE C:07K20NB =0E>4:8 2 :0@1>=0B=KE B>;I0E 0=384@8B0. !CI5AB2C5B B0:65 <=5=85, GB> 2A5 :><?>=5=BK ;07C@8B>2KE <5B0A><0B8B>2 708<AB2>20=K 87 2<5I0NI8E ?>@>4 157 ?@82=>A0 25I5AB20 872=5 [5]. ;O >F5=:8 10;0=A0 ?@82=>A0-2K=>A0 25I5AB20 ?@8 <5B0A><0B8G5A:>< ?@5>1@07>20=88 3@0=8B>84>2 1K; 45B0;L=> 87CG5= >1@075F, 2 :>B>@>< =0 @0AAB>O=88 5A< ?@54AB02;5=K >A=>2=K5 7>=K =081>;55 @0A?@>AB@0=5==KE <5B0A><0B8B>2 A ;07C@8B>< >B =587<5=5==KE 3@0=8B>2 4> D>@AB5@8BA>45@60I8E <@0<>@>2. !B@>5=85 <5B0A><0B8G5A:>9 :>;>=:8 ;07C@8B>2KE <5B0A><0B8B>2 >=0IIIIIIIVV0@035=578AKf+QrtzKf+DiDi+LazPhDol+Fo@8<5G0=85. Qrtz  :20@F, Kf  :0;852K9 ?>;52>9 H?0B, Di  48>?A84, Laz  ;07C@8B, Ph  D;>3>?8B, Dol  4>;><8B, Fo  D>@AB5@8B. 57C;LB0BK 20;>2>3> E8<8G5A:>3> 0=0;870 :064>9 7>=K ?@82545=K 2 B01;8F5. "01;8F0 %8<8G5A:85 A>AB02K 3@0=8B0 (I), D>@AB5@8B>2>3> <@0<>@0 (V) 8 A@54=89 E8<8G5A:89 A>AB02 <5B0A><0B8G5A:8E ?>@>4 (II IV) ><?>=5=BIII IVVSiO271,2545,6314,55TiO20,020,050,02Al2O315,1512,081,95FeO0,020,070,07MnO0,000,030,01MgO0,8912,5017,16CaO1,5017,1737,42Na2O4,773,910,12K2O6,253,451,32SO30,002,8512,35CO20,102,2615,20CC<<0100,00100,00100,00! CG5B>< ?;>B=>AB8 8 <>I=>AB8 ?>@>4, A;030NI8E 7>=K (II IV) <5B0A><0B8G5A:>9 :>;>=:8, @0AAG8B0= 8E A@54=89 E8<8G5A:89 A>AB02. ;O A>?>AB02;5=8O 2 B>9 65 B01;8F5 ?@82545=K E8<8G5A:85 A>AB02K 3@0=8B>2 8 D>@AB5@8BA>45@60I8E <@0<>@>2. >;CG5==K5 40==K5 ?>:07K20NB, GB> 2A5 :><?>=5=BK G5B:> @0745;ONBAO =0 425 3@C??K: 0) :><?>=5=BK, A>45@60=85 :>B>@KE 70:>=><5@=> C<5=LH05BAO >B 3@0=8B>2 (I) : <@0<>@0< (V), : =8< >B=>AOBAO Si, Al, Na 8 K; 1) :><?>=5=BK, :>=F5=B@0F88 :>B>@KE B0:65 70:>=><5@=> C<5=LH0NBAO 2 >1@0B=>< =0?@02;5=88, >B <@0<>@>2 : 3@0=8B0< (Mg, Ca). !;54C5B >A>1> ?>4G5@:=CBL, GB> A>45@60=85 :064>3> 87 :><?>=5=B>2 2 <5B0A><0B8G5A:8E ?>@>40E =5 ?@52KH05B 8E :>=F5=B@0F89 2 3@0=8B5 8;8 <@0<>@5, GB> C:07K205B =0 ?5@5@0A?@545;5=85 :><?>=5=B>2 <564C MB8<8 E8<8G5A:8 =5@02=>25A=K<8 3>@=K<8 ?>@>40<8 2 ?@>F5AA5 D>@<8@>20=8O 18<5B0A><0B8G5A:>9 :>;>=:8. B0:, :@5<=89, 0;N<8=89, =0B@89 8 :0;89 A>45@60BAO 2 8AE>4=KE ?>@>40E (3@0=8B0E), ?@8G5< :>;8G5AB20 8E ?@52KH0NB =5>1E>48<K5 4;O D>@<8@>20=8O 0?>A8;8:0B=KE <5B0A><0B8B>2 8 =5:>B>@0O G0ABL 2K=>A8BAO, O2;OOAL 8AB>G=8:>< 25I5AB20 4;O D>@<8@>20=8O 0?>:0@1>=0B=KE 8 0?>A:0@=>2KE <5B0A><0B8G5A:8E >1@07>20=89. 0==K5, ?>;CG5==K5 2 @57C;LB0B5 87CG5=8O 87>B>?=>3> A>AB020 A5@K, C:07K20NB =0 ?5@28G=>->A04>G=>5 55 ?@>8AE>645=85. 1>30I5=85 A5@>9 ?@>8AE>48;> =0 AB0488 M?835=5B8G5A:8E ?@5>1@07>20=89 >A04>G=KE ?>@>4, 4> <><5=B0 8E <5B0<>@D8G5A:8E 8 <5B0A><0B8G5A:8E 87<5=5=89 [6] !;54>20B5;L=>, 8AB>G=8:>< A5@K B0:65 O2;ONBAO 2<5I0NI85 ?>@>4K. > @57C;LB0B0< @0AG5B0 10;0=A0 25I5AB20 ?@8 >1@07>20=88 ;07C@8B>2KE ?>@>4 <>6=> A45;0BL 2K2>4 > B><, GB> 2A5 >A=>2=K5 :><?>=5=BK, B@51CNI85AO 4;O >1@07>20=8O ;07C@8B0, A>45@60BAO 2> 2<5I0NI8E ?>@>40E, ?@8G5< :>;8G5AB20 8E ?@52KH0NB =5>1E>48<K5 4;O D>@<8@>20=8O 0?>A8;8:0B=KE <5B0A><0B8B>2. "0:8< >1@07><, =0 ?>AB<03<0B8G5A:>< MB0?5 >1@07>20=8O ;07C@8B>2KE <5AB>@>645=89 =5 >B<5G05BAO ?@82=>A0 :0:8E-;81> :><?>=5=B>2 872=5, 8 ?@>F5AAK ;07C@8B>2>9 <8=5@0;870F88 >A=>20=K =0 ?5@5@0A?@545;5=88 :><?>=5=B>2 =0 :>=B0:B5 E8<8G5A:8 =5@02=>25A=KE A@54. 8B5@0BC@0: 1. >@68=A:89 .!. 8<5B0A><0B8G5A:85 D;>3>?8B>2K5 8 ;07C@8B>2K5 <5AB>@>645=8O 0@E5O @8109:0;LO. .: 874.   !!! , 1947. 164 A. 2. 20=>2 .. 07C@8BK !!! . >2>A818@A:,  0C:0 , 1985. 3. Hogarth D.D. Lapis Lazuli from Baffin island  a precambrian meta  evaporite. //Lithos. 1978. V.11. N 1. 4. Kulke H. Die Lapislazuli  Lagerstatte SareSang (Badakhshan) Geologie, Entstehung, Kulturgeschichte und Bergbau. //Afganistan Journal, 1976. Jg 3. H. 2. S. 43 56. 5. >@>1L52 ..  35=578A5 ;07C@8B0. //8=5@0;>38O 8 35=578A F25B=KE :0<=59 >AB>G=>9 !818@8. >2>A818@A:: 0C:0. !81. >B4-=85, 1983. C. 62 68. 6. 8=>3@04>2 . ., 8F0@52 . . 7>B>?=K9 A>AB02 A5@K 8 =5:>B>@K5 >A>15==>AB8 >1@07>20=8O ;07C@8B0. //5>E8<8O 8 <8=5@0;>38O A5@K. .: 0C:0, 1972. C. 267-282. $ &/ ",+%   "+%  " PR1 # ! )" /I5=:> ./. XE "/I5=:> ./."   #:@  , 3. !8<D5@>?>;L, #:@08=0, imr @ utel.net.ua Yashchenko N. Formation of rare-metal cordierite granites PR1 of the Ukranian shield (CB Ukr SGPI, Simferopol, Ukraine). The formation of rare-metal cordierite granites PR1 has been distinguished. Cordierite granites form a series of veined bodies differentiated fracture intrusions.Depending on an erosional shear different mineral types of cordierite granites are distinguished.On the apical level spodumen, petalite,cordierite-bearing pegmatoids are distinguished. All granite varieties contain high-ferruginous cordierite ferricordierite, characterized by high concentrations of Li, Be,Cs. Ferricordierite is usually substituted by ferri-halloysite.Cordierite granites are derivatives of high aluminiferous leucogrenitic melts. $>@<0F8O @54:><5B0;L=KE :>@485@8B>2KE ?53<0B>84=KE 3@0=8B>2 PR1 1K;0 2K45;5=0 02B>@>< 2 1985 3. ?@8 ?@>2545=88   ?> >F5=:5 @54:><5B0;L=KE ?53<0B8B>2 @807>2A:>3> 1;>:0. >@485@8B>2K5 3@0=8BK 8<5NB H8@>:>5 @538>=0;L=>5 @0A?@>AB@0=5=85 2 ?@545;0E #:@08=A:>3> I8B0 (2>;G0=A:89 :><?;5:A 0?04=>3> 8 >AB>G=>3> @807>2LO, ?@88=3C;LA:89 :><?;5:A =3C;>-=3C;5F:>3> @09>=0 8@>2>3@04A:>3> 1;>:0 [3], ?>;O  ;8B852KE ?53<0B8B>2 (?>;O=>-"0H;K:A:>3> @09>=0 2 70?04=>9 G0AB8 8@>2>3@04A:>3> 1;>:0 [1]). >@485@8B>2K5 ?53<0B>84=K5 3@0=8BK  ?@>872>4=K5 2KA>:>3;8=>75<8ABKE ;59:>3@0=8B=KE @0A?;02>2, D>@<8@>202H8EAO 2 CA;>28OE ?@>B>?@>B5@>7>9A:>9 0:B82870F88 0@E59A:>9 ?;0BD>@<K (C@>25=L 2,3 2,2 <;@4. ;5B[3]). ! =8<8 A2O70=K ?@><KH;5==K5 :>=F5=B@0F8 @54:8E <5B0;;>2 (8725AB=K5  ;8B852K5 ?53<0B8BK ) >@485@8B>2K5 3@0=8BK >1@07CNB A5@88 68;L=KE B5; ( ?53<0B8B>2K5 ?>;O ), ?@8C@>G5==K5 : ?@>BO65==K< B5:B>=8G5A:8< 7>=K< 2 3=59A>2KE B>;I0E AR3 (70?04=>-?@807>2A:0O, F5=B@0;L=>-?@807>2A:0O, 8=3C;>-8=3C;5F:0O A5@88). 8;L=>5 ?>;5  MB> 548=0O B@5I8==0O 8=B@C78O, 2:;NG0NI0O @07=>9 <>I=>AB8 68;K, 409:8, <83<0B8BK. K45;ONBAO <5;:>75@=8ABK5 (0?;8B>84=K5), A@54=575@=8ABK5, 3@C1>75@=8ABK5 ?53<0B>84=K5 @07=>AB8, 2 M=4>:>=B0:B5 68; G0AB> C;02;8205BAO 7>=0 <5;:>3> 75@=0.  7028A8<>AB8 >B C@>2=O M@>78>==>3> A@570 2K45;ONBAO @07;8G=K5 <8=5@0;L=K5 @07=>284=>AB8 3@0=8B>2, => 2A5 >=8 >B=>AOBAO : B8?C 2KA>:>3;8=>75<8ABKE ;59:>3@0=8B>2 (A>45@60B =>@<0B82=K9 :>@C=4). 0 3;C1>:8E C@>2=OE :>@485@8B>2K5 3@0=8BK >1>30I5=K <8:@>:;8=>< (<0A.%: SiO2 72,2, TiO2 0,01, AL2O3 14,4, Fe2O3 0,5, FeO 1,3, MnO 0,02, MgO 0,5, CaO 0,6, Na2O 2,2, K2O 6,4, P2O5 0,1, SO3 0,4, H2O+ 0,7, F 0,03, Li2O 0,012, Rb2O 0,022, Cs2O 0,002, Be 0,0024 ), 1;865 : 0?8:0;L=><C C@>2=N ?@5>1;040NB >;83>:;07-0;L18B>2K5 @07=>AB8 (<0A.%): SiO2 72,6, TiO2 0,01, Al2O3 16,9, Fe2O3 0,7, FeO 0,1, MnO 0,02, MgO 0,1, CaO 0,4, Na2O 5,5, K2O 2,9, P2O5 0,17, SO3 0,05, F 0,01, Li2O 0,04, Rb2O 0,02, Cs2O 0,002, Be 0,01. 0 2A5E C@>2=OE 2AB@5G0NBAO E0@0:B5@=K5 3@C1>75@=8ABK5 :>@485@8B-:20@F52K5 ?53<0B>84K, CG0AB:0<8 ?5@5E>4OI85 2 <8:@>?53<0B8B>2K5 A@0AB0=8O :>@485@8B0 8 :20@F0 (<0A.%): SiO2 84,6, TiO2 <0,01, Al2O3 8,2, Fe2O3 0,15, FeO 3,4, MnO 0,02, MgO 0,8, CaO 0,2, Na2O 0,6, K2O 0,1, P2O5 0,02, F 0,01, Li2O 0,08, Rb2O 0,004, Cs2O 0,002, Be 0,08. > 2A5E @07=>284=>ABOE :>@485@8B>2KE 3@0=8B>2 (2 B>< G8A;5, 2 A?>4C<5=>2KE 8 ?5B0;8B>2KE ?53<0B8B0E, <83<0B8B0E) :>@485@8B >B;8G05BAO 2KA>:>9 65;578AB>ABLN (0,6 0,8), ?>72>;ONI59 >B=5AB8 53> : D5@@>:>@485@8BC, A5:0=8=08BC [2] (<0A.%): SiO2 46,42, TiO2 0,01, Al2O3 30,13, Fe2O3 1,42, FeO 10,75, MgO 2,42, CaO 0,12, Na2O 1,63, K2O 0,28, CO2 0,55, H2O 4,4, F <0,01, Li2O 0,64, Rb2O 0,008, Cs2O 0,06, Be 0,1. $5@@>:>@485@8B >1KG=> 70<5I5= 3>;C1>20B>-A5@K< <8=5@0;><, 1;87:8< : D5@@830;;C078BC* (<0A.%): SiO2 38,13, TiO2 0,01, Al2O3 35,60, FeO 4,18, MnO 0,02, MgO 2,59, CaO 0,30, Na2O 0,34, K2O 0,44, H2O+ 17,11, F 0,04, Li2O 0,59, Rb2O 0,001, Cs2O 0,002, Be 0,025.  :>@485@8B-<8:@>:;8=>2KE 3@0=8B0E ?@5>1;0405B B>=:>@5H5BG0BK9 <8:@>:;8= A>AB020 Ab13Or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a, Al, P, Rb, Cs, Be (<0A.%): SiO2 70,7, TiO2 0,04, Al2O3 16,1, Fe2O3 0,1, FeO 1,4, MnO 0,2, Mg0 0,15, CaO 1,1, Na2O 5,6, K2O 3,1, P2O5 0,7, CO2 0,2, H2O+ 0,13, Li2O 0,5 1,1, Rb2O 0,06 0,1, Cs2O 0,01). @8 MB>< D5@@>:>@485@8B A>45@68B 2KA>:85 :>=F5=B@0F88 Li (0,7 1,8% Li2O), Be (0,5%), Cs (0,06% Cs20). >@485@8B 87 <83<0B8B>2KE ?@>68;:>2 ( :>@485@8B878@>20==KE 3=59A>2 ) B0:65 E0@0:B5@87C5BAO 2KA>:8<8 A>45@60=8O<8 ;8B8O (0,5 0,6% Li2O), Be (0,025 0,10%). "0:8< >1@07><, 2A5< @07=>284=>ABO< :>@485@8B>2KE 3@0=8B>2 (=57028A8<> >B C@>2=O M@>78>==>3> A@570 B@5I8==>3> 8=B@C7820) ?@8ACI8 >1I85 E0@0:B5@=K5 G5@BK <8=5@0;L=>3> 8 E8<8G5A:>3> A>AB020  ?@8ACBAB285 2 :0G5AB25 B8?><>@D=>3> <8=5@0;0 D5@@>:>@485@8B0 (:>=F5=B@0B>@0 Li, Be), 2KA>:0O 3;8=>75<8AB>ABL 3@0=8B>2, G5B:> 2K@065==0O 35>E8<8G5A:0O A?5F80;870F8O =0 Li, Be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ineralogy of the Upper Mantle Xenoliths in Alkaline Basalts of Tariat and Dariganga plateaus, Mongolia Babushkina M.S. XE "Babushkina M.S." , Nikitina L.P. XE "Nikitina L.P." , Ovchinnikov N.O. XE "Ovchinnikov N.O." , Saltikova A.K. XE "Saltikova A.K."  Precambrian Geology and Geochronology Institute RAS, St.Petersburg, Russia, saltann@mail.ru The mantle xenoliths are carried out from various upper mantle zones to the surface by kimberlites, lamproites and alkaline basalts. They permit us to study the composition, the structure and thermal state of the mantle. Upper mantle xenoliths in alkaline basalts are found in many Early Proterozoic and Phanerozoic folded belts. In our work the spinel- and garnet-spinel peridotites and pyroxenites from Cenozoic (NQ) alkaline basalts from Central (Tariat plateau) and South-East (Dariganga plateau) Mongolia are studied. Tariat and Dariganga plateaus are placed on the Central Asian folded belt. The alkaline basalts locations are associated with the Baykal rift system. Spinel peridotites xenoliths from Dariganga are found in several eruption centers. Tariat xenoliths are sampled from basalts of Shavarin-Zaram volcano. Main minerals are Cr-reach diopside, orthopyroxene En8590 and olivine Fo90. Their compositions for Dariganga and Tariat xenoliths are very similar. Accessory spinel composition essentially varies in the FeAl2O4 MgAl2O4FeCr2O4MgCr2O4 system. At high total FeO in the spinel Fe3+-bearing minal presence is allowable. Both garnet from garnet-spinel lherzolites and garnet xenocrystalls are pyrope-almandine suite: pyrope is order of 70 mol.%, almandine 15 mol.%, grossular 10 mol.%, andradite and spessartine+uvarovite 2 mol.%. The valence state of iron in the pyroxenes, olivine, spinel and garnet was determined by MQssbauer spectroscopy. High disorder degree of Fe2+ in the structure is revealed. Secondary mineralization is found in the altered areas in the xenoliths. The aphanitic texture is specific to such areas. There are euhedral secondary olivine, clinopyroxene and spinel microkrystalls in aphanitic matrix. The phlogopite, magnetite, pyrrotite and silicate phases with high content of (Na2O+K2O) are also observed. Such aggregates are distributed in interstitial space and as inclusions in primary minerals. The accessory spinel is most subject to the alteration. Chemical zoning in few altered spinel grains is found. In the grains rimes increasing of Cr2O3 and MgO concentrations and decreasing of Al2O3 and total FeO take place. Some spinel grains have two different altered rims. One is composed of ferriferous spinel and NiFe sulphid. Other is aggregate of high Cr2O3 spinel and uncertain silicate phase. Partial melting and fluid metasomatism cause such kinds of xenoliths alterations we suggest. These processes mechanisms are discussed. Pressure and temperature for Dariganga and Tariat xenolith formation are estimated using the data of unaltered minerals composition. The P and T for spinel-garnet rocks are calculated by GarOpx geothermobarometer [2]. Temperature of spinel peridotite (garnet free) was obtained by CpxOpx and OlCpx thermometers [3]. Pressure for ones was determined using Mongolia region geotherm [1] under the assumption of PT relationship is linear. The spinel peridotites formed at 10001300C and 2540 kbar, and garnet-spinel peridotites at 13001550 C and 3550 kbar. The Fe2+ high disordered distribution between nonequivalent sites in the main minerals structure suggests the cation distribution was partially quenched during speed elevation by basalt magma. It is felt that mineral equilibria of mantle rocks was not essentially altered during elevation to the surface. References: 1.Glebovitski V.A., Nikitina L.P. XE "Nikitina L.P." , Khiltova V.Ya. The thermal state of the mantle underlying Precambrian and Phanerozoic structures: evidence from garnet-orthopyroxene thermobarometry of garnet peridotite xenoliths in kimberlite andalkali basalts // Izvestia, Phisics of the solid Earth, 2001. V.37, No3. P.193214. 2.Nikitina, L.P. Garnet-orthopyroxene & Garnet-clinopyroxene thermobarometers for the mantle xenoliths // Thesaurus Contributions to advanced studies in geology, vol. 3: Capricious Earth: Models modelling of geologic processes and objects, V.A. Glebovitski & V.I. Dech, Eds, St. Petersburg Athens, 2000. P.4453. 3.Nikitina, L.P., Ivanov, M.V. Geological thermobarometry based on the mineral-forming reactions with participation phases // St. Petersburg: Nedra, 1992. STUDYING ORGANIC SUBSTANCE AS A STRUCTURAL ELEMENT OF URIC STONES. Borbat V.F. XE "Borbat V.F." , Golovanova O.A. XE "Golovanova O.A." , Pitanova P.A. XE "Pitanova P.A."  Omsk State University, Omsk, Russia,  HYPERLINK "mailto:pakach@orgchem.univer.omsk.su" pakach@orgchem.univer.omsk.su Among pathogenic minerals formed in live organisms two groups are distinguished physiologically essential for an organism and pathogenic. Researches point out a lot of common and difference features between the two groups, for instance significant swing of proportion between mineral and organic components in pathogenic biominerals. It is known that the content of organic substance (OS) in biominerals varies greatly and the basis is protein. As for the structure, OS represents both fibril and amorphous substance which is not reflected on roentgenogramms [1]. According to Korago [1] the content of OS in uric stones may be different, protein being 5873% of the organic mass. Among proteins in uric acids there are albumins, globulins which can be found in blood as well. A particular place in organo-mineral aggregates (OMA) research is taken by defining their organic component. Unfortunately some researches ignore this essential part of the aggregate probably because the substance is hard to find due to its minor quantity or, which is more likely, it was not paid enough attention to as it was mineral substances, especially those exotic to the organism that were of interest to the scientists. But in spite of this a lot of authors underline a particular role of organic substance in the process of formation and growth of the stones, its influence on their shape and structure. The following mechanisms of OMA genesis are distinguished: biomineralization and free extraction from the solution of mineral and organic substance of a stone. A specific characteristic of biomineralization objects the participation in building both mineral (inorganic) and organic substance makes it necessary to use various research methods while studying it. We study building peculiarities of such type of pathogenic formations as uric stones. The basis of the organic part of uric stones is built by proteins and glycoproteins thus the study was aimed at investigating these particular substances. Chemical and IR-spectroscopy analysis methods were used. The research conducted confirmed the presence of protein substances in the concrements. The quality analysis results show not only the presence of proteins but also the peculiarities of dissemination. It is found out that protein compositions may be of the following types of localization: core, interlayer (concentric ray layers), diffuse (as spots into crystal minerals). There is no doubt nowadays that a whole series of organic substances have some kind of connection with mineral substance, but probably it is not a definite organic substance that causes formation of mineral but a certain complex of organic substances in urine leads to the growth of concrements. It can be supposed that the role of organic substance is the greatest at the very first stage of stone formation. Later on the connection between organic and mineral components becomes more occasional which is shown in the research results pointing to great variations in organic component composition for the stones of the same chemical structure [1,3]. Thus special attention should be drawn not only to defining the composition of organic components but to studying its composition at the very centres of concrements with mineral substance study going alongside. References: 1.Korago A. Introduction to Biomineralogy. 1992. StP. 280p. 2.Tiktinsky O., Alexandrov V. Uric Stone Disease. StP. Medicine. 2000. 384 p. 3.Yushkin N., Katkova V., Tkachev Yu. Mechnisms, Factors and Evolution of Mineral Formation. Syktyvkar. 2000. 34p. MINERALS of the MIDWESTERN UNITED STATES Huizing T.E. XE "Huizing T.E."  Curator of Mineralogy, Cincinnati Museum Center 1301 Western Avenue, Cincinnati, Ohio 45203, USA, tehuizing@fuse.net The Midwestern states of Ohio, Indiana, Kentucky, Tennessee, Illinois and Missouri share a simple suite of minerals that are found wherever dolomitized limestones outcrop or are exposed by surface or underground mining. Of interest to collectors are approximately two-dozen minerals that can occur as well crystallized carbonates, sulfides, sulfates, oxides, halides and ubiquitous quartz. The following table lists these minerals and the elements that form them. Metals present in the original sediments were mobilized by relatively low-temperature (100200 degrees centigrade) fluids flowing up-slope from the ancient basins and saline seas of the region and were concentrated. As these fluids reached an arch or dome adjacent to the basins, minerals crystallized in open cavities within the host rock when the pressure and temperature were reduced. Other factors, such as the pH of the fluid, the presence of pyrobitumen, and the presence of fresh formation water influenced the timing and degree of crystallization. Minerals found in the limestones of the midwestern USA are often well crystallized, beautiful, and abundant and occur in a wide range of habit, color, and association with other minerals. Table ELEMENTATOMIC NUMBERCARBONATESULFIDESULFATEOXIDEHALIDEsodium11halitemagnesium12dolomitecalcium20calcite aragonitegypsumfluoriteiron26pyrite marcasitehematite goethitecobalt27siegenitenickel28milleritecopper29malachitechalcopyritezinc30smithsonite sphaleritestrontium38strontianite benstonitecelestinebarium56witheritebaritelead82leadhillitegalenaPGM AND OTHER ACCESSORY MINERALS OF HYDROGENOUS FERROMNGANESE OCEANIC CRUSTS PACIFIC OCEAN CASE STUDY 1Torokhov M.P., 2Anikeeva L.I., 1Alexandrov P.A., 2Prasolov E.M. 1VNIIOkeangeologia, St.Petersburg, Russia, TOROKHOV@spb.cityline.ru 21 Centre of Isotopic Studies VSEGEI, St.Petersburg, Russia The study of accessory minerals in ferromanganese crusts was done to determine self mineral phases of those elements that are of practical interest !> , Ni, Cu, REE, PGE, Te, W. Hydrogenous crusts were taken from two well-known deposits of Magellan Seamount and of Wake-Nekker (the Pacific Ocean). Extraction of heavy minerals was based on original approach in hydro environment that permits to exclude technogenic pollution of a treated sample and to separate micron-size minerals of heavy fraction. Concentration coefficient composed ca. 1:10000000, that allowed to extract phases of those minerals that hardly could be find in original crusts. Discovered mineral associations (Table 1) are represented by diagenetic paragenesis: sulfides, chlorides, sulfates, phosphates, oxides, and native metals and alloys. Mineral phases were analyzed by electronic microscope ABT-55 (Japan) with link-10000 under accelerating voltage 25 kV in the Institute of Precambrian Research (analytics M.D.Tolmachev, M.R.Pavlov). The time of impulse accumulations ranged from 30 up to 300 sec. Elements with contents exceeding 2( were taken in account. The wide of electronic beam is estimated to be 3 microns. Table 1 Accessory minerals of hydrogenous crusts Sulfides, telluridesChloridesSulfatesPhosphatesOxidesNative metals and alloysSphaleriteAtakamiteBariteApatiteWolframiteNiChalcopyriteMonaziteTelluriteBronzeGaleniteZinciteBrassMolybdeniteGahnite(Fe,Cr,Ni)Pyrite(Ce,Fe)O2CuAnilite(Cu,Zn)2O(Fe,Ni)Marmatite(Ce,La,Fe)O2(Fe,Cr)Covellite(W,Fe)O2(Fe,W,V,Cr)Geerite Titanomagnetite(Ce,La,Fe)W-PyriteTaColoradoiteAgZnIt is necessary to stress that mentioned minerals are of autigenic nature and we do not take in account those minerals that were supplied to the crusts from other sources: basalts, sediments, cosmos. PGE-bearing mineral phases were determined in form of solid alloys Fe,Pt,Pd,Rh, as well as sulfides, stannates, and silicides (Table 2). Grain sizes are varying from 1 to 10 ppm. Pt is dominant in most part of PGM compositions that corresponds to a bulk chemical composition of PGEs in the studied crusts. Forms of PGM grains testify to their formation in-situ (Fig.2,3,4). This idea is also supported by the presence of Fe and Mn in some PGM grains composition. Table 2 PGE-bearing minerals of hydrogenous crusts MineralCompositionFigureREFERENCESunnamed(Pd3.83Pt0.11Ru0.06)4.00(Se0.87S0.07As0.06)1.002this workunnamed(Ag0.40Cu0.22Pb0.12Pd0.06Ni0.03)S1.003this workferroplatinumPt2.25Fe1.00 4this workferroplatinum(Pt2.21Pd0.005Rh0.05)Fe1.00 this workrustenburgite(Pt2.13Pd0.76Ni0.09Cu0.09)3.07(Sn0.87Sb0.06)0.93Iunnamed(Cu3.51Pt0.63Fe0.50.Sn0.22Ni0.09.Mn0.04Ag0.04)5.03Si0.96Iunnamed(Cu3.14Pt0.68Fe0.18Mn0.04)4.04Si0.96Iunnamed(Cu3.35Pt0.61Fe0.05Mn0.05)4.06Si0.95Ibronze(Cu0.87Sn0.05Fe0.03Si0.03Pt0.01Ag0.01)1.00I  REE-bearing phases are represented by oxides, monazite, native metals, REE-bearing goethite. Predominance of Ce corresponds to that of bulk chemical REE composition in hydrogenous crusts. Mineral phases of Te are represented by tellurite, ,Te-bearing geerite, colorodaite. Compositions of W are represented by wolframite, (W,Fe)O2, W-bearing pyrite, solid alloys (Fe,W,V,Cr). It is necessary to note, that separated volume of accessory minerals (micrograms) supports the idea that main part of ore elements is presented in form of cation-anionic compositions, or at least in form of submicron grains ore element clusters inaccessible for microprobe determinations (detection limit 2-3 microns). It is normally proved by separate analyses of homogenous Fe-Mn matter were Co, Ni, Cu usually have measurable meanings. Widely manifested alloys of Fe,Cr,Ni in all types of studied crusts are of definitely autigenic character that is supported by numerous discoveries of pseudomorphs over microfossils, such as Foraminiferas etc. replaced by similar alloys (Fig.1). Morphology of separate mineral grains as cancer-like, ovoid forms and veinlets indicate to the possibility of mineral formation from gels. In course of each-layer treatment where crust ages could differ in tens of Ma (Melnikov et.al.,1994), we did not find yet any serious quantitative difference in accessorys amount that testifies to relatively rapid mineral formation. However, mineral compositions of accessories could significantly variable following to variations of bulk chemical composition of a layer. Separated mineral phases of metals are not interesting in technological aspect due to their small amount. However, the genetic interpretation of their formation could be of significant interest in understanding of intercrustal environments and essence of chemical reactions. rocesses on mineral formation. The formation of hydrogenous crusts takes place in oxidizing, low alkaline hydrochemical conditions that determine a stability of oxide metal forms. Thermodynamical calculations, particularly, show that under a clarke contents of Fe, Mn and Co in oceanic water, the most stable mineral forms will be vernadite (Fe-vernadite) and other ferrous minerals of composition FeO(OH), where a part of iron is replaced (up to 2 wt.%) isomorphically by cobalt. 1. The specifity of mentioned accessory minerals is that they could be formed, as a rule, in rather reductant environment, that in together with mentioned facts proving their autigenic formation, point to their genesis at a stage of crusts diagenesis. Ferromaganese hydrogenous crusts are of valuable sorption potential. In fact, the crusts are a kind of cold chemical reactors. Concentration coefficients of separate metal cations and anions from seawater could exceed ten ths. of magnitude what result in significant enrichment of their content in porous waters due to desorption and formation of coagulative structures of most ore minerals. 2. Their next feature is the confinement to bathymetric intervals with intensive decay of biogenic organic matter accompanied by formation of its incomplete oxidation (ammonia, chelates, cetones etc.) that could be also concentrated in porous waters of the crusts. These two features are most probable reasons of the mentioned variety of accessory minerals in the studied crusts. Typical feature of transitional metals of d-row (Fe, Cr, Ni, Mo, Mn, V, W, Rh, Ru) is their ability to form complexes with products of incomplete organic decay as CO, arsines, isocyanides, NO and other molecules that have delocalised (-orbitals ((-acids). The typical features of these ligands is their ability to stabilize low-valency state of metals oxidation, i.e. to promote the formation of more reductant metal forms up to native metals. Special research was undertaken to determine the gaseous content in separate crust (lower layer) that shows a possibility of reductant environment within crust layer (Table 3). "able 3 Chemical composition of gases from hydrogenous crust-lower layer (Wake-Nekker). Composition,%2, c.u.N2/COQuantity,Am3/g E 10-3H2N2+COCO2CH4C2H6C3-C5(2N2+COCO2CH4C2H6,10-2C3-C5,10-20.4664311.71.21.10.060.07150.0699.74.70.251816Notes: c.u.-conditional unites References: 1. Rudashevsky N.S., e.a. Platinum minerals in ferromanganese oceanic crusts // Doklady Akademii Nauk, 2001. v.378. !2. .1 4 (in Russian). 2. Melnikov M.Ye.,Pulyaeva I.A. Ferromanganese crusts of the Marcus-Wake Rise and Magellan Mountains, Pacific Ocean: structure, composition, age // Tikhookeanskaya Geologia, 1994. !4. .13 27 (in Russian). CHOLESTEROL AS AN ORGANIC COMPONENT OF BIOMINERALS AT CHOLELITHIASIS 1Yudina L.N., 2Golovanova O.A., 2Borbat V.F., 2Nizovsky A.I. 1Omsk State Medical Academy, Omsk, Russia; 2Omsk State University Omsk, Russia, pakach@orgchem.univer.omsk.su Studying biominerals and biogenic mineral formation in live organisms a very important trend in biomineralogical research. It is urgent while solving the problems connected the pathological biomineral new formations growth leading to various diseases, including cholelithiasis. Normal, functionally full biominerals are formed as usual in physico-chemical systems with stable characteristics only (ion strength, mineral-forming ion activity, pH and buffer capacity) while pathological biominerals are formed as a result of a break of defending physico-chemical systems of the organism. According to modern views, the basic gall-stone forming process is a result of destabilization of physico-chemical condition of gall, gall-stones formation goes alongside with precipitation of such gall components as cholesterol, bilirubin, inorganic and organic calcium salts, etc. [1]/ the variety of these components is shown in chemical composition of gall-stones, which are divided into cholesterol, pigment and mixed, the first being most common. The majority of gall-stones are polymineral, including up to 20 macro- and microelements (calcium, magnesium, sodium, aluminum, iron, copper, manganese and others), which proportions are different for different regions. Cholesterol lithogenesis at the first stage of development is breaking of colloidal gall stability, and depends on cholesterol excess or lack of gall acids and lecitine [2]. The gall lithogene index (LI) research method includes defining cholesterol, gall acids sum, phospholipids and comparing the data obtained while building schemes. The possibility of using the ratio of cholesterol to lecitine as an informative LI is studied [3]. Revealing regulatory processes which lead to or prevent formation of gall-stones, establishing correlation of various factors which determine lithogenesis with peculiarities of concrements composition and structure is of certain interest while solving the problems put in front of mineralogists, chemists and doctors. We studied a series of 93 gall-stones taken from patients of surgery departments in Omsk hospitals. The roentgen-phase analysis of the samples which have crystal structure showed the presence of anhydrous and monohydrous forms of cholesterol. In part of the concrements calcite and more seldom faterite were identified. The stones with amorphous structure were analyzed by IR-spectroscopy and IR-Furie spectroscopy. While studying native samples spectra corresponding to almost pure cholesterol were obtained (> 95%). After the extraction with ethanol, chloroform or their mixture calcite, aragonite, faterite were found. At IR-spectroscopy of 7 gall-stones bilirubin, calcite, sodium salt of cholic acid, vermiculite were observed. Predominance of cholesterol component of gall-stones shows the peculiarities of amino-acid composition of gall-stones. It goes alongside with the participation of glicine, connected with cholic acid in crystal formation according to the scheme [4]: Glicine ( acetyl CoA ( isoprenoids ( cholesterol Molecular nature of gall-stones organic and mineral components collaboration is not known yet. It is established that organic matrix rules the qualities of biominerals in general through the surface energy of crystallites [5]. In pathological formation that process is likely to be broken which leads to non-controlled growth of organomineral formations, at cholelithiasis as well. Defining the composition and structure of gall-stones and also studying the dissemination of organic and biomineral components in them will enable to evaluate parameters of stone-forming environment and its evolution in pathogenic mineral formation process. References:1.Marahovsy Y. Cholelithiasis: on the Way of Diagnosis on Early Stages of Pathological Process in Gall-blade. // Russian Journal of Gastroenterology, Gepathology, Coloproctology, !4 (19). P. 6 16. 2.Carrey M. Pathogenesis of Gallstones. //Am. J. Surg., 1993. !4. P.410 419. 3.Rubens Yu., Yurika E., Seleznyov Y. Lithogene Indices: Methods of Defining, Clinical Opportunities, Information // Clinical Medicine. 1992. !7 8. P.39 41. 4.Yushkin N., Katkova V., Tkachev Yu. Mechnisms, Factors and Evolution of Mineral Formation. Syktyvkar, 2000. 34p. 5.Bilobrov V.M., Bogdan N.M. Features normal and pathological minerals. // Mineralogy and life: Materials to Regional Mineral Seminar. Syktyvkar, 1993. P.52 54. 2B>@A:89 C:070B5;L:  INDEX \h "A" \c "2" \z "1033"  B Babushkina M.S., 74 Borbat V.F., 75 G Golovanova O.A., 75 H Huizing T.E., 75 N Nikitina L.P., 74 O Ovchinnikov N.O., 74 P Pitanova P.A., 75 S Saltikova A.K., 74  ;D5@>20 .!., 11 =8A8<>2 .!., 2 =8A8<>20 .!., 3 =B>=>2 .., 65 ?>;;>=>2 .., 27 @B5<5=:> ., 5, 6 @B5<5=:> .., 5, 6 N?>20 . ., 7  0:H552 ., 25 0:H552 .., 25 5;>3C1 .., 40 >@=O: #.., 10 >@>28:>20 ..., 11 @8B28= !.., 12 C;0E .., 15  0;875@ .., 37, 38 8:5=BL52 .., 27  0;8520 . ., 14 >9;> -.., 20 @5:>20 .!., 41  O:82 .., 10  20=>2 .., 18 20=>2 ., 18 A05=:> !.., 19, 20 AB><8=0 .., 20  >1OH52 ..!., 37 >;<>3>@>2 ..., 41 >=>=:>20 .., 14 >B;O@>2 .., 40 @8=>2 .., 27 C4@O2F520 .., 25 C7=5F>20 .., 27 C@06:>2A:0O .!, 11  >2A:0O .., 44 KA5=:> .., 6 NB>52 .., 20  0A;5==8:>20 .., 30 59:A8=0 ..., 30 >8A5520 .., 34 >E>2 .., 27 CDB0E>2 .., 36  8:0=4@>2 !.., 37 >2>A5;>2 .., 40  0;LG8: .., 41 5:>2 .., 44 5B@>2 !.$., 45 >;5E>2A:89 ..!., 12, 69 >B0?>2 !.!., 49  0E<0=>20 .., 52 >52 !.., 62 ! !025;L52 .., 55 !5<:>20 ".., 56 !<>;O=A:89 .., 58 !>:>;-CBK;>2A:89 .., 60 !>:>;>2 !.., 51 !?8@84>=>2 -.., 17, 64 !B>;?>2A:0O .., 41 !CBO38=0 .., 55 !CE0@652A:0O .!, 61 " "@C=8;8=0 .., 62 "C@G:>20 ., 44 $ $5@C78 .., 30 $8;8<>=>2 !.., 63 % %;5ABC=>20 .., 65 ' '5@=8FK=0 .., 68 ( (C;L38= .., 69 / /I5=:> ./., 73   PAGE 62  / 8=5@0;K 8 ?0@035=578AK <8=5@0;>2  / 8=5@0;K 8 ?0@035=578AK <8=5@0;>2  PAGE 63  Fig.4. Pt,Fe solid alloy in Ti-Mgtin Fe-vernadite, bse image sphere, bse image  Fig.3. Ag,Cu,Pb,Pd, Ni-sulfide in Fe-vernadite, bse image  Fig. 2. Pd,Pt,Ru-selenide in over Foraminiferas, bse image Sn,As  oxide, bse image  Fig. 1 (Fe,Cr,Ni) pseudomorph over Foraminiferas, bse image  8A. $@03<5=B AB@>5=8O @0480;L=>-;CG8AB>3> A@>AB:0 A0<>@>4=>9 <548 (!u) A :0;LF8B>< (!a). 84=0 8=4C:F8>==0O HB@8E>2:0 =0 ?>25@E=>ABOE 2K45;5=89 8A.1 !>>B=>H5=85 SiO2 8 TiO2 2 :@5<=89-A>45@60I5< 8;L<5=8B5 87 <03<0B8G5A:8E ?>@>4 5@E>O=>->;K<A:8E <57>7>84: @8>;8B>2 8 B@0E8@8>;8B>2 (1), 0=4578B>2 8 0=4578B>-1070;LB>2 (2), 3@0=>48>@8B-?>@D8@>2 (3). Fig.1. Diagram of SiO2 and TiO2 contents in Si-bearing ilmenite from magmatic rocks of Verkhoyansk-Kolyma mesozoides: 1  from rhyolites and trachyrhyolites, 2  from andesites and andesite-basalts, 3  from granodiorite-prphyres. 8A. 2. A?KH5G=>5 8 2KA25G820NI55 2>7459AB285 @5=B35=>2A:8E ;CG59 =0  A8=8E F5=B@>2 A25B;>-A5@>3> A5;;08B0. #A;>28O 70?8A8: ( @53.= 420 =<, S=4 =<, VD=0,7 @/A, (2=30 <8=., t >1;.=80 <8=.;  @0AG5B ?@8 (1/e=22 <8=. Fig. 2. XEOL intensity of 420 nm band of greyish sellaite as a function of time for primary and second exciting  calculation with (1/e=22 min.  8A.1 !?5:B@K $ AC@0=A:>3> A5;;08B0 ?@8 (ex=370 nm. Fig. 1. Variations of fluorescence spectra of the Suran sellaite under (ex=370 nm.  LINK Excel.Chart.5 "C:\\TEXT\\SOKOLOV\\MUSSPB.XLS" "c" \p \* MERGEFORMAT   EMBED Excel.Sheet.8  8A. !?5:B@K ;075@>;N<8=5AF5=F88 E0==5H8B0 (a), :0@1>F5@=08B0 (b), AB@>=F80=8B0 (c) 8 4803@0<<0 >B=>H5=89 :>=F5=B@0F89 F5=B@>2 Sm3+ (d): 35:A03>=0;L=K5 (() 8 <>=>:;8==K5 (() G;5=K 3@C??K 15@10=:8B0, :0@1>F5@=08B ((), AB@>=F80=8B (() Fig. Laser luminescence spectra of khanneshite (a), carbocernaite (b), strontianite (c) and ratio concentration of Sm3+ centres diagram (d): hexagonal (() and monoclinic (() berbankite group members, carbocernaite ((), strontianite (() LINK Excel.Chart.5 "C:\\TEXT\\SOKOLOV\\MUSSPB.XLS" "a" \p \* MERGEFORMAT  LINK Excel.Chart.5 "C:\\TEXT\\SOKOLOV\\MUSSPB.XLS" "b" \p \* MERGEFORMAT  8A. !>AB02 B5;;C@84>-AC;LD840 <548 8 A5@51@0   8A. 3 @0D8:8 @0A?@545;5=8O TiO2, Nb2O5, Ta2O5 8 FeO 24>;L >A8 C4;8=5=8O :@8AB0;;0 MH8=8B0  8A. 2. >?5@5G=>5 A5G5=85 :@8AB0;;0 MH8=8B0 87 ?>;52>H?0B>2>9 7>=K <80A:8B>2>3> ?53<0B8B0 :>?8 210 ;L<5=A:8E 3>@ 8 AE5<0 @0A?>;>65=8O B>G5: 0=0;87>2 (8=45:AK  >1>7=0G5=8O A>>B25BAB2CNI8E ?8@0<84 @>AB0 :@8AB0;;0)  8A. 1. @>4>;L=>5 A5G5=85 :@8AB0;;0 MH8=8B0 87 ?>;52>H?0B>2>9 7>=K <80A:8B>2>3> ?53<0B8B0 :>?8 210 ;L<5=A:8E 3>@ 8 AE5<0 @0A?>;>65=8O B>G5: 0=0;87>2 8A. 803@0<<0 A>AB02>2 AC;LD>0@A5=84>2 65;570, :>10;LB0 8 =8:5;O ?> [1]. 1  0@A5=>?8@8B 87 @C4 H:8=8=A:>3> <5AB>@>645=8O; 2  35@A4>@D8B 8 ?@<56CB>G=0O D070 @O40 0@A5=>?8@8B-35@A4>@D8B 87 @C4 H:8=8=A:>3> <5AB>@>645=8O. 8A. !>>B=>H5=85 :0B8>=>2 Fe Al Mg 2 BC@<0;8=0E #A?5=A:>9 3>@:8. 8A.%0@0:B5@ @0A?@545;5=8O N3-45D5:B>2 2 :@8AB0;;0E 0;<07>2 (n  :>;8G5AB2> >1@07F>2): 0  A> !@54=53> "8<0=0, 1  87 5A?C1;8:8 !0E0, 2  87 @E0=35;LA:>9 >1;0AB8, 3  87 5@<A:>9 >1;0AB8 Fig. The character of distribution of N3-defects in crystals of diamonds (n  number of studied diamonds) 0  from Middle Timan region, 1  from Saha republic, 2  from Arhangelskiy region, 3  from Krasnovisherskiy region EMBED Word.Picture.8 8A. 8:@>7>=4>2K5 ?@>D8;8 ?> :@8AB0;;0< 3@0=0B>2 87 M:;>38B>2 15;>@5F:>3> <5B0<>@D8G5A:>3> :><?;5:A0. @8<5G0=85: 0  >1@075F 18704 (N3>-70?04=K9 A:;>= E@51B0 0O@40: 2 8AB>:0E @CGLO /=4K:); 1  >1@075F 15839 (CG0AB>:  %>;>4=K9 :;NG ); 2  >1@075F 18615 (:0@L5@ =0 70?04=>< A:;>=5 2KA>BK 607,6<), CG0AB>: @57:>3> ?>2KH5=8O A>45@60=8O 65;570 8 ?>=865=8O A>45@60=8O <03=8O A ;52>3> :@0O 3@0D8:0  @53@5AA82=0O >B>@>G:0. 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